公开(公告)号：US4446007A

公开(公告)日：1984-05-01

申请号：US386463

申请日：1982-06-08

申请人： Fritz A. Smith

发明人： Fritz A. Smith

IPC分类号： C10G45/64 ,  C10G49/24 ,  C10G47/16

CPC分类号： C10G49/24 ,  C10G45/64

摘要： An improved method for hydrodewaxing a petroleum or shale oil fraction, e.g. petroleum distillate, in a reactor is provided which involves contacting said fraction with hydrogen in the presence of a catalyst comprising a crystalline zeolite having a silica to alumina mole ratio of at least 12 under hydrodewaxing conditions wherein the average reactor temperature at start-up of from about 200.degree. C. to 310.degree. C. is increased uniformly to at least 360.degree. C. within about seven days from start-up.

摘要翻译： 用于加氢脱蜡石油或页岩油馏分的改进方法，例如。 石油馏出物在反应器中提供，其包括在催化剂存在下使所述馏分与氢气接触，所述催化剂包含在加氢脱蜡条件下二氧化硅与氧化铝摩尔比至少为12的结晶沸石，其中起始时的平均反应器温度 在启动后约七天内，约200℃至310℃均匀地增加至至少360℃。

公开(公告)号：US4053390A

公开(公告)日：1977-10-11

申请号：US641394

申请日：1975-12-17

申请人： Lewis C. James

发明人： Lewis C. James

IPC分类号： C10G47/30 ,  C10G49/24 ,  C10G13/02 ,  C10G23/10

CPC分类号： C10G49/24

摘要： In starting up an upflow, ebullated bed hydroprocessing reactor, a light oil is used, to establish an ebullating bed. As heavy residual feedstock is incrementally substituted, the ebullating pump speed and gas flow rate need to be monitored and adjusted for smooth operation. By knowing and controlling the viscosity and density of the feedstock, flow variations inside the reactor can be minimized, resulting in a constant pump speed and gas flow rate.

公开(公告)号：US3654138A

公开(公告)日：1972-04-04

申请号：US3654138D

申请日：1970-06-17

申请人： STANDARD OIL CO

发明人： MOSBY JAMES F ,  KOLLER JAMES C JR

IPC分类号： C10G49/24 ,  C10G13/02 ,  C10G23/00

CPC分类号： C10G49/24

摘要： START-UP METHOD COMPRISES CONTACTING THE HYDROCRACKING CATALYST WITH A HYDROGEN-CONTAININ G GAS AT A PRESSURE BETWEEN ABOUT 0 AND ABOUT 2,500 P.S.I.G. AND A TEMPERATURE BETWEEN ABOUT 400* F. AND ABOUT 850* F.; COOLING THE CATALYST TO MINIMIZE CONVERSION OF HYDROCARBONS; CONTACTING THE CATALYST WITH A FIRST PRELIMINARY HYDROCARBON FEEDSTOCK HAVING LOW CONCENTRATIONS OF NITROGEN, SULFUR AND AROMATICS IN A MANNER THAT WILL NOT DELETERIOUSLY AFFECT THE CATALYST; INCREASING THE TEMPERATURE IN THE REACTION ZONE TO OBTAIN CONVERSION OF THE FIRST PRELIMINARY HYDROCARBON FEEDSTOCK TO LOWER-BOILING HYDROCARBONS; STOPPING THE FLOW OF THE FIRST PRELIMINARY HYDROCARBON FEEDSTOCK; AND CONTACTING THE CATALYST WITH A PRICIPAL PETROLEUM HYDROCARBON FEEDSTOCK. THE HYDROCRACKING CATALYST COMPRISES A HYDROGENATION COMPONENT ON A CO-CATALYTIC SUPPORT. THE PREFERRED SUPPORT COMPRISES ULTRASTABLE, LARGEPORE CRYSTALLINE ALUMINOSILICATE MATERIAL SUSPENDED IN A POROUS MATRIX OF AMORPHOUS SILICA-ALUMINA. THE PREFERRED HYDROGENATION COMPONENT COMPRISES A MIXTURE OF COBALT OXIDE AND MOLYBDENUM TRIOXIDE.

