公开(公告)号：WO2016022581A1

公开(公告)日：2016-02-11

申请号：PCT/US2015/043642

申请日：2015-08-04

Applicant: EQUISTAR CHEMICALS, LP

Inventor： LEE, Chun, D. ,  BOTROS, Maged, G. ,  PODBORNY, William, R.

IPC: C09J123/06 ,  C09J4/00

CPC classification number: C09J123/06 ,  B32B7/12 ,  B32B27/08 ,  B32B27/18 ,  B32B27/306 ,  B32B27/32 ,  B32B27/327 ,  B32B27/34 ,  B32B27/36 ,  B32B2250/24 ,  B32B2307/72 ,  B32B2405/00 ,  B32B2419/00 ,  B32B2439/00 ,  B32B2439/70 ,  C08L23/04 ,  C08L23/0815 ,  C08L23/16 ,  C08L51/06 ,  C08L2205/035 ,  C08L2207/062 ,  C08L2314/02 ,  C08L2314/06 ,  C09J123/04 ,  C09J123/0815 ,  C08L23/08

Abstract: The present disclosure provides a polyolefin-based composition made from or containing (A) a first grafted polyolefin composition, (B) a second grafted polyolefin composition made from or containing a first metallocene-catalyzed linear low density polyethylene grafted with an unsaturated monomer, (C) a second metallocene-catalyzed linear low density polyethylene composition, (D) a Ziegler-Natta-catalyzed linear low density polyethylene composition, (E) an elastomeric composition made from or containing (i) an elastomeric ethylene copolymer and (ii) an ethylene-propylene elastomer, and (F) a tackifier composition. Optionally, the polyolefin- based composition may be further made from or contain an additives composition. The polymeric composition is suitable for use as a tie-layer adhesive composition.

Abstract translation: 本公开内容提供由（A）第一接枝聚烯烃组合物制备或含有的聚烯烃基组合物，（B）由或接受由不饱和单体接枝的第一茂金属催化的线性低密度聚乙烯制成的第二接枝聚烯烃组合物（ C）第二茂金属催化的线性低密度聚乙烯组合物，（D）齐格勒 - 纳塔催化的线性低密度聚乙烯组合物，（E）由（或）弹性体乙烯共聚物制备或包含（或） 乙烯 - 丙烯弹性体和（F）增粘剂组合物。 任选地，聚烯烃基组合物可以进一步由添加剂组合物制成或含有添加剂组合物。 聚合物组合物适合用作粘结层粘合剂组合物。

公开(公告)号：WO2015142602A1

公开(公告)日：2015-09-24

申请号：PCT/US2015/020071

申请日：2015-03-12

Applicant: EQUISTAR CHEMICALS, LP ,  BASELL POLIOLEFINE ITALIA, S.R.L.

Inventor： BOTROS, Maged, G. ,  COSTANTINI, Enrico ,  HOLLAND, Charles, S. ,  LEE, Chun, D. ,  MASARATI, Enrico

IPC: C08L51/06 ,  C08L23/12 ,  C09J151/06 ,  C09J123/12 ,  B32B27/32

CPC classification number: C08L23/10 ,  C08L23/14 ,  C08L23/16 ,  C08L51/06 ,  C08L2203/16 ,  C09J123/14 ,  C08L23/02

Abstract: The present disclosure provides a polyolefin-based composition suitable for use as adhesives and/or tie-layer adhesive compositions as well as a multi-layered structure made from and/ or containing the polyolefin-based composition. The polyolefin-based composition is made from and/or contains (a) a grafted polyolefin composition, (b) a first polymer composition, (c) a polypropylene-containing blend composition, and (d) optionally, an additives composition having one or more additives.

Abstract translation: 本公开内容提供了适合用作粘合剂和/或粘结层粘合剂组合物的聚烯烃基组合物以及由和/或含有聚烯烃基组合物制成的多层结构。 聚烯烃基组合物由（a）接枝聚烯烃组合物和（b）第一聚合物组合物，（c）含聚丙烯的共混物组合物和（d）任选的， 更多的添加剂。

公开(公告)号：WO2011082048A1

公开(公告)日：2011-07-07

申请号：PCT/US2010/061719

申请日：2010-12-22

Applicant: EQUISTAR CHEMICALS, LP

Inventor： BOTROS, Maged, G.

