摘要:
A method for recovering base oil from waste lubricating oil by separating base oil range constituents from a waste lubricating oil mixture, thereafter separating higher quality base oil constituents and lower quality base oil constituents from the base oil recovered from the waste lubricating oil mixture and thereafter treating the lower quality base oil constituents to produce marketable base oil. The total base oil produced from a waste lubricating oil mixture by this process is greater than the quantity producible by previous processes using only base oil separation from the waste lubricating oil mixture or processes which use only treatment of the base oil recovered from the waste lubricating oil mixture to produce the product base oil.
摘要:
A method for producing ILSAC GF5 or higher compatible oils from used oil, comprising separating material having a boiling point less than about 350° F. from recovered oil to produce de-volatized fraction and light oil fraction. Separating material with a boiling point greater than about 350° F. and less than about 650° F. from the de-volatized oil fraction to produce fuel oil fraction and heavy oil fraction. Separating material with a boiling point greater than about 1200° F. from the heavy oil fraction to produce partially purified oil fraction and residual fraction. Treating the partially purified oil fraction to separate it into purified oil fraction and contaminant fraction. Hydrogenating the contaminant fraction to remove predetermined compounds, further saturating the fraction and thereby creating a saturated oil fraction. Fractionating the saturated oil stream to produce one or more of naphtha fraction, diesel oil fraction and base oil fraction.
摘要:
The present disclosure is directed to a method and system of removing solubilized metals from a Fischer-Tropsch (FT) reactor product. The FT reactor product is contacted with a chelating agent to form metal complexes. The FT reactor product containing metal complexes are subjected to centrifugal separation to form a heavy phase and a light phase containing less than 500 wppb solubilized metals.
摘要:
The present invention relates to a process for the removal of mercury from a mercury-containing hydrocarbon fluid feed using specifically selected ionic liquids comprising, contacting the mercury-containing hydrocarbon fluid feed with an ionic liquid having the formula [Cat+][M+][X−] and separating from the ionic liquid a hydrocarbon fluid product having a reduced mercury content compared to the mercury-containing fluid feed.
摘要:
A process for de-acidifying a hydrocarbon feed includes contacting the hydrocarbon feed containing an organic acid with a feed-immiscible phosphonium ionic liquid to produce a hydrocarbon and feed-immiscible phosphonium ionic liquid mixture and separating the mixture to produce a hydrocarbon effluent having a reduced organic acid content relative to the hydrocarbon feed. Optionally, a de-emulsifier is added to at least one of the contacting and separating steps.
摘要:
Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream with a phosphorous compound selected from the group consisting of phosphine, hydrocarbylphosphines, hydrocarbylphosphites, hydrocarbylphosphonates, hydrocarbylphosphates, hydrocarbylphosphine oxides, hydrocarbylthiophosphites, and hydrocarbylphosphine sulfides to convert the metals to oil insoluble compounds which can be removed from the hydrocarbon containing feed stream by conventional methods.
摘要:
A process for removing metals in a petroleum oil material. The process comprises causing the petroleum oil material to react with a removing agent which comprises a phosphoric acid ester. A microwave irradiation environment was created during the reaction to provide the required energy essential for separating such contaminations from the oil chemical network. The process of the invention is applied at ambient pressure and low temperature compared to the conventional metal removal processes. The process of the invention can be readily scaled up and integrated into an industrial facility.
摘要:
A process for the treatment of a hydrocracking unit bottoms recycle stream, and preferably the fresh hydrocracker feed to remove heavy poly-nuclear aromatic (HPNA) compounds and HPNA precursors employs, in the alternative, an adsorption step which removes most of the HPNA compounds followed by an ionic liquid extraction step to remove the remaining HPNA compounds, or a first ionic liquid extraction step which removes most of the HPNA compounds followed by an adsorption step to remove the remaining HPNA compounds. Ionic liquids of the general formula Q+A− are identified for use in the process; organic polar solvents are identified for removal of the HPNA compounds in solution. Suitable adsorbents are identified for use in packed bed or slurry bed columns that operate within specified temperature and pressure ranges.
摘要:
A method for producing ILSAC GF5 or higher compatible oils from used oil, comprising separating material having a boiling point less than about 350° F. from recovered oil to produce de-volatized oil fraction and light oil fraction. Separating material with a boiling point greater than about 350° F. and less than about 650° F. from the de-volatized oil fraction to produce fuel oil fraction and heavy oil fraction. Separating material with a boiling point greater than about 1200° F. from the heavy oil fraction to produce partially purified oil fraction and residual fraction. Treating the partially purified oil fraction to separate it into purified oil fraction and contaminant fraction. Hydrogenating the contaminant fraction to remove predetermined compounds, further saturating the fraction and thereby creating a saturated oil fraction. Fractionating the saturated oil stream to produce one or more of naphtha fraction, diesel oil fraction and base oil fraction.
摘要:
A process for removing a nitrogen compound from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the nitrogen compound with a VGO-immiscible phosphonium ionic liquid to produce a vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced nitrogen content relative to the vacuum gas oil feed.