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    ISOLATING SEMICONDUCTING SINGLE-WALLED NANOTUBES OR METALLIC SINGLE-WALLED NANOTUBES AND APPROACHES THEREFOR
    41.
    发明申请
    ISOLATING SEMICONDUCTING SINGLE-WALLED NANOTUBES OR METALLIC SINGLE-WALLED NANOTUBES AND APPROACHES THEREFOR 审中-公开
    分离半导体单壁纳米管或金属单壁纳米管及其方法

    公开(公告)号：WO2016154468A1

    公开(公告)日：2016-09-29

    申请号：PCT/US2016/024072

    申请日：2016-03-24

    Applicant: THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY

    Inventor： BAO, Zhenan ,  POCHOROVSKI, Igor

    IPC: D01F9/12 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  H01B1/04

    CPC classification number: C01B31/0266 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/22 ,  C08F136/20 ,  H01C7/00

    Abstract: Embodiments in accordance with the present disclosure include methods, polymers, and complexes. For example, a method embodiments includes providing a solution including a disassembled supramolecular polymer and a bond disrupting agent, adding an antisolvent to the solution to precipitate the supramolecular polymer, and isolating the precipitated supramolecular polymer from the bond disrupting agent. The isolated supramolecular polymer is configured to selectively disperse single-walled carbon nanotubes (SWNTs) of a particular electrical type from a SWNT mixture including SWNTS of at least two electrical types.

    Abstract translation: 根据本公开的实施方案包括方法，聚合物和配合物。 例如，方法实施方案包括提供包括分解的超分子聚合物和键断裂剂的溶液，向溶液中加入反溶剂以沉淀超分子聚合物，并从沉淀的超分子聚合物与键断裂剂分离。 隔离的超分子聚合物被配置为从包括至少两种电气类型的SWNTS的SWNT混合物中选择性分散特定电气类型的单壁碳纳米管（SWNT）。

    METHODS OF ENRICHING DIFFERENT SPECIES OF CARBON NANOTUBES
    42.
    发明申请
    METHODS OF ENRICHING DIFFERENT SPECIES OF CARBON NANOTUBES 审中-公开
    增加碳纳米管不同物种的方法

    公开(公告)号：WO2013062488A1

    公开(公告)日：2013-05-02

    申请号：PCT/SG2012/000404

    申请日：2012-10-25

    Applicant: NANYANG TECHNOLOGICAL UNIVERSITY

    Inventor： CHAN, Bee Eng Mary ,  SUNDRAMOORTHY, Ashok Kumar

    IPC: C01B31/02 ,  B82Y40/00 ,  B82B3/00 ,  H01L21/335 ,  H01L29/772

    CPC classification number: C01B31/0273 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/172 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/22 ,  Y10S977/845

    Abstract: A method of enriching specific species of carbon nanotubes by exposing a composition of carbon nanotubes to an azo compound is provided. The method includes a) mixing the azo compound with a suspension comprising the composition of carbon nanotubes to form a mixture; b) incubating the mixture to react the azo compound with the carbon nanotubes; and c) separating a supernatant and a precipitate formed in the mixture. An electrode and a field-effect transistor comprising a single-walled carbon nanotube species enriched using the method are also provided.

    Abstract translation: 提供了通过将碳纳米管组合物暴露于偶氮化合物来富集碳纳米管的特定种类的方法。 该方法包括：a）将偶氮化合物与包含碳纳米管组合物的悬浮液混合以形成混合物; b）孵育混合物以使偶氮化合物与碳纳米管反应; 和c）分离上清液和在混合物中形成的沉淀物。 还提供了包括使用该方法富集的单壁碳纳米管物质的电极和场效应晶体管。

    METHOD AND KIT FOR SEPARATING METAL AND SEMICONDUCTOR CARBON NANOTUBES
    47.
    发明申请
    METHOD AND KIT FOR SEPARATING METAL AND SEMICONDUCTOR CARBON NANOTUBES 审中-公开
    用于分离金属和半导体碳纳米管的方法和试剂盒

    公开(公告)号：WO2010089395A3

    公开(公告)日：2010-10-07

    申请号：PCT/EP2010051510

    申请日：2010-02-08

    Applicant: COMMISSARIAT ENERGIE ATOMIQUE ,  CHENEVIER PASCALE

    Inventor： CHENEVIER PASCALE

    IPC: C01B31/02

    CPC classification number: B82Y30/00 ,  B82Y40/00 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/22 ,  C01B2202/34 ,  C01B2202/36

    Abstract: The present invention relates to a method for separating metal carbon nanotubes with a single layer of graphene (m-SWNT) and semiconductor nanotubes with a single layer of graphene (sc-SWNT) including a step of grafting, in particular by the radical chemical grafting of a diazonium salt by-product on a mixture of m-SWNTs and sc-SWNTs so as to obtain a mixture of grafted m-SWNTs and non-grafted sc-SWNTs, by means of which the grafted m-SWNTs and non-grafted sc-SWNTs are separated due to differential chemical and/or physical properties caused by said grafting. The present invention also relates to a kit for separating m-SWNTs and sc-SWNTs.