IPC: B32B27/00

CPC classification number: B32B27/00 ,  Y10T428/31544 ,  Y10T428/3175 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31931

Abstract: Multilayer structures having layers of a styrene polymer, polyethylene, propylene polymer, and common tie layers of a styrene-butadiene-styrene tπblock copolymer-containing adhesive.

Abstract translation: 具有苯乙烯聚合物，聚乙烯，丙烯聚合物层和苯乙烯 - 丁二烯 - 苯乙烯含嵌段共聚物的粘合剂的普通粘合层的多层结构。

公开(公告)号：WO2004016667A2

公开(公告)日：2004-02-26

申请号：PCT/US2003/015413

申请日：2003-05-15

Applicant: EQUISTAR CHEMICALS, LP

Inventor： BOTROS, Maged, G.

IPC: C08F255/02

CPC classification number: C09J151/06 ,  C08F255/02 ,  C08L2666/02 ,  C08L2666/04

Abstract: Improved grafted propylene copolymer compositions and adhesive blends containing same are provided. The grafts are obtained by reacting propylene-ethylene impact copolymers having specified rubber contents and molecular weight distributions with ethylenically unsaturated acids or acid derivatives, such as maleic anhydride.

Abstract translation: 提供了改进的接枝丙烯共聚物组合物和含有它们的粘合剂共混物。 通过使具有特定橡胶含量和分子量分布的丙烯 - 乙烯抗冲共聚物与烯属不饱和酸或酸衍生物如马来酸酐反应获得接枝。

公开(公告)号：WO2017200867A1

公开(公告)日：2017-11-23

申请号：PCT/US2017/032379

申请日：2017-05-12

Applicant: EQUISTAR CHEMICALS, LP

Inventor： BOTROS, Maged, G. ,  PODBORNY, William, R. ,  CORCORAN, Lindsay, E.

IPC: C09J123/08 ,  B32B27/32 ,  C08L51/06

Abstract: Adhesive compositions, processes of forming adhesive compositions, and multi -layer films are discussed herein. Hie processes generally include contacting an olefin monomer with a catalyst system within a polymerization zone to form an olefin based polymer under polymerization conditions sufficient to form the olefin based polymer, the catalyst system including a metal component generally represented by the formula: MR X ; wherein M is a transition metal, R is a halogen, an aikoxy, or a hydrocarboxyl group and x is the valence of the transition metal, wherein the catalyst system further includes an internal donor (ID) comprising a C 3 -C 6 cyclic ether: and withdrawing the olefin based polymer from the polymerization zone; and melt blending the olefin based polymer with a functionalized poly olefin to form a polyolefm based adhesive composition, wherein the process is an in-line process.

Abstract translation: 本文讨论了粘合剂组合物，形成粘合剂组合物的过程和多层膜。 方法通常包括使烯烃单体与催化剂体系在聚合区内接触以在足以形成烯烃基聚合物的聚合条件下形成烯烃基聚合物，所述催化剂体系包含通常由下式表示的金属组分：MR _{X ; 其中M是过渡金属，R是卤素，烷氧基或烃基，并且x是过渡金属的化合价，其中所述催化剂体系进一步包括含有C 3键的内给体（ID） C 6 -C 6环醚：从聚合区中取出烯烃基聚合物; 和将烯烃基聚合物与官能化聚烯烃熔融共混以形成基于聚烯烃的粘合剂组合物，其中该方法是在线方法。}

公开(公告)号：WO2016049035A1

公开(公告)日：2016-03-31

申请号：PCT/US2015/051463

申请日：2015-09-22

Applicant: EQUISTAR CHEMICALS, LP

Inventor： BOTROS, Maged, G.

