公开(公告)号：WO2009131942A1

公开(公告)日：2009-10-29

申请号：PCT/US2009/041130

申请日：2009-04-20

Applicant: BATTELLE MEMORIAL INSTITUTE ,  SPRENKLE, Vincent, L. ,  MEINHARDT, Kerry, D. ,  CHICK, Lawrence, A. ,  KIM, Jin, Yong

Inventor： SPRENKLE, Vincent, L. ,  MEINHARDT, Kerry, D. ,  CHICK, Lawrence, A. ,  KIM, Jin, Yong

IPC: B01J23/83 ,  B01J23/89 ,  C25B11/00 ,  H01M4/88 ,  H08M4/12

CPC classification number: H01M4/90 ,  B01J23/83 ,  B01J23/894 ,  H01M4/8885 ,  H01M4/9066 ,  H01M2008/1293

Abstract: Methods for improving the sulfur -tolerance of nickel-based catalyst systems, as well as the improved catalyst systems, are disclosed. The methods can include adding praseodymium alone, or in combination with ruthenium and/or cerium, to a nickel-based catalyst system, thereby inhibiting sulfur poisoning of the catalyst system. Improved catalyst systems can have an added amount of praseodymium alone, or in combination with ruthenium and/or cerium, sufficient to inhibit poisoning of the system by sulfur.

Abstract translation: 公开了改进镍基催化剂体系的耐硫性的方法以及改进的催化剂体系。 所述方法可以包括将镨单独添加或与钌和/或铈组合加入到镍基催化剂体系中，从而抑制催化剂体系的硫中毒。 改进的催化剂体系可以单独添加镨，或与钌和/或铈组合，足以抑制硫系统的中毒。

公开(公告)号：WO2010039436A1

公开(公告)日：2010-04-08

申请号：PCT/US2009/057186

申请日：2009-09-16

Applicant: BATTELLE MEMORIAL INSTITUTE ,  KIM, Jin, Yong ,  SPRENKLE, Vincent, L. ,  CANFIELD, Nathan ,  MEINHARDT, Kerry, D. ,  CHICK, Lawrence, A.

Inventor： KIM, Jin, Yong ,  SPRENKLE, Vincent, L. ,  CANFIELD, Nathan ,  MEINHARDT, Kerry, D. ,  CHICK, Lawrence, A.

IPC: H01M4/86 ,  H01M4/88 ,  H01M8/12

CPC classification number: H01M4/8885 ,  H01M4/8605 ,  H01M4/9033 ,  H01M4/905

Abstract: Lanthanum strontium cobalt iron oxides (La(1-x )SrxCoyFe1-yO3-ƒ; (LSCF) have excellent power density (>500 mW/cm2 at 750°C). When covered with a metallization layer, LSCF cathodes have demonstrated increased durability and stability. Other modifications, such as the thickening of the cathode, the preparation of the device by utilizing a firing temperature in a designated range, and the use of a pore former paste having designated characteristics and combinations of these features provide a device with enhanced capabilities.

Abstract translation: 镧锶钴铁氧化物（La（1-x）SrxCoyFe1-yO3-;（LSCF）具有优异的功率密度（750℃时> 500mW / cm2），当被金属化层覆盖时，LSCF阴极显示出增加的耐久性和 通过利用指定范围内的烧制温度制备器件，以及使用具有指定特征和这些特征的组合的成孔剂糊剂的其它修改例如阴极的增厚，以及使用具有增强的能力的器件 。

公开(公告)号：WO2007001380A2

公开(公告)日：2007-01-04

申请号：PCT/US2005/033755

申请日：2005-09-19

Applicant: BATTELLE MEMORIAL INSTITUTE ,  WEIL, K., Scott ,  CHICK, Lawrence, A. ,  COYLE, Christopher, A. ,  HARDY, John, S. ,  XIA, Guanguang ,  MEINHARDT, Kerry, D. ,  SPRENKLE, Vincent, L. ,  PAXTON, Dean, M.

Inventor： WEIL, K., Scott ,  CHICK, Lawrence, A. ,  COYLE, Christopher, A. ,  HARDY, John, S. ,  XIA, Guanguang ,  MEINHARDT, Kerry, D. ,  SPRENKLE, Vincent, L. ,  PAXTON, Dean, M.

