Ionic liquids containing secondary hydroxyl-groups and a method for their preparation
    3.
    发明申请
    Ionic liquids containing secondary hydroxyl-groups and a method for their preparation 审中-公开
    含有仲羟基的离子液体及其制备方法

    公开(公告)号:US20050065020A1

    公开(公告)日:2005-03-24

    申请号:US10934386

    申请日:2004-09-07

    IPC分类号: B01J31/00 C07F5/02 C07F13/00

    CPC分类号: B01J31/0284

    摘要: The invention provides ionic liquids having a secondary hydroxyl group, and an atom-efficient method for the preparation of these ionic liquids, by epoxidation of a protonated nitrogen-containing organic base (which can optionally be prepared in situ) in the presence of an anion suitable for supporting ionic liquid formation.

    摘要翻译: 本发明提供具有仲羟基的离子液体和用于制备这些离子液体的原子有效方法,通过在阴离子存在下,质子化的含氮有机碱(其可以任选地原位制备)进行环氧化 适合支持离子液体形成。

    Conversion method
    4.
    发明授权
    Conversion method 有权
    转换方法

    公开(公告)号:US08637660B2

    公开(公告)日:2014-01-28

    申请号:US12303358

    申请日:2007-05-18

    IPC分类号: C07H1/00 C07H1/08

    摘要: A process for the preparation of water-soluble cellulose hydrolysis products, which comprises admixing cellulose with an ionic liquid in which the cellulose has at least some solubility, said ionic liquid state at a temperature at or below 150 -C, and treating the resulting solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25 -C.

    摘要翻译: 一种制备水溶性纤维素水解产物的方法,其包括将纤维素与其中纤维素具有至少一些溶解度的离子液体混合,所述离子液体状态在150℃或低于150℃的温度下,并将所得溶液 在水存在下用酸,所述酸在25℃下的水中pKa小于2。

    Process For The Preparation Of Chalcogene Compounds
    5.
    发明申请
    Process For The Preparation Of Chalcogene Compounds 有权
    制备硫属化合物的方法

    公开(公告)号:US20120108822A1

    公开(公告)日:2012-05-03

    申请号:US13263192

    申请日:2010-03-30

    IPC分类号: C07D233/84

    CPC分类号: C07D233/42 Y02P20/582

    摘要: The present invention is a novel process for the preparation of chalcogenone compounds by conversion of ionic liquids and salts comprising nitrogen-containing heterocyclic cations and basic anions to the corresponding nitrogen-containing heterocyclic chalcogenones by reaction with elemental chalcogens.

    摘要翻译: 本发明是通过与元素硫属原子反应将离子液体和包含含氮杂环阳离子和碱性阴离子的盐转化成相应的含氮杂环硫族化合物来制备硫族化合物的新方法。

    CONVERSION METHOD
    6.
    发明申请
    CONVERSION METHOD 有权
    转换方法

    公开(公告)号:US20110312048A1

    公开(公告)日:2011-12-22

    申请号:US12676824

    申请日:2008-09-03

    IPC分类号: C13K1/02 C12P7/02

    摘要: A process is described for the preparation of water-soluble cellulose hydrolysis products The process comprises admixing cellulose with an ionic liquid capable of solvating or dissolving at least some of the cellulose, said ionic liquid being a compound comprised solely of cations and anions and which exists in a liquid state at a temperature at or below 15O° C., and in which the anions are selected from sulfate, hydrogen sulfate and nitrate; and treating the resulting solvate or solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25° C.

    摘要翻译: 描述了用于制备水溶性纤维素水解产物的方法。该方法包括将纤维素与能够溶解或溶解至少一些纤维素的离子液体混合,所述离子液体是仅由阳离子和阴离子组成的化合物,其存在 在等于或低于150℃的温度下处于液态,其中阴离子选自硫酸根,硫酸氢根和硝酸根; 并在酸存在下用酸处理得到的溶剂合物或溶液,所述酸在25℃下的水中pKa小于2。

    CONVERSION METHOD
    7.
    发明申请
    CONVERSION METHOD 有权
    转换方法

    公开(公告)号:US20130034891A1

    公开(公告)日:2013-02-07

    申请号:US13649726

    申请日:2012-10-11

    IPC分类号: C12P7/02 C12P7/10

    摘要: A process is described for the preparation of water-soluble cellulose hydrolysis product. The process comprise admixing cellulose with an ionic liquid capable of solvating or dissolving at least some of the cellulose, said ionic liquid being a compound comprises solely of cations and anions and which exists in a liquid state at a temperature at or below 150° C., and in which the anions are selected from halide and cyanate; and treating the resulting solvate or solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25° C.