IPC: C09J123/06 ,  C08L23/06 ,  C08L51/06 ,  C08L23/22 ,  B32B27/32

CPC classification number: C09J123/06 ,  B32B7/12 ,  C08L23/06 ,  C08L23/22 ,  C08L51/06 ,  C08L2201/08 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2205/06 ,  C08L2207/062 ,  C09J5/00 ,  C09J7/00 ,  C09J7/28 ,  C09J151/06 ,  C09J2201/122 ,  C09J2400/163 ,  C09J2423/00 ,  C09J2423/04 ,  C09J2451/00

Abstract: A polyolefin-based composition made from or containing (A) a first polymer composition made from or containing a polyolefin grafted with an unsaturated monomer, (B) a second polymer composition made from or containing a polyethylene, and (C) a third polymer composition made from or containing (i) a first polyisobutylene and (ii) a second polyisobutylene. The first polyisobutylene has a Viscosity Average Molecular Weight (VAMWi), and the second polyisobutylene has a Viscosity Average Molecular Weight (VAMW2), wherein VAMWi ≠ VAMW2. The polyolefin-based composition is useful as an adhesives or a tie-layer adhesive composition for multi-layered structures. In particular, the composition is useful as an adhesive to bind a metal layer to a dissimilar substrate.

Abstract translation: 一种由（A）由或不含有接枝有不饱和单体的聚烯烃制成或含有的第一聚合物组合物制成的聚烯烃基组合物，（B）由聚乙烯制成或含有聚乙烯的第二聚合物组合物，和（C）第三聚合物组合物 由（i）第一聚异丁烯和（ii）第二聚异丁烯制成或含有。 第一聚异丁烯具有粘度平均分子量（VAMWi），第二聚异丁烯具有粘度平均分子量（VAMW2），其中VAMWi≠VAMW2。 聚烯烃基组合物可用作多层结构的粘合剂或粘结层粘合剂组合物。 特别地，该组合物可用作将金属层结合到不同基材上的粘合剂。

公开(公告)号：WO2013032932A1

公开(公告)日：2013-03-07

申请号：PCT/US2012/052346

申请日：2012-08-24

Applicant: EQUISTAR CHEMICALS, LP ,  BOTROS, Maged, G.

Inventor： BOTROS, Maged, G.

IPC: B32B27/08 ,  B32B37/00 ,  B29C47/06

CPC classification number: B32B27/08 ,  B29C47/0004 ,  B29C47/0026 ,  B29C47/0057 ,  B29C47/065 ,  B29K2023/16 ,  B29K2221/003 ,  B29K2223/065 ,  B32B7/00 ,  B32B7/005 ,  B32B7/04 ,  B32B7/10 ,  B32B7/12 ,  B32B9/00 ,  B32B25/00 ,  B32B25/08 ,  B32B25/16 ,  B32B27/00 ,  B32B27/06 ,  B32B27/28 ,  B32B27/306 ,  B32B27/32 ,  B32B27/327 ,  B32B27/34 ,  B32B2274/00 ,  B32B2307/514 ,  B32B2307/736 ,  B32B2439/70 ,  C08L23/00 ,  C08L51/06 ,  Y10T428/3175 ,  Y10T428/31757 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31928 ,  Y10T428/31931 ,  Y10T428/31938

Abstract: An oriented multilayer structure for shrink applications having a polymeric layer, a tie layer adhered to said polymeric layer. The tie layer is made up of the reaction product of a live, grafted polyolefin and an olefin elastomer. The multilayer structure is oriented and the tie layer provides strong adhesion to barrier layers even at high orientation levels.

Abstract translation: 一种用于收缩应用的定向多层结构，其具有聚合物层，粘结层粘附到所述聚合物层。 连接层由活的，接枝的聚烯烃和烯烃弹性体的反应产物组成。 多层结构是取向的，并且连接层即使在高定向水平下也提供对阻挡层的强粘合性。

公开(公告)号：WO2012044776A1

公开(公告)日：2012-04-05

申请号：PCT/US2011/053897

申请日：2011-09-29

Applicant: EQUISTAR CHEMICALS, LP ,  BOTROS, Maged, G.

Inventor： BOTROS, Maged, G.

