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公开(公告)号：US20180044260A1
公开(公告)日：2018-02-15
申请号：US15555604
申请日：2015-12-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Nikolaos Soultanidis , Jeevan s. Abichandani , Mayank Shekhar
CPC classification number: C07C1/20 , B01J29/405 , B01J37/28 , B01J2229/36 , C07C2/42 , C07C5/333 , C07C5/393 , C07C5/415 , C07C2529/40 , C10G11/02 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C15/08 , C07C15/02
Abstract: Processes are provided for conversion of oxygenated hydrocarbon, such as methanol and/or dimethyl ether, to aromatics, such as a para-xylene, and olefins, such as ethylene and propylene. The processes entail using a reactor having multiple reaction zones where each zone is prepared to promote desired reactions.
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公开(公告)号：US09637694B2
公开(公告)日：2017-05-02
申请号：US14683482
申请日：2015-04-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Christopher M. Evans , Nikolaos Soultanidis , Reyyan Koc-Karabocek , David T. Ferrughelli , Teng Xu
CPC classification number: C10G69/06 , C10G9/36 , C10G2300/80
Abstract: The invention relates to a process for upgrading pyrolysis tar, such as steam cracker tar, in the presence of a utility fluid. The utility fluid contains 2-ring and/or 3-ring aromatics and has solubility blending number (SBN)≧120. The invention also relates to the upgraded pyrolysis tar and to the use of the upgraded pyrolysis tar, for example, for fuel oil blending.
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公开(公告)号：US20160122667A1
公开(公告)日：2016-05-05
申请号：US14683482
申请日：2015-04-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Christopher M. Evans , Nikolaos Soultanidis , Reyyan Koc-Karabocek , David T. Ferrughelli , Teng Xu
IPC: C10G69/06
CPC classification number: C10G69/06 , C10G9/36 , C10G2300/80
Abstract: The invention relates to a process for upgrading pyrolysis tar, such as steam cracker tar, in the presence of a utility fluid. The utility fluid contains 2-ring and/or 3-ring aromatics and has solubility blending number (SBN)≧120. The invention also relates to the upgraded pyrolysis tar and to the use of the upgraded pyrolysis tar, for example, for fuel oil blending.
Abstract translation: 本发明涉及一种用于在效用流体存在下升级热解焦油，例如蒸汽裂解焦油的方法。 实用液体含有2-环和/或3-环芳烃，溶解度共混数（SBN）≥120。 本发明还涉及升级的热解焦油和使用升级的热解焦油，例如用于燃料油混合。
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公开(公告)号：US20180370874A1
公开(公告)日：2018-12-27
申请号：US15775466
申请日：2016-12-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Michael Salciccioli , Hari Nair , Glenn C. Wood , Nikolaos Soultanidis
Abstract: Systems and methods are provided for forming para-xylene from aromatics-containing streams having reduced or minimized amounts of C2+ side chains. Reduced or minimized amounts of C2+ side chains can provide benefits for improving and/or allowing modification of transalkylation conditions, xylene isomerization conditions, or a combination thereof. Such aromatics-containing streams can be formed, for example, by conversion of methyl halide, methanol, syngas, and/or dimethyl ether to aromatics by an aromatic conversion process. The methyl halide, methanol, syngas, and/or dimethyl ether can be formed by conversion of methane.
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公开(公告)号：US10053633B2
公开(公告)日：2018-08-21
申请号：US15722808
申请日：2017-10-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： James H. Beech, Jr. , Nikolaos Soultanidis , Steven E. Silverberg
IPC: C10G2/00 , B01J29/06 , B01J29/064 , B01J23/70 , B01J29/48 , B01J23/26 , B01J29/42 , C07C1/04 , B01J35/00 , C10G29/22 , B01J29/076 , B01J23/46 , B01J29/40 , C07C2/86 , B01J23/06 , B01J23/34
CPC classification number: C10G2/334 , B01J23/06 , B01J23/26 , B01J23/34 , B01J23/462 , B01J23/70 , B01J29/06 , B01J29/064 , B01J29/076 , B01J29/405 , B01J29/42 , B01J29/48 , B01J35/0006 , C07C1/0485 , C07C2/864 , C07C2529/40 , C10G2/331 , C10G29/22 , C10G2400/30 , Y02P20/52 , C07C15/08 , C07C15/04 , C07C15/06
Abstract: This disclosure relates to the production of xylenes from syngas, in which the syngas is converted to an aromatic product by reaction with a Fischer-Tropsch catalyst and an aromatization catalyst. The Fischer-Tropsch catalyst and aromatization catalyst may be different catalysts or combined into a single catalyst. The aromatic product is then subjected to selective alkylation with methanol and/or carbon monoxide and hydrogen to increase its p-xylene content.