CPC classification number: C03C27/044 ,  B32B2315/02 ,  C03C8/24 ,  C03C27/042 ,  C04B35/645 ,  C04B37/025 ,  C04B2235/6025 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/6567 ,  C04B2235/6583 ,  C04B2235/661 ,  C04B2237/10 ,  C04B2237/30 ,  C04B2237/32 ,  C04B2237/34 ,  C04B2237/343 ,  C04B2237/348 ,  C04B2237/40 ,  C04B2237/402 ,  C04B2237/403 ,  C04B2237/405 ,  C04B2237/406 ,  C04B2237/52 ,  C04B2237/592 ,  C04B2237/704 ,  C04B2237/706 ,  C04B2237/708 ,  H01M8/0282 ,  H01M8/0286 ,  Y02P70/56

Abstract: A seal formed between two parts that will remain gas tight in high temperature operating environments which experience frequent thermal cycling, which is particularly useful as an insulating joint in solid oxide fuel cells. A first metal part is attached to a reinforcing material. A glass forming material in the positioned in between the first metal part and the second part, and a seal is formed between the first metal part and the second part by heating the glass to a temperature suitable to melt the glass forming materials. The glass encapsulates and bonds at least a portion of the reinforcing material, thereby adding tremendous strength to the overall seal. A ceramic material may be added to the glass forming materials, to assist in forming an insulating barrier between the first metal part and the second part and to regulating the viscosity of the glass during the heating step.

Abstract translation: 在经历频繁热循环的高温操作环境中将保持气密的两个部件之间形成的密封件，其特别用作固体氧化物燃料电池中的绝缘接头。 第一金属部件附接到增强材料。 通过将玻璃加热至适于熔融玻璃形成材料的温度，在位于第一金属部件与第二部件之间的玻璃形成材料以及在第一金属部件与第二部件之间形成密封。 玻璃封装并粘合至少一部分增强材料，从而为整个密封增加了巨大的强度。 可以将陶瓷材料添加到玻璃形成材料中，以帮助在第一金属部件和第二部件之间形成绝缘屏障并且在加热步骤期间调节玻璃的粘度。

公开(公告)号：WO2009131942A9

公开(公告)日：2010-07-15

申请号：PCT/US2009041130

申请日：2009-04-20

Applicant: BATTELLE MEMORIAL INSTITUTE ,  SPRENKLE VINCENT L ,  MEINHARDT KERRY D ,  CHICK LAWRENCE A ,  KIM JIN YONG

Inventor： SPRENKLE VINCENT L ,  MEINHARDT KERRY D ,  CHICK LAWRENCE A ,  KIM JIN YONG

IPC: B01J23/83 ,  B01J23/89 ,  C25B11/00 ,  H01M4/88

CPC classification number: H01M4/90 ,  B01J23/83 ,  B01J23/894 ,  H01M4/8885 ,  H01M4/9066 ,  H01M2008/1293

Abstract: Methods for improving the sulfur -tolerance of nickel-based catalyst systems, as well as the improved catalyst systems, are disclosed. The methods can include adding praseodymium alone, or in combination with ruthenium and/or cerium, to a nickel-based catalyst system, thereby inhibiting sulfur poisoning of the catalyst system. Improved catalyst systems can have an added amount of praseodymium alone, or in combination with ruthenium and/or cerium, sufficient to inhibit poisoning of the system by sulfur.

Abstract translation: 公开了改进镍基催化剂体系的耐硫性的方法以及改进的催化剂体系。 所述方法可以包括将镨单独添加或与钌和/或铈组合加入到镍基催化剂体系中，从而抑制催化剂体系的硫中毒。 改进的催化剂体系可以单独添加镨，或与钌和/或铈组合，足以抑制硫系统的中毒。

公开(公告)号：WO2007001380A3

公开(公告)日：2007-07-26

申请号：PCT/US2005033755

申请日：2005-09-19

Applicant: BATTELLE MEMORIAL INSTITUTE ,  WEIL K SCOTT ,  CHICK LAWRENCE A ,  COYLE CHRISTOPHER A ,  HARDY JOHN S ,  XIA GUANGUANG ,  MEINHARDT KERRY D ,  SPRENKLE VINCENT L ,  PAXTON DEAN M

Inventor： WEIL K SCOTT ,  CHICK LAWRENCE A ,  COYLE CHRISTOPHER A ,  HARDY JOHN S ,  XIA GUANGUANG ,  MEINHARDT KERRY D ,  SPRENKLE VINCENT L ,  PAXTON DEAN M

IPC: C03C8/24 ,  C03C8/14 ,  C04B37/02 ,  H01M8/12 ,  H01M8/24

CPC classification number: C03C27/044 ,  B32B2315/02 ,  C03C8/24 ,  C03C27/042 ,  C04B35/645 ,  C04B37/025 ,  C04B2235/6025 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/6567 ,  C04B2235/6583 ,  C04B2235/661 ,  C04B2237/10 ,  C04B2237/30 ,  C04B2237/32 ,  C04B2237/34 ,  C04B2237/343 ,  C04B2237/348 ,  C04B2237/40 ,  C04B2237/402 ,  C04B2237/403 ,  C04B2237/405 ,  C04B2237/406 ,  C04B2237/52 ,  C04B2237/592 ,  C04B2237/704 ,  C04B2237/706 ,  C04B2237/708 ,  H01M8/0282 ,  H01M8/0286 ,  Y02P70/56

