SYNTHESIS OF SILICOALUMINOPHOSPHATES
    31.
    发明申请
    SYNTHESIS OF SILICOALUMINOPHOSPHATES 审中-公开
    硅烷基磷酸酯的合成

    公开(公告)号:WO2003106343A1

    公开(公告)日:2003-12-24

    申请号:PCT/US2003/012713

    申请日:2003-04-24

    IPC分类号: C01B37/08

    摘要: The invention is directed to a method of synthesising silicoaluminophosphate molecular sieves using synthesis templates that contain at least one dimethylamino moiety, selected from one or more of the following; N,N-dimethylethanolamine, N,N-dimethylpropanolamine, N,N-dimethylbutanolamine, N,N-dimethylheptanolamine, N,N-dimethylhexanolamine, N,N-dimethylethylenediamine, N,N-dimethylbutylenediamine, N,N-dimethylheptylenediamine, N,N-dimethylhexylenediamine 1-dimethylamino-2-propanol, N,N-dimethylethylamine, N,N-dimethylpropylamine, N,N-dimethylpentylamine, N,N-dimethylhexylamine or N,N-dimethylheptylamine. The use of dimethylamino moiety containing templates results in good quality SAPO molecular sieves of CHA framework type.

    摘要翻译: 本发明涉及使用含有至少一个选自以下一种或多种的二甲基氨基部分的合成模板合成硅铝磷酸盐分子筛的方法; N,N-二甲基乙醇胺,N,N-二甲基丙醇胺,N,N-二甲基丁醇胺,N,N-二甲基庚醇胺,N,N-二甲基己醇胺,N,N-二甲基乙二胺,N,N-二甲基丁二胺,N, N-二甲基己二胺1-二甲基氨基-2-丙醇,N,N-二甲基乙胺,N,N-二甲基丙胺,N,N-二甲基戊胺,N,N-二甲基己胺或N,N-二甲基庚胺。 使用含二甲氨基部分的模板产生优质的CHA骨架类型的SAPO分子筛。

    SYNTHESIS OF A CRYSTALLINE SILICOALUMINOPHOSPHATE
    33.
    发明申请
    SYNTHESIS OF A CRYSTALLINE SILICOALUMINOPHOSPHATE 审中-公开
    一种晶体硅烷基磷酸盐的合成

    公开(公告)号:WO1991013132A1

    公开(公告)日:1991-09-05

    申请号:PCT/US1990001162

    申请日:1990-03-01

    IPC分类号: C10G65/12

    摘要: A silicoaluminophosphate molecular sieve is disclosed and is characterized in that the P2O5 to alumina mole ratio at the surface is about 0.80 or less, the P2O5 to alumina mole ratio of the bulk is 0.96 or greater and the silicon content at the surface is greater than that of the bulk.

    摘要翻译: 公开了硅铝磷酸盐分子筛,其特征在于表面处的P 2 O 5与氧化铝的摩尔比为约0.80以下,体积的P2O5与氧化铝的摩尔比为0.96以上,表面的硅含量大于 的大量。

    SILICOALUMINOPHOSPHATE CATALYST FOR CHLOROMETHANE CONVERSION
    35.
    发明申请
    SILICOALUMINOPHOSPHATE CATALYST FOR CHLOROMETHANE CONVERSION 审中-公开
    用于氯甲烷转化的硅铝磷酸盐催化剂

    公开(公告)号:WO2016099775A8

    公开(公告)日:2017-05-18

    申请号:PCT/US2015061344

    申请日:2015-11-18

    IPC分类号: B01J29/85 C07C11/02

    摘要: Disclosed is a catalyst capable of producing an olefin from an alkyl halide, the catalyst comprising a silicoaluminophosphate (SAPO) having a chabazite zeolite structure with the following chemical composition (SixAlyPz)O2, where x, y, and z represent the mole fractions of silicon, aluminum, and phosphorus, respectively, present as tetrahedral oxides, x is 0.01 to 0.30 and the sum of x + y + z is 1, and where the catalyst comprises silicon tetrahedral oxides that are connected with three or less aluminum tetrahedral oxide as shown by 29Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy peak(s) with peak(s) maxima between -93 ppm and -115 ppm.

