POLYHYDROXYL/PHOSPHATE COPOLYMERS AND COMPOSITIONS CONTAINING THE SAME
    63.
    发明申请
    POLYHYDROXYL/PHOSPHATE COPOLYMERS AND COMPOSITIONS CONTAINING THE SAME 审中-公开
    聚羟基/磷酸酯共聚物及其组合物

    公开(公告)号:WO01004250A1

    公开(公告)日:2001-01-18

    申请号:PCT/US1999/015682

    申请日:1999-07-12

    摘要: A polyhydroxyl/phosphate polymer comprising a polyhydroxy moiety and a phosphorous moiety. This polymer is of general structure (I) wherein: each Z is independently selected from the group consisting of H, a, b, c and d; each Q is independently selected from the group consisting of e, and M; each X is independently selectected from the group consisting of M, and f; each M is independently selected from the group consisting of H, Na, K, -OCH2CH2SO3Na, -OCH2CH2N(CH3)3Cl and NH4 ; each R is independently selected from the group consisting of C2 to C22 alkyl alcohol. In this polymer at least about 10 %, by weight of the polyhydroxyl/phosphate polymer is phosphorous, at least about 1 %, by weight of the polyhydroxyl/phosphate polymer is carbon. Further the polyhydroxyl/phosphate polymer has an average molecular weight of at least about 600. Detergent and oral care compositions having these polyhydroxyl/phosphate polymers are also disclosed.

    摘要翻译: 包含多羟基部分和磷部分的多羟基/磷酸酯聚合物。 该聚合物具有通式结构(I),其中:Z各自独立地选自H,a,b,c和d; 每个Q独立地选自e和M组成的组; 每个X独立地选自由M和f组成的组; 每个M独立地选自H,Na,K,-OCH 2 CH 2 SO 3 Na,-OCH 2 CH 2 N(CH 3)3 Cl和NH 4 +; 每个R独立地选自C 2至C 22烷基醇。 在该聚合物中,至少约10重量%的多羟基/磷酸酯聚合物是磷,至少约1重量%的多羟基/磷酸酯聚合物是碳。 此外,多羟基/磷酸酯聚合物的平均分子量至少为约600.还公开了具有这些多羟基/磷酸酯聚合物的洗涤剂和口腔护理组合物。

    PHOSPHINIMINE MODIFICATION OF ORGANIC POLYMERS AND SILICONES
    64.
    发明申请
    PHOSPHINIMINE MODIFICATION OF ORGANIC POLYMERS AND SILICONES 审中-公开
    有机聚合物和硅氧烷的磷酰胺改性

    公开(公告)号:WO00071589A1

    公开(公告)日:2000-11-30

    申请号:PCT/US2000/013537

    申请日:2000-05-18

    摘要: Methods have been developed top roduce phosphazene modified organic or siloxane polymers. The method includes: (a) providing an organic or siloxane polymer comprising phosphine units; and (b) reacting the organic or siloxane polymer with a phosphazene azide compound under conditions wherein the phosphazene azide compound is bound to the phosphine units in the polymer, thereby producing the phosphazene-modified organic or siloxane polymer. The organic polymer of step (a) is produced by reacting a first monomer comprising phosphine with a second monomer via free radical or anionic polymerization techniques to produce the organic polymer comprising phosphine units. The first and second monomers can be identical. A wide variety of organic polymer backbones can be modified using these techniques. The second monomer, for example, can be selected from monomers forming polyolefins, polydienes, polyacrylics, polyethylenes, polyvinyl chlorides, polyisoprenes, polystyrenes, polycaprolactam, poly(methyl)(meth)acrylates, and polypropylenes. Alternatively, the siloxane polymer of step (a) is produced by reacting a monomer comprising phosphine with a hydrosilicone polymer via hydrosilylation polymerization techniques to produce the siloxane polymer comprising phosphine units. These phosphazene modified organic and siloxane polymers are useful in a variety of applications, particularly as a fire retardant material.

    摘要翻译: 已经开发了方法,研究了磷腈改性有机或硅氧烷聚合物。 该方法包括:(a)提供包含磷化氢单元的有机或硅氧烷聚合物; 和(b)在叠氮化磷化合物与聚合物中的膦单元结合的条件下使有机或硅氧烷聚合物与磷氮杂叠氮化合物反应,从而制备磷腈改性的有机或硅氧烷聚合物。 步骤(a)的有机聚合物通过使自由基或阴离子聚合技术使包含膦的第一单体与第二单体反应制备包含磷化氢单元的有机聚合物来制备。 第一和第二单体可以相同。 使用这些技术可以改变各种各样的有机聚合物主链。 例如,第二单体可以选自形成聚烯烃,聚二烯,聚丙烯酸,聚乙烯,聚氯乙烯,聚异戊二烯,聚苯乙烯,聚己内酰胺,聚(甲基)(甲基)丙烯酸酯和聚丙烯的单体。 或者,步骤(a)的硅氧烷聚合物通过氢化硅烷化聚合技术使包含膦的单体与氢硅氧烷聚合物反应制备包含磷化氢单元的硅氧烷聚合物来制备。 这些磷腈改性的有机和硅氧烷聚合物可用于各种应用,特别是作为阻燃材料。

    BIFUNCTIONAL POLYMERS
    65.
    发明申请
    BIFUNCTIONAL POLYMERS 审中-公开
    双功能聚合物

    公开(公告)号:WO00059965A1

    公开(公告)日:2000-10-12

    申请号:PCT/IB1999/002101

    申请日:1999-12-22

    CPC分类号: D21H17/34 D21H21/18

    摘要: Novel polymers are provided having phosphonated and sulphonated substituent groups such that the polymer is multifunctional in its use. Optional amide substituents are used to reduce electrostatic charge density or for hydrogen bonding. An advantage of the polymer is the flexibility of using it for multiple purposes. A particular application is for bonding paper fillers and paper fiber together.