    Abstract translation: 本发明涉及用单层石墨烯（m-SWNT）和具有单层石墨烯（sc-SWNT）的半导体纳米管分离金属碳纳米管的方法，其包括接枝步骤，特别是通过自由基化学接枝 的重氮盐副产物在m-SWNTs和sc-SWNTs的混合物上以获得接枝的m-SWNTs和未接枝的sc-SWNTs的混合物，通过该混合物接枝的m-SWNTs和未接枝的m- 由于所述接枝引起的差异化学和/或物理性质，sc-SWNT分离。 本发明还涉及用于分离m-SWNT和sc-SWNT的试剂盒。

    SEPARATION OF CARBON NANOTUBE BUNDLES VIA INTERFACIAL TRAPPING
    49.
    发明申请
    SEPARATION OF CARBON NANOTUBE BUNDLES VIA INTERFACIAL TRAPPING 审中-公开
    碳纳米管束通过界面俘获分离

    公开(公告)号：WO2009036354A3

    公开(公告)日：2009-05-14

    申请号：PCT/US2008076272

    申请日：2008-09-12

    Applicant: UNIV FLORIDA ,  WANG KAI-WEI ,  REEVES RYAN DAVID ,  ZIEGLER KIRK JEREMY

    Inventor： WANG KAI-WEI ,  REEVES RYAN DAVID ,  ZIEGLER KIRK JEREMY

    IPC: B82B3/00

    CPC classification number: B82Y30/00 ,  B82Y40/00 ,  C01B32/172 ,  C01B32/174 ,  C01B2202/28

    Abstract: In embodiments of the invention, bundles of carbon nanotubes are separated from individual nanotubes via interfacial trapping of bundled carbon nanotube bundles at an emulsion interface between suspension-phase and a solution-phase. The separation method comprises dispersing a mixture of individual and bundled carbon nanotubes in a solution comprising surfactant; adding at least one solvent to the surfactant solution to form a two- phase mixture; agitating the two-phase mixture to form an emulsion interface between the solution-phase and a suspension-phase, where nanotube bundles selectively segregate to the emulsion interface. Single-walled carbon nanotube suspensions exhibit strong fluorescence, which can be used to assess the degree of separation and determine if a repeated extraction of any remaining bundled carbon nanotubes remaining in the suspension-phase is desired. In another embodiment of the invention, separation of carbon nanotubes by type is carried out by interfacial trapping.

    Abstract translation: 在本发明的实施方案中，通过在悬浮相和溶液相之间的乳液界面处捆绑的碳纳米管束的界面俘获，碳纳米管束与单独的纳米管分离。 分离方法包括将单独和成束的碳纳米管的混合物分散在包含表面活性剂的溶液中; 向表面活性剂溶液中加入至少一种溶剂以形成两相混合物; 搅拌两相混合物以在溶液相和悬浮液相之间形成乳液界面，其中纳米管束选择性地分离到乳液界面。 单壁碳纳米管悬浮液表现出强烈的荧光，其可用于评估分离程度并确定是否需要重复提取任何剩余的悬浮相中剩余的束状碳纳米管。 在本发明的另一个实施方案中，按类型分离碳纳米管是通过界面捕获进行的。

    METHODS FOR FORMING FREESTANDING NANOTUBE OBJECTS AND OBJECTS SO FORMED
    50.
    发明申请
    METHODS FOR FORMING FREESTANDING NANOTUBE OBJECTS AND OBJECTS SO FORMED 审中-公开
    形成新型纳米材料的方法和形成的物体

    公开(公告)号：WO2008097275A3

    公开(公告)日：2009-04-16

    申请号：PCT/US2007019190

    申请日：2007-08-30

    Applicant: MOLECULAR NANOSYSTEMS INC ,  PAN LAWRENCE ,  FORNACIARI BERT

    Inventor： PAN LAWRENCE ,  FORNACIARI BERT

    IPC: D01F9/12 ,  B82B1/00 ,  B82B3/00

    CPC classification number: B82Y40/00 ,  B81C99/008 ,  B82Y30/00 ,  C01B32/162 ,  C01B32/172 ,  C01B2202/08 ,  Y10T428/24

    Abstract: Methods for forming freestanding objects primarily comprising aligned carbon nanotubes, as well as the objects made by these methods, are provided. Arrays of generally aligned carbon nanotubes are first synthesized on a substrate then released from the substrate and densified, maintaining the aligned arrangement. These densified arrays can take the form of thin strips which can be joined together, for example by lamination, to form larger objects of arbitrary size. These objects can be further cut or otherwise machined to desired dimensions and shapes. Release from the substrate can be accomplished mechanically, such as by shearing, or chemically, such as by etching. Densification can be accomplished, for example, through compaction or by taking advantage of capillary forces. In the latter case, an array is first wetted with a fluid and then dried. As the fluid is removed, capillary forces draw the nanotubes closer together.

    Abstract translation: 提供了主要包括对准的碳纳米管的独立物体的形成方法以及由这些方法制成的物体。 一般排列的碳纳米管的阵列首先在衬底上合成，然后从衬底上释放并致密化，保持对准的布置。 这些致密化的阵列可以采用薄带的形式，其可以例如通过层压连接在一起，以形成任意尺寸的较大物体。 这些物体可以进一步切割或以其它方式加工成所需的尺寸和形状。 例如通过剪切或化学方法，例如通过蚀刻，可以机械地实现从衬底的释放。 致密化可以例如通过压实或利用毛细管力来实现。 在后一种情况下，首先用流体润湿阵列然后干燥。 当流体被去除时，毛细管力将纳米管拉近。

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