    摘要翻译: 公开了能够由烷基卤生产烯烃的催化剂,所述催化剂包含具有以下化学组成(SixAlyPz)O 2的菱沸石沸石结构的硅铝磷酸盐(SAPO),其中x,y和z代表硅的摩尔分数 ,铝和磷,分别以四面体氧化物存在,x为0.01至0.30,x + y + z之和为1,并且其中催化剂包含如图所示与三个或更少的铝四面体氧化物连接的硅四面体氧化物 通过具有在-93ppm和-115ppm之间的峰值最大值的29Si魔角旋转(MAS)核磁共振(NMR)光谱峰来确定。

    SILICOALUMINOPHOSPHATE CATALYST FOR CHLOROMETHANE CONVERSION
    38.
    发明申请
    SILICOALUMINOPHOSPHATE CATALYST FOR CHLOROMETHANE CONVERSION 审中-公开
    用于氯乙烯转化的硅烷基磷酸酯催化剂

    公开(公告)号:WO2016099775A1

    公开(公告)日:2016-06-23

    申请号:PCT/US2015/061344

    申请日:2015-11-18

    IPC分类号: B01J29/85 C07C11/02

    摘要: Disclosed is a catalyst capable of producing an olefin from an alkyl halide, the catalyst comprising a silicoaluminophosphate (SAPO) having a chabazite zeolite structure with the following chemical composition (Si x Al y P z )O 2 , where x, y, and z represent the mole fractions of silicon, aluminum, and phosphorus, respectively, present as tetrahedral oxides, x is 0.01 to 0.30 and the sum of x + y + z is 1, and where the catalyst comprises silicon tetrahedral oxides that are connected with three or less aluminum tetrahedral oxide as shown by 29 Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy peak(s) with peak(s) maxima between -93 ppm and -115 ppm.

    摘要翻译: 公开了一种能够由烷基卤化物生产烯烃的催化剂,该催化剂包含具有以下化学成分(SixAlyPz)O 2的菱沸石沸石结构的硅铝磷酸盐(SAPO),其中x,y和z表示硅的摩尔分数 ,铝和磷分别以四面体氧化物存在,x为0.01〜0.30,x + y + z的和为1,其中催化剂包含四面体氧化物,其与三个或更少的四面体氧化铝连接,如图所示 通过29Si魔角旋转(MAS)核磁共振(NMR)光谱峰(s),峰(s)最大值在-93ppm和-115ppm之间。

    ALUMINOPHOSPHATE MOLECULAR SIEVES USING AN ORGANO-1-OXA-4-AZONIUMCYCLOHEXANE COMPOUND
    39.
    发明申请
    ALUMINOPHOSPHATE MOLECULAR SIEVES USING AN ORGANO-1-OXA-4-AZONIUMCYCLOHEXANE COMPOUND 审中-公开
    使用有机基-1-氧代-4-亚氨基半乳糖苷化合物的二磷酸分子筛

    公开(公告)号:WO2016089728A1

    公开(公告)日:2016-06-09

    申请号:PCT/US2015/062906

    申请日:2015-11-30

    申请人: UOP LLC

    IPC分类号: C01B39/54

    摘要: A method for synthesizing an aluminophosphate based molecular sieve is described. The method may include the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon, and a 1-oxa-4-azacyclohexane derivative; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organo-1-oxa-4-azoniumcyclohexane compound; (d) forming a reaction mixture comprising reactive sources of Al, and P, and the solution; and (e) heating the reaction mixture to form the molecular sieve.

    摘要翻译: 描述了一种用于合成基于磷酸铝的分子筛的方法。 该方法可以包括以下步骤:(a)制备含水,取代的烃和1-氧杂-4-氮杂环己烷衍生物的含水混合物; (b)使含水混合物反应; (c)得到包含有机-1-氧杂-4-氮鎓环己烷化合物的溶液; (d)形成包含Al和P的反应源和所述溶液的反应混合物; 和(e)加热反应混合物以形成分子筛。