    摘要翻译: 提供了具有膦酸化和磺化取代基的新型聚合物,使得该聚合物在其使用中是多功能的。 使用任选的酰胺取代基来降低静电电荷密度或用于氢键合。 聚合物的优点是将其用于多种目的的灵活性。 特别的应用是将纸张填充物和纸纤维粘合在一起。

    PHOSPHATIZED AMINE CHAIN-EXTENDED EPOXY POLYMERIC COMPOUNDS
    66.
    发明申请
    PHOSPHATIZED AMINE CHAIN-EXTENDED EPOXY POLYMERIC COMPOUNDS 审中-公开
    磷酸胺链延长环氧聚合物

    公开(公告)号:WO99015570A1

    公开(公告)日:1999-04-01

    申请号:PCT/US1998/019723

    申请日:1998-09-21

    摘要: This invention provides a novel phosphatized polymeric product which is formed by: (a) forming an amine-extended resinous composition having unreacted epoxy groups by mixing, under free-radical initiated polymerization conditions, a polymerizable, ethylenically unsaturated monomeric component and a polyepoxide component; and (b) phosphatizing at least a portion of the unreacted epoxy groups of the resinous composition. The present invention also provides novel coating compositions containing the aforedescribed polymeric product. While these novel coating compositions have a number of different uses, they are particularly useful for application to metal substrates such as can end stock since they result in a cured film which has excellent performance properties such as flexibility and extensibility, adhesion, resistance to boiling liquid pack tests and boiling water taste test results.

    摘要翻译: 本发明提供了一种新型磷酸化聚合物产品,其通过以下步骤形成:(a)在自由基引发的聚合条件下,通过在可自由基引发的聚合条件下混合可聚合的烯属不饱和单体组分和聚环氧化物组分,形成具有未反应的环氧基团的胺延伸的树脂组合物; 和(b)使树脂组合物的至少一部分未反应的环氧基磷酸化。 本发明还提供了含有上述聚合物产品的新型涂料组合物。 虽然这些新型涂料组合物具有许多不同的用途,但是它们特别适用于金属基材如罐端料,因为它们产生具有优异性能的固化膜,例如柔韧性和延展性,粘合性,耐沸腾性 包装测试和沸水味道测试结果。

    SORPTION AGENT CONTAINING NUCLEOTIDE, FOR AFFINITY CHROMATOGRAPHY
    67.
    发明申请
    SORPTION AGENT CONTAINING NUCLEOTIDE, FOR AFFINITY CHROMATOGRAPHY 审中-公开
    NUKLEOTIDHALTIGES吸附剂的亲和色谱

    公开(公告)号:WO98046350A1

    公开(公告)日:1998-10-22

    申请号:PCT/EP1998/001880

    申请日:1998-04-01

    摘要: The invention relates to sorption agents for affinity chromatography on the basis of base carriers containing hydroxyl groups, polymers being covalent-bonded on the surfaces of said base carriers. According to the invention, the base carrier contains aliphatic hydroxyl groups, the covalent-bonded polymers are bonded to the base carrier via a terminal monomer unit, the monomer units are bonded linearly, and the polymers contain monomer units of formula (I) wherein R , R and R independently mean H or CH3, R means H, C1-C5 alkyl or C6-C12 aryl, n is a whole number between 1 and 5, and one of the radicals X is OH and the other radical Y is a radical containing nucleoside bonded via an alkylene radical. The invention also relates to the production and the use of the inventive sorption agents.

    摘要翻译: 本发明涉及基于含羟基的基的亲和色谱吸附剂支持在其表面的聚合物共价键合,其中:a)基材支撑包含脂族羟基基团)的共价键合的聚合物经由末端单体单元结合到基体支承B,C) 单体单元线性地连接,并且其中所述聚合物含有式(I)的单体单元,其中R <1>,R <2>和R <3>独立地voneiander H或CH 3,R <4>为H,C1-C5烷基或 C6-C12芳基,n是X是OH,另一个基团X是基团nucleosidhaltigen其经由亚烷基,以及它们的生产和使用结合图1和5和基团中的一个之间的整数。

    FLAME RETARDANT PRESSURE-SENSITIVE ADHESIVE AND METHOD OF MAKING

    公开(公告)号:WO2023073470A1

    公开(公告)日:2023-05-04

    申请号:PCT/IB2022/059781

    申请日:2022-10-12

    IPC分类号: C08F8/40 C08F220/18

    摘要: A method of making a (meth)acrylate copolymer having pendent phosphate-containing groups and a pressure-sensitive adhesive that contains the (meth)acrylate copolymer having pendent phosphate-containing groups are provided. The method includes reacting a precursor (meth)acrylate copolymer having pendent carboxylic acid groups with an epoxy-functionalized phosphate compound. The pendent phosphate-containing groups on the reaction product can function as a flame retardant for the pressure-sensitive adhesive.