SULPHUR CONTAINING HIGH REFRACTIVE INDEX MONOMER

    公开(公告)号:WO2014072995A3

    公开(公告)日:2014-05-15

    申请号:PCT/IN2013/000659

    申请日:2013-10-30

    Abstract: This invention discloses aromatic based sulfur containing hydrophobic acrylate monomer with high refractive index. The invention further discloses process for the preparation of 2-phenyl-2-(phenylthio)ethyl acrylate of the formula (I). This monomer can be polymerized to take the form of an optical products having high refractive index. Optical products made from this monomer having high refractive index can be thinner and provide same refractive power as product made from a material having a relatively low refractive index. In particular the polymeric material prepared from the novel monomer can be used for making intraocular lenses that are thinner than the conventionally used ones offering advantages of reduced volume of space and light weight materials.

    SULPHUR CONTAINING HIGH REFRACTIVE INDEX MONOMER
    26.
    发明申请
    SULPHUR CONTAINING HIGH REFRACTIVE INDEX MONOMER 审中-公开
    含高折射率单体的硫

    公开(公告)号:WO2014072995A2

    公开(公告)日:2014-05-15

    申请号:PCT/IN2013000659

    申请日:2013-10-30

    CPC classification number: C07C323/12 C07C323/16 C08F220/38

    Abstract: This invention discloses aromatic based sulfur containing hydrophobic acrylate monomer with high refractive index. The invention further discloses process for the preparation of 2-phenyl-2-(phenylthio)ethyl acrylate of the formula (I). This monomer can be polymerized to take the form of an optical products having high refractive index. Optical products made from this monomer having high refractive index can be thinner and provide same refractive power as product made from a material having a relatively low refractive index. In particular the polymeric material prepared from the novel monomer can be used for making intraocular lenses that are thinner than the conventionally used ones offering advantages of reduced volume of space and light weight materials.

    Abstract translation: 本发明公开了具有高折射率的含芳族硫的疏水性丙烯酸酯单体。 本发明进一步公开了制备式(I)的2-苯基-2-(苯硫基)乙酯的方法。 该单体可以聚合成具有高折射率的光学产品的形式。 由这种具有高折射率的单体制成的光学产品可以更薄并且提供与由具有相对低折射率的材料制成的产品相同的折射能力。 特别地,由新单体制备的聚合物材料可用于制造比常规使用的具有减小的空间体积和轻质材料优点的薄的人工晶状体。

    STABLE HOMOGENEOUSLY MIXED NANOSCALE COATINGS DERIVED FROM UNIQUE MULTI-FUNCTIONAL AND MULTIDENTATE AROMATIC ADSORBATES
    27.
    发明申请
    STABLE HOMOGENEOUSLY MIXED NANOSCALE COATINGS DERIVED FROM UNIQUE MULTI-FUNCTIONAL AND MULTIDENTATE AROMATIC ADSORBATES 审中-公开
    稳定的均匀的多功能和多功能芳族吸收剂混合的纳米涂料

    公开(公告)号:WO2013134520A1

    公开(公告)日:2013-09-12

    申请号:PCT/US2013/029643

    申请日:2013-03-07

    CPC classification number: C07C323/20 C07C319/02 C07D213/32 C09D4/00 C09D5/00

    Abstract: Novel tridentate-, bidentate-, and monodentate-based aromatic adsorbates including self-assembled monolayers (SAMs), especially, mixed multi-component SAMs, where the adsorbates comprise an aromatic ring including one head group or a plurality of dentate head groups and one tunable tail group or a plurality of tail groups and methods for making the same, and methods for using same, their use in the preparation of homogeneously mixed multi-component self-assembled monolayers (SAMs). The adsorbants and SAMs derived therefrom are ideally suited for biosensing, biosensing diagnostics, biological interfacial mimics, surface protections for nanoparticles, inert coatings for artificial implants, and corrosion-resistant coatings for microelectronics components.

    Abstract translation: 包括自组装单层(SAM)的新型三齿,二齿和单齿芳族吸附物,特别是混合多组分SAM,其中吸附物包括一个包括一个头基团或多个齿状头基团的芳环,一个 可调尾组或多个尾组及其制备方法及其使用方法,它们用于制备均匀混合的多组分自组装单层(SAM)。 从其衍生的吸附剂和SAM理想地适用于生物传感,生物传感诊断,生物界面模拟物,纳米颗粒的表面保护,人造植入物的惰性涂层和微电子部件的耐腐蚀涂层。

    LINKER ARMS FOR NANOCRYSTALS AND COMPOUNDS THEREOF
    30.
    发明申请
    LINKER ARMS FOR NANOCRYSTALS AND COMPOUNDS THEREOF 审中-公开
    关于纳米晶体及其化合物的链接

    公开(公告)号:WO0190716A3

    公开(公告)日:2002-04-04

    申请号:PCT/US0116739

    申请日:2001-05-24

    Abstract: This invention generally relates to nanocrystal compounds, and linker arm for nanocrystal compounds that attach the nanocrystals to the organic compounds. The nanocrystal compound comprises a nanocrystal, linker arm, and organic compound. Preferably, the organic compound is a biologically active compound that can provide a fluorescent sensor. Preferably, the linker arm is a polyether chain with an attachment point for the nanocrystal and an attachment point for the organic compound. Specifically, the nanocrystal is attached to the linker arm through a R group and the organic compound is attached to the linker arm through a R2 group.R is a bond or is selected from the group consisting of: SH, O(CH2(n)O)nSH, NH(CH2(n)O)nSH, NH(CH2(n)NH)SH, S(CH2(n)O)nSH, and S(CH2(n)S)SH. n is 1-10, with S being attached to the nanocrystal. R2 is a bond or selected from the group consisting of carbonyl, NH, S, CONH, COO, S, C1-10 alkyl, carbamate, and thiocarbamate.

    Abstract translation: 本发明一般涉及将纳米晶体附着到有机化合物上的纳米晶体化合物和用于纳米晶体化合物的连接臂。 纳米晶体化合物包括纳米晶体,连接臂和有机化合物。 优选地,有机化合物是可以提供荧光传感器的生物活性化合物。 优选地,连接臂是具有纳米晶体的附着点和有机化合物的附着点的聚醚链。 具体地,纳米晶体通过R基团连接到连接臂上,有机化合物通过R 2基团连接到连接臂上.R是键或选自:SH,O(CH 2(n) O)nSH,NH(CH 2(n)O)n SH,NH(CH 2(n)NH)SH,S(CH 2(n)O)n SH和S(CH 2(n) n是1-10,其中S连接到纳米晶体上。 R2是选自羰基,NH,S,CONH,COO,S,C 1-10烷基,氨基甲酸酯和硫代氨基甲酸酯的键。

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