    摘要翻译: 描述了制备水溶性纤维素水解产物的方法。 该方法包括将纤维素与能够溶解或溶解至少一些纤维素的离子液体混合,所述离子液体是仅由阳离子和阴离子组成的化合物,并且在等于或低于150℃的温度下以液态存在。 ,其中阴离子选自卤化物和氰酸酯; 并在酸存在下用酸处理得到的溶剂合物或溶液,所述酸在25℃下的水中pKa小于2。

    CONVERSION METHOD
    8.
    发明申请
    CONVERSION METHOD 有权
    转换方法

    公开(公告)号:US20120029247A1

    公开(公告)日:2012-02-02

    申请号:US12676831

    申请日:2008-09-03

    IPC分类号: C07C29/00 C13K1/02

    摘要: A process is described for the preparation of water-soluble cellulose hydrolysis products, which comprises admixing cellulose with an ionic liquid capable of solvating or dissolving at least some of the cellulose, said ionic liquid being a compound comprised solely of cations and anions and which exists in a liquid state at a temperature at or below 15O° C., the cations in said ionic liquid having the general formula (I), in which Z represents a nitrogen or phosphorus atom, R1 represents a methyl or ethyl group, each of R2 and R3, which may be the same or different, is selected from C4-3alkyl, optionally-substituted benzyl, optionally-substituted phenyl, and C5-7 cycloalkyl, and R4 represents C1-8 alkyl, optionally-substituted benzyl, optionally-substituted phenyl or C5-7cyclohexyl; in which the optional substituents on a benzyl or phenyl ring are one, two or three substituents selected from C1-4alkyl or alkoxy groups, halogen atoms and nitro groups; and treating the resulting solvate or solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25° C.

    摘要翻译: 描述了用于制备水溶性纤维素水解产物的方法,其包括将纤维素与能够溶解或溶解至少一些纤维素的离子液体混合,所述离子液体是仅由阳离子和阴离子组成的化合物,其存在 在等于或低于150℃的液态下,具有通式(I)的所述离子液体中的阳离子,其中Z表示氮或磷原子,R1表示甲基或乙基,R2各自表示 和可以相同或不同的R 3选自C 4-3烷基,任选取代的苄基,任选取代的苯基和C 5-7环烷​​基,R 4表示C 1-8烷基,任选取代的苄基,任选取代的 苯基或C 5-7环己基; 其中苄基或苯环上的任选取代基是选自C 1-4烷基或烷氧基,卤素原子和硝基的一个,两个或三个取代基; 并在酸存在下用酸处理得到的溶剂合物或溶液,所述酸在25℃下的水中pKa小于2。

    CONVERSION METHOD
    9.
    发明申请
    CONVERSION METHOD 有权
    转换方法

    公开(公告)号:US20090198046A1

    公开(公告)日:2009-08-06

    申请号:US12303358

    申请日:2007-05-18

    IPC分类号: C07H1/00 C07C29/00

    摘要: A process for the preparation of water-soluble cellulose hydrolysis products, which comprises admixing cellulose with an ionic liquid in which the cellulose has at least some sollubility, said ionic liquid state at a temperature at or below 150 -C, and treating the resulting solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25 -C.

    摘要翻译: 一种制备水溶性纤维素水解产物的方法,其包括将纤维素与其中纤维素具有至少一些溶解性的离子液体混合,所述离子液体状态在150℃或更低的温度下,并将所得溶液 在水存在下用酸,所述酸在25℃下的水中pKa小于2。

    GLYCIDOL PREPARATION
    10.
    发明申请
    GLYCIDOL PREPARATION 审中-公开
    甘氨酸制剂

    公开(公告)号:US20160200699A1

    公开(公告)日:2016-07-14

    申请号:US14910835

    申请日:2014-08-08

    IPC分类号: C07D301/02

    CPC分类号: C07D301/02

    摘要: This invention relates to an improved one-pot synthetic process for the preparation of glycidol from the reaction of glycerol and dimethyl carbonate. More specifically, the invention relates to a one-pot synthetic process for the preparation of glycidol comprising the reaction of glycerol and dimethyl carbonate in the presence of an ionic liquid catalyst having the formula: [Cat+][X] wherein: [Cat] represents one or more cationic species, and [X] represents one or more anionic species; wherein the reaction is conducted at a temperature of from 100° C. to 160° C. and wherein the molar ratio of glycerol to dimethylcarbonate is from 1:4 to 1:10.

    摘要翻译: 本发明涉及从甘油和碳酸二甲酯的反应制备缩水甘油的改进的一锅合成方法。 更具体地说,本发明涉及一种用于制备缩水甘油的一锅合成方法,其包括在具有下式的离子液体催化剂存在下,甘油和碳酸二甲酯的反应:[Cat +] [X]其中:[Cat]代表 一种或多种阳离子物质,[X]表示一种或多种阴离子物质; 其中所述反应在100℃至160℃的温度下进行,并且其中甘油与碳酸二甲酯的摩尔比为1:4至1:10。