Abstract: A seal formed between two parts that will remain gas tight in high temperature operating environments which experience frequent thermal cycling, which is particularly useful as an insulating joint in solid oxide fuel cells. A first metal part is attached to a reinforcing material. A glass forming material in the positioned in between the first metal part and the second part, and a seal is formed between the first metal part and the second part by heating the glass to a temperature suitable to melt the glass forming materials. The glass encapsulates and bonds at least a portion of the reinforcing material, thereby adding tremendous strength to the overall seal. A ceramic material may be added to the glass forming materials, to assist in forming an insulating barrier between the first metal part and the second part and to regulating the viscosity of the glass during the heating step.

Abstract translation: 在两个部件之间形成的密封件，其将在经受频繁热循环的高温操作环境中保持气密，这在固体氧化物燃料电池中作为绝缘接头特别有用。 第一金属部件附接到增强材料。 定位在第一金属部分和第二部分之间的玻璃形成材料，并且通过将玻璃加热到适于熔化玻璃形成材料的温度，在第一金属部分和第二部分之间形成密封。 玻璃封装并粘合至少一部分增强材料，从而为整体密封增加了巨大的强度。 陶瓷材料可以添加到玻璃形成材料中，以帮助在第一金属部分和第二部分之间形成绝缘屏障，并且在加热步骤期间调节玻璃的粘度。

公开(公告)号：WO2007001380B1

公开(公告)日：2007-08-23

申请号：PCT/US2005033755

申请日：2005-09-19

Applicant: BATTELLE MEMORIAL INSTITUTE ,  WEIL K SCOTT ,  CHICK LAWRENCE A ,  COYLE CHRISTOPHER A ,  HARDY JOHN S ,  XIA GUANGUANG ,  MEINHARDT KERRY D ,  SPRENKLE VINCENT L ,  PAXTON DEAN M

Inventor： WEIL K SCOTT ,  CHICK LAWRENCE A ,  COYLE CHRISTOPHER A ,  HARDY JOHN S ,  XIA GUANGUANG ,  MEINHARDT KERRY D ,  SPRENKLE VINCENT L ,  PAXTON DEAN M

IPC: C03C8/24 ,  C03C8/14 ,  C04B37/02 ,  H01M8/12 ,  H01M8/24

CPC classification number: C03C27/044 ,  B32B2315/02 ,  C03C8/24 ,  C03C27/042 ,  C04B35/645 ,  C04B37/025 ,  C04B2235/6025 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/6567 ,  C04B2235/6583 ,  C04B2235/661 ,  C04B2237/10 ,  C04B2237/30 ,  C04B2237/32 ,  C04B2237/34 ,  C04B2237/343 ,  C04B2237/348 ,  C04B2237/40 ,  C04B2237/402 ,  C04B2237/403 ,  C04B2237/405 ,  C04B2237/406 ,  C04B2237/52 ,  C04B2237/592 ,  C04B2237/704 ,  C04B2237/706 ,  C04B2237/708 ,  H01M8/0282 ,  H01M8/0286 ,  Y02P70/56

Abstract: A seal formed between two parts that will remain gas tight in high temperature operating environments which experience frequent thermal cycling, which is particularly useful as an insulating joint in solid oxide fuel cells. A first metal part is attached to a reinforcing material. A glass forming material in the positioned in between the first metal part and the second part, and a seal is formed between the first metal part and the second part by heating the glass to a temperature suitable to melt the glass forming materials. The glass encapsulates and bonds at least a portion of the reinforcing material, thereby adding tremendous strength to the overall seal. A ceramic material may be added to the glass forming materials, to assist in forming an insulating barrier between the first metal part and the second part and to regulating the viscosity of the glass during the heating step.

Abstract translation: 在两个部件之间形成的密封件将在高温操作环境中保持气密，所述高温操作环境经历频繁的热循环，其特别用作固体氧化物燃料电池中的绝缘接头。 第一金属部件附接到增强材料。 通过将玻璃加热至适于熔融玻璃形成材料的温度，在位于第一金属部件与第二部件之间的玻璃形成材料以及在第一金属部件与第二部件之间形成密封。 玻璃封装并粘合至少一部分增强材料，从而为整个密封增加了巨大的强度。 可以将陶瓷材料添加到玻璃形成材料中，以帮助在第一金属部件和第二部件之间形成绝缘屏障并且在加热步骤期间调节玻璃的粘度。