公开(公告)号：WO0226381A3

公开(公告)日：2002-06-27

申请号：PCT/GB0104306

申请日：2001-09-26

Applicant: SCIONIX LTD ,  ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

Inventor： ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

IPC: B01J31/04 ,  B01J31/02 ,  B01J31/26 ,  B01J31/30 ,  B01J31/32 ,  B01J31/34 ,  C07B37/12 ,  C07B61/00 ,  C07C45/69 ,  C07C47/42 ,  C07C47/445 ,  C07C49/543 ,  C07C49/553 ,  C07C209/68 ,  C07C211/62 ,  C07C211/63 ,  C07C211/64 ,  C07C215/90 ,  C25D3/02 ,  C25D3/66 ,  C25D21/14 ,  C25F3/20 ,  C25F3/24 ,  H01M6/16 ,  H01M10/36

CPC classification number: B01J31/0284 ,  B01J31/006 ,  B01J31/0279 ,  B01J31/26 ,  B01J2231/125 ,  B01J2231/326 ,  C07B37/12 ,  C07C45/69 ,  C07C211/63 ,  C07C215/90 ,  C07C2601/16 ,  C07C2602/42 ,  C07C2602/44 ,  C25D3/02 ,  C25D3/665 ,  C25F3/20 ,  C25F3/24 ,  H01M6/164 ,  H01M6/166 ,  H01M10/36 ,  C07C47/42 ,  C07C49/543 ,  C07C49/553 ,  C07C47/445

Abstract: Ionic compounds having a freezing point of no more than 50 DEG C, formed by the reaction of at least one amine salt of the formula R R R R N X (I) with at least one hydrated salts, which is a chloride, nitrate, sulphate or acetate of Li, Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, Bi, La or Ce; wherein R , R and R are each independently a C1 to C5 alkyl or a C6 to C10 cycloalkyl group, or wherein R and R taken together represent a C4 to C10 alkylene group, thereby forming with the N atom of formula (I) a 5 to 11 membered heterocyclic ring, and wherein R is hydrogen, or phenyl, or C1 to C12 alkyl or cycloalkyl group, optionally substituted with at least one group selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, COOR , CHO, COR and OR , wherein R is a C1 to C10 alkyl or cycloalkyl group, and X is an anion capable of being complexed by the said hydrated salt. The compounds are useful as solvents, electrolytes, and catalyts, and have particular application in solvents/electrolytes for metal plating and electropolishing processes, in particular in chromium plating.

Abstract translation: 由至少一种通式为R 1 R 2 R 3 R 4 N + X - 的胺盐反应形成的冰点不超过50℃的离子化合物， （I）与至少一种水合盐反应，所述水合盐是Li，Mg，Ca，Cr，Mn，Fe，Co，Ni，Cu，Zn，Cd，Pb，Bi，La的氯化物，硝酸盐，硫酸盐或乙酸盐或 策; 其中R 1，R 2和R 3各自独立地为C 1至C 5烷基或C 6至C 10环烷基，或者其中R 2和R 3合在一起表示C 4至C 10亚烷基 从而与式（I）的N原子形成5至11元杂环，并且其中R 4为氢或苯基或C 1至C 12烷基或环烷基，其任选地被至少一个选自下列的基团取代： OH，Cl，Br，F，I，苯基，NH 2，CN，NO 2，COOR 5，CHO，COR 5和OR 5，其中R 5为C 1至C 10烷基或环烷基 并且X-是能够被所述水合盐络合的阴离子。 这些化合物可用作溶剂，电解质和催化剂，并且特别用于金属电镀和电解抛光工艺的溶剂/电解质中，特别是用于镀铬。

公开(公告)号：WO0226701A3

公开(公告)日：2003-05-01

申请号：PCT/GB0104300

申请日：2001-09-26

Applicant: SCIONIX LTD ,  ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

Inventor： ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

IPC: C07H3/02 ,  B01J31/02 ,  B01J31/04 ,  C07C31/20 ,  C07C31/36 ,  C07C33/22 ,  C07C39/04 ,  C07C39/07 ,  C07C39/28 ,  C07C41/30 ,  C07C47/565 ,  C07C47/575 ,  C07C47/58 ,  C07C53/126 ,  C07C53/16 ,  C07C53/18 ,  C07C55/06 ,  C07C55/08 ,  C07C57/32 ,  C07C59/10 ,  C07C59/153 ,  C07C59/265 ,  C07C59/50 ,  C07C63/06 ,  C07C65/03 ,  C07C205/06 ,  C07C211/10 ,  C07C211/11 ,  C07C211/46 ,  C07C211/63 ,  C07C215/12 ,  C07C215/76 ,  C07C215/90 ,  C07C219/06 ,  C07C229/04 ,  C07C229/12 ,  C07C229/60 ,  C07C233/05 ,  C07C233/65 ,  C07C235/46 ,  C07C275/00 ,  C07C275/02 ,  C07C275/20 ,  C07C309/30 ,  C07C311/16 ,  C07C335/02 ,  C25C1/20 ,  C25D3/02 ,  C25F3/16

CPC classification number: C25D3/02 ,  B01J31/006 ,  B01J31/0249 ,  B01J31/0279 ,  B01J31/0284 ,  B01J31/04 ,  B01J2231/125 ,  B01J2231/4261 ,  C07C41/30 ,  C07C275/02 ,  C25F3/16 ,  H01M2300/0025 ,  Y02P20/542 ,  C07C43/215

Abstract: Ionic compounds with a freezing point