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Patent Agency Ranking
公开(公告)号：US20180208523A1
公开(公告)日：2018-07-26
申请号：US15928142
申请日：2018-03-22
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Paul F. Keusenkothen , Seth M. Washburn , Neeraj Sangar , Nikolaos Soultanidis , Mayank Shekhar
CPC classification number: C07C1/20 , B01J8/0221 , B01J8/0278 , B01J8/0285 , B01J8/06 , B01J8/1863 , B01J8/26 , B01J2208/00309 , C10G3/46 , C10G3/47 , C10G3/49 , C10G2400/30
Abstract: A catalyst system and processes for combined aromatization and selective hydrogen combustion of oxygenated hydrocarbons are disclosed. The catalyst system contains at least one aromatization component and at least one selective hydrogen combustion component. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the aromatization component alone.
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公开(公告)号：US20150175499A1
公开(公告)日：2015-06-25
申请号：US14560889
申请日：2014-12-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John D. Ou , Nikolaos Soultanidis , Mayank Shekhar , Samia Ilias , Helge Jaensch , Stephen J. McCarthy
IPC: C07C1/22
CPC classification number: C07C1/22 , C07C1/24 , C07C2/64 , C07C5/2729 , C07C6/00 , C07C6/06 , C07C2529/40 , C10G3/49 , C10G29/205 , C10G2400/30 , Y02P30/20 , Y02P30/42
Abstract: Methods are provided for conversion of methanol and/or dimethyl ether to aromatics, such as a para-xylene, and olefins, such as ethylene and propylene. The methods can be used in conjunction with molecular sieve (zeolite) catalysts that are prepared for use in conjunction with selected effective conversion conditions. The combination of a catalyst and a corresponding effective conversion condition can allow for improved yield aromatics and olefins generally; improved yield of desired aromatics and olefins, such as para-xylene, ethylene, and/or propylene; reduced production of less desirable side products, such as methane, CO, CO2, and/or coke; or a combination thereof. The preparation of the catalyst can include modification of the catalyst with a transition metal, such as Zn or Ga. The preparation of the catalyst can also include steaming of the catalyst. In some aspects, the preparation of the catalyst can further include modifying the catalyst with phosphorous.
Abstract translation: 提供了用于将甲醇和/或二甲醚转化为芳族化合物如对二甲苯和烯烃如乙烯和丙烯的方法。 这些方法可以与准备与选择的有效转化条件结合使用的分子筛（沸石）催化剂结合使用。 催化剂和相应的有效转化条件的组合可以允许通常改善产率芳族化合物和烯烃; 所需芳族化合物和烯烃的产率提高，如对二甲苯，乙烯和/或丙烯; 降低生产较不理想的副产物，如甲烷，CO，CO2和/或焦炭; 或其组合。 催化剂的制备可以包括用过渡金属如Zn或Ga改性催化剂，催化剂的制备还可以包括蒸发催化剂。 在一些方面，催化剂的制备可进一步包括用磷改性催化剂。
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公开(公告)号：US10647640B2
公开(公告)日：2020-05-12
申请号：US15775466
申请日：2016-12-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Michael Salciccioli , Hari Nair , Glenn C. Wood , Nikolaos Soultanidis
Abstract: Systems and methods are provided for forming para-xylene from aromatics-containing streams having reduced or minimized amounts of C2+ side chains. Reduced or minimized amounts of C2+ side chains can provide benefits for improving and/or allowing modification of transalkylation conditions, xylene isomerization conditions, or a combination thereof. Such aromatics-containing streams can be formed, for example, by conversion of methyl halide, methanol, syngas, and/or dimethyl ether to aromatics by an aromatic conversion process. The methyl halide, methanol, syngas, and/or dimethyl ether can be formed by conversion of methane.
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公开(公告)号：US10647633B2
公开(公告)日：2020-05-12
申请号：US16075727
申请日：2017-01-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Nikolaos Soultanidis , Todd E. Detjen , Scott J. Weigel
IPC: C07C2/86 , B01J29/42 , B01J29/46 , B01J29/40 , B01J37/28 , C07C15/067 , B01J29/44 , B01J29/80 , B01J37/00 , B01J35/00
Abstract: A fluidized bed process for producing para-xylene via toluene and/or benzene methylation with methanol using a dual function catalyst system. A first catalyst accomplishes the toluene and/or benzene methylation and a second catalyst converts the by-products of the methylation reaction or unconverted methylating agent, improves the yields of the desired products, or a combination thereof. The inclusion of the second catalyst can suppress the C1-C5 non-aromatic fraction by over 50% and significantly enhance the formation of aromatics.
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公开(公告)号：US10059638B2
公开(公告)日：2018-08-28
申请号：US15555604
申请日：2015-12-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Nikolaos Soultanidis , Jeevan S. Abichandani , Mayank Shekhar
CPC classification number: C07C1/20 , B01J29/405 , B01J37/28 , B01J2229/36 , C07C2/42 , C07C5/333 , C07C5/393 , C07C5/415 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/54 , C10G11/02 , C10G45/60 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C15/08 , C07C15/02
Abstract: Processes are provided for conversion of oxygenated hydrocarbon, such as methanol and/or dimethyl ether, to aromatics, such as a para-xylene, and olefins, such as ethylene and propylene. The processes entail using a reactor having multiple reaction zones where each zone is prepared to promote desired reactions.
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