公开(公告)号：US3556986A

公开(公告)日：1971-01-19

申请号：US3556986D

申请日：1969-09-29

申请人： CHEVRON RES

发明人： BECK ROBERT R ,  KNOWLTON HAROLD E ,  MCCOY CHARLES S

IPC分类号： B01J23/40 ,  B01J23/42 ,  C10G35/22 ,  C10G49/24 ,  C10G69/08 ,  C10G23/00

CPC分类号： B01J23/40 ,  B01J23/42 ,  C10G35/22 ,  C10G49/24 ,  C10G2400/02

摘要： A COMBINED HYDROFINING-DESULFURIZING-REFORMING SYSTEM IS BROUGHT ON STREAM RAPIDLY WHEN PROCESSING A FEED BOILING IN THE RANGE FROM 150* TO 450*F. AND CONTAINING SUBSTANTIALLY NO C3-C5 HYDROCARBONS, BY INTRODUCING MAKEUP C3-C5 HYDROCARBONS TO THE HYDROFINING ZONE OR DESULFURIZING ZONE AND PERMITTING THE C3-C5 HYDROCARBONS TO BE REFLUXED IN THE DESULFURIZING ZONE.

公开(公告)号：US09777227B2

公开(公告)日：2017-10-03

申请号：US14683458

申请日：2015-04-10

申请人： ExxonMobil Chemical Patents Inc.

发明人： Nikolaos Soultanidis ,  John S. Buchanan ,  Christopher M. Evans ,  David T. Ferrughelli ,  Luc R. M. Martens ,  Keith G. Reed ,  Frank C. Wang ,  Teng Xu ,  Cathleen Yung

IPC分类号： C10G69/06 ,  C10G69/00 ,  C10G49/00 ,  C10G49/22 ,  C10G49/24 ,  C10L1/04

CPC分类号： C10G49/00 ,  C10G49/22 ,  C10G49/24 ,  C10G69/00 ,  C10G69/06 ,  C10G2300/4031 ,  C10G2300/4081 ,  C10L1/04

摘要： The invention relates to a utility fluid, such as a fluid containing aromatic and non-aromatic ringed molecules, useful as a diluent when hydroprocessing pyrolysis tar, such as steam cracker tar. The specified utility fluid comprises ≧10.0 wt % aromatic and non-aromatic ring compounds and each of the following: (a) ≧1.0 wt % of 1.0 ring class compounds; (b) ≧5.0 wt % of 1.5 ring class compounds; (c) ≧5.0 wt % of 2.0 ring class compounds; and (d) ≦0.1 wt % of 5.0 ring class compounds. The invention also relates to methods for producing such a utility fluid and to processes for hydroprocessing pyrolysis tar.

公开(公告)号：US09617484B2

公开(公告)日：2017-04-11

申请号：US14299838

申请日：2014-06-09

申请人： UOP LLC

发明人： Richard K. Hoehn ,  Phillip F. Daly ,  Xin X. Zhu

IPC分类号： C10G49/24 ,  C10G49/26 ,  C10G45/02 ,  C10G45/72 ,  C10G45/12 ,  C10G45/06

CPC分类号： C10G49/24 ,  C10G45/02 ,  C10G45/06 ,  C10G45/12 ,  C10G45/72 ,  C10G49/26 ,  C10G2300/202 ,  C10G2300/4031

摘要： Methods and apparatuses are provided for hydrotreating hydrocarbons. A method includes heating a start-up oil in a stripper liquid fraction heat exchanger during a start-up period, and heating a reactor with the start-up oil. The start-up oil is discharged from the reactor when the start-up period ends, and a standard operating period begins after the start-up period. A reactor effluent is produced by introducing a hydrocarbon stream into the reactor during the standard operating period, where hydrogen sulfide is produced from an organic sulfur compound in the hydrocarbon stream. Steam is produced in the stripper liquid fraction heat exchanger during the standard operating period.

公开(公告)号：US5888377A

公开(公告)日：1999-03-30

申请号：US994897

申请日：1997-12-19

申请人： Ricky Val Bertram

发明人： Ricky Val Bertram

IPC分类号： C10G47/18 ,  C10G49/24 ,  C10G65/10

CPC分类号： C10G47/18 ,  C10G49/24

摘要： The safety, convenience and environmental acceptability of starting a two-stage hydrocracking process unit is increased by employing aqueous ammonia as a selective catalyst poison. The aqueous ammonia is injected into the recycle gas system of the hydrocracking process. The invention eliminates the possibility of forming a large airborne cloud of ammonia gas upon an accidental release of the ammonia stream as is possible with the injection of anhydrous ammonia. The invention also stabilizes the operation of the unit through the use of a maintenance injection rate sufficient to maintain an inlet ammonia content above about 40 ppm.

