摘要:
According to several exemplary embodiments of the present disclosure, a proppant composition is provided that includes a plurality of unconsolidated particulates having a resin coating on the surface of the particulates, such that chemically active amine sites remain on the surface of the proppant particulates. The proppant composition can remain unconsolidated under storage conditions, inside a wellbore, and inside a subterranean fracture in the absence of an activator. For example, the proppant composition can remain unconsolidated in a gravel pack region or frac pack region in a wellbore in the absence of an activator. According to several exemplary embodiments of the present invention, the proppant composition remains unconsolidated under storage conditions of temperatures of up to 150F, up to 100F, or up to 50F and atmospheric pressure from about one month to about eighteen months.
摘要:
Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.
摘要:
Electrically-conductive sintered, substantially round and spherical particles and methods for producing such electrically-conductive sintered, substantially round and spherical particles from an alumina-containing raw material. Methods for using such electrically-conductive sintered, substantially round and spherical particles in hydraulic fracturing operations. A proppant pack comprising: a plurality of particles, each said particle, comprising a substantially uniform coating of an electrically-conductive metal having a thickness of at least 10 nm formed on the outer surface of each said particle, wherein each particle has a specific gravity of less than 4 and a size of about 80 mesh to about 10 mesh, wherein the pack has an electrical conductivity of at least about 5 S/m, and wherein increasing a load on the pack by a factor of 2 increases the electrical conductivity of the pack by at least 50%.
摘要:
The present invention relates to methods for hydraulically fracturing a subterranean formation to improve the production rates and ultimate recovery by contacting unconsolidated resin-coated proppant particulates residing in a propped fracture with a reactive crosslinker in order to form a consolidated proppant pack. The present invention also relates to methods for use in water injection wells to consolidate the resin-coated proppant particulates in a gravel packed or frac packed region of a wellbore.
摘要:
Methods are provided for identifying the location and height of induced subterranean formation fractures and the presence of any associated frac-pack or gravel pack material in the vicinity of the borehole using pulsed neutron capture (PNC) logging tools. The proppant/sand used in the fracturing and packing processes is tagged with a thermal neutron absorbing material. When proppant is present, increases in detected PNC formation and/or borehole component cross-sections, combined with decreases in measured count rates, are used to determine the location of the formation fractures and the presence and percent fill of pack material in the borehole region. Changes in measured formation cross-sections relative to changes in other PNC parameters provide a relative indication of the proppant in fractures compared to that in the borehole region
摘要:
Foundry media having a low surface porosity and methods for producing the media are disclosed. One method includes minimizing a moisture content of the media prior to sintering the media, which minimized moisture content minimized the surface porosity of the sintered media. The media can be coated with resin, and a mold made therefrom. The media requires less resin than conventional media because of the low porosity, and stronger molds can be made from the media.
摘要:
Disclosed is a method for making a material having a controlled microstructure, the method including providing particles of a ceramic mineral material, the particles having a metal oxide dopant therein. The particles of the ceramic mineral material are consolidated into larger aggregates of a size relevant to the desired application using standard industrial mixing and pelletizing technology. The aggregates are heated under reducing conditions so that at least part of the dopant is reduced to form a transient, metastable liquid phase among the particles. The liquid phase includes at least part of the reduced dopant and promotes sintering of the particles and forms islands of reduced metal within the material and on the surface of the aggregates. Following heating of the aggregates under reducing conditions, the aggregates are heated under oxidizing conditions such that the islands of reduced metal are oxidized and/or go into solid solution within the particles, thereby creating voids within and form a shell thereon the particles.
摘要:
Sintered, spherical composite pellets having high strength and low density, are described, along with processes for their manufacture. One method includes forming a green pellet from a mixture of clay, bauxite or a clay-bauxite mixture with a sacrificial phase such that upon sintering of the pellet, the sacrificial phase is removed from the pellet. The use of such sintered pellets in hydraulic fracturing of subterranean formations is also described.
摘要:
Surface modified oil and gas well hydraulic fracturing proppants for improving wettability, altering chemical reactivity, altering surface topography, imparting lubrictiy or controlling relative permeability to flow of fluids of such proppants. The use and preparation of such coated proppants in hydraulic fracturing of subterranean formations is also described.