IPC: B32B27/32 ,  C08L23/08 ,  C08F255/02 ,  C08F291/02 ,  B32B7/10 ,  C09J123/08

CPC classification number: C09J7/0292 ,  B32B7/12 ,  B32B27/08 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/34 ,  B32B2250/05 ,  B32B2250/24 ,  B32B2250/246 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/412 ,  B32B2307/7242 ,  B32B2439/70 ,  C08F255/02 ,  C08F291/02 ,  C08L23/0815 ,  C08L23/16 ,  C08L51/003 ,  C08L51/04 ,  C08L51/06 ,  C08L2205/03 ,  C09J5/00 ,  C09J7/28 ,  C09J7/29 ,  C09J123/06 ,  C09J123/0815 ,  C09J123/16 ,  Y10T428/13 ,  Y10T428/2804 ,  Y10T428/31692 ,  Y10T428/31913 ,  Y10T428/31917 ,  Y10T428/31924 ,  Y10T428/31938 ,  C08F222/06

Abstract: Tie-layer adhesives having graft compositions for bonding to metal substrates is disclosed. The graft compositions are made up of the reaction product of a live, grafted polyolefin and an olefin elastomer. The grafted polyolefin is first made by heating a polyolefin and an unsaturated monomer. Further reaction of the live, grafted polyolefin with an olefin elastomer provides the graft composition. Grafting efficiency is boosted dramatically by the presence of the olefin elastomer and use of the additional reaction step. The graft composition, when formulated into a tie-layer adhesive provides improved bonding to metal substrates.

Abstract translation: 公开了具有用于粘合到金属基底的接枝组合物的粘合层粘合剂。 接枝组合物由活性，接枝聚烯烃和烯烃弹性体的反应产物组成。 接枝聚烯烃首先通过加热聚烯烃和不饱和单体制备。 活性接枝聚烯烃与烯烃弹性体的进一步反应提供了接枝组合物。 接枝效率由烯烃弹性体的存在和额外的反应步骤的使用显着提高。 接枝组合物配制成粘结层粘合剂时，可以改善与金属基材的接合性。

公开(公告)号：WO2003066783A1

公开(公告)日：2003-08-14

申请号：PCT/US2002/025247

申请日：2002-08-08

Applicant: EQUISTAR CHEMICALS, LP

Inventor： BOTROS, Maged, G.

IPC: C10L1/14

CPC classification number: C10L1/146 ,  C10L1/1973 ,  C10L1/2364

Abstract: Improved fuel additives and distillate fuels containing said additives are described. The additives impart improved low temperature flow and filterability and also impart stability to distillate fuels, particularly hard-to-treat distillate fuels. The additives are a combination of an olefin/vinyl carboxylate polymer and two specific polyimides having different alkyl substituent.

Abstract translation: 描述了含有所述添加剂的改进的燃料添加剂和馏出燃料。 添加剂赋予改善的低温流动性和过滤性，并且还赋予馏出燃料，特别是难以处理的馏出燃料的稳定性。 添加剂是烯烃/羧酸乙烯酯聚合物和具有不同烷基取代基的两种特定聚酰亚胺的组合。

公开(公告)号：WO2015057856A1

公开(公告)日：2015-04-23

申请号：PCT/US2014/060720

申请日：2014-10-15

Applicant: EQUISTAR CHEMICALS, LP

Inventor： BOTROS, Maged, G.

IPC: C08L51/00 ,  C08L23/04 ,  C08L23/16 ,  C08L29/04 ,  C08L77/00

CPC classification number: C09J123/0815 ,  C08F255/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/16 ,  C08L51/06 ,  C08L2203/16 ,  C08L2205/035 ,  C08L2207/062 ,  C08L2207/07 ,  Y10T428/2878 ,  C08F222/06

Abstract: The present disclosure provides a polyolefin-based composition, suitable for use as a tie-layer adhesive composition, and a process for making the polyolefin-based composition. The polyolefin-based composition is made from and/or contains a grafted polyolefin copolymer composition, a base resin composition, and optionally, an additives composition. The grafted polyolefin copolymer composition is made from and/or contains a grafted polyolefin composition, an olefin elastomer composition, and a long-chain branched polyolefin composition. The grafted polyolefin is coupled to the olefin elastomer and the long-chain branched polyolefin.

Abstract translation: 本公开内容提供了适合用作粘结层粘合剂组合物的聚烯烃基组合物以及制备聚烯烃基组合物的方法。 聚烯烃基组合物由和/或含有接枝聚烯烃共聚物组合物，基础树脂组合物和任选的添加剂组合物制成。 接枝聚烯烃共聚物组合物由和/或包含接枝聚烯烃组合物，烯烃弹性体组合物和长支链聚烯烃组合物制成。 接枝聚烯烃与烯烃弹性体和长支链聚烯烃偶合。