摘要翻译： 通过使用氨水作为选择性催化剂毒物，可以提高启动两级加氢裂化处理单元的安全性，方便性和环境可接受性。 将氨水注入加氢裂化过程的循环气体系统中。 本发明消除了在注入无水氨的情况下意外释放氨气流时形成大量空气中的氨气的可能性。 本发明还通过使用足以维持高于约40ppm的入口氨含量的维护注入速率来稳定单元的操作。

公开(公告)号：US5006224A

公开(公告)日：1991-04-09

申请号：US361197

申请日：1989-06-05

申请人： John A. Smegal ,  Haluk A. Bilgic ,  Robert C. Ryan ,  Vance J. Grieshop

发明人： John A. Smegal ,  Haluk A. Bilgic ,  Robert C. Ryan ,  Vance J. Grieshop

IPC分类号： C10G49/24

CPC分类号： C10G49/24

摘要： The instant invention comprises an improved hydrorefining process which comprises contacting hydrocarbonaceous oil feed and hydrogen with a catalyst comprising a hydrogenation component selected from the group consisting of Group VIB metal component, Group VIII non-noble metal component and mixtures thereof, optionally comprising a phosphorous-containing component or compound, and an alumina-containing support, at hydrorefining conditions, wherein the improvement comprises heating the catalyst at initial start-up from a temperature below about 450.degree. F. to hydrorefining temperature at an average rate of less than 30.degree. F. per hour in the presence of hydrogen and said oil feed.

摘要翻译： 本发明包括改进的加氢精制方法，其包括使烃油进料和氢与含有选自VIB族金属组分，VIII族非贵金属组分及其混合物的氢化组分的催化剂接触，任选地包含含磷 - 在加氢精制条件下，所述改进包括在初始启动时将催化剂从低于约450°F的温度加热至加氢精制温度，平均速率低于30°F 在氢气和所述油进料的存在下每小时。

公开(公告)号：US4119530A

公开(公告)日：1978-10-10

申请号：US761504

申请日：1977-01-21

申请人： George J. Czajkowski ,  Frank Stolfa

发明人： George J. Czajkowski ,  Frank Stolfa

IPC分类号： C10G45/18 ,  C10G49/24 ,  C10G23/08

CPC分类号： C10G45/18 ,  C10G49/24

摘要： A startup method for moving-bed reactors used in hydrocarbon conversion processes wherein the reactor is brought on-stream at full capacity while it contains less than a full loading of catalyst, and quantities of catalyst are intermittently added to the reactor while the hydrocarbons are being processed. Catalyst removal is then begun at a rate lower than the rate of catalyst addition and adjusted when the catalyst retention volume of the reactor becomes filled. The method is specifically adaptable to the hydrogenation of olefinic materials, the desulfurization of petroleum fractions and the production of liquid products from coal.

摘要翻译： 用于烃转化过程中的移动床反应器的启动方法，其中反应器以满容量运载，同时其含有小于全负载量的催化剂，并且将数量的催化剂间歇地加入到反应器中，同时烃是 处理。 然后以低于催化剂加入速率的速率开始催化剂去除，并且当反应器的催化剂保留体积被填充时调节。 该方法特别适用于烯烃材料的氢化，石油馏分的脱硫和煤的液体产物的生产。

公开(公告)号：US4064036A

公开(公告)日：1977-12-20

申请号：US732533

申请日：1976-10-14

申请人： Danford E. Clark

发明人： Danford E. Clark

IPC分类号： C10G49/24 ,  B01J29/14 ,  G01M3/04 ,  G01N31/10 ,  G01N33/00

CPC分类号： C10G49/24

摘要： In the pressure testing of catalyst-loaded reactors with nitrogen gas at elevated temperatures, it is found that certain types of zeolite catalysts are substantially degraded in activity. The catalysts concerned comprises a Group VIII noble metal in an oxidized state, dispersed on a crystalline hydrogen zeolite, e.g., Y zeolite. It has now been discovered however that if such catalysts are first prereduced with a dilute, non-combustible mixture of nitrogen and hydrogen, damage on subsequent pressure testing with nitrogen is prevented or drastically reduced. Following pressure testing, the catalyst is activated by dehydration in a stream of hydrogen at elevated temperatures and pressures.

摘要翻译： 在具有氮气的催化剂负载的反应器在升高的温度下的压力测试中，发现某些类型的沸石催化剂的活性显着降低。 所涉及的催化剂包括分散在结晶氢沸石如Y沸石上的氧化态的VIII族贵金属。 然而，现在已经发现，如果首先用稀释的，不可燃的氮气和氢气的混合物还原这种催化剂，则防止或大大降低随后用氮气进行的压力测试的损害。 经过压力测试，催化剂在高温和高压下在氢气流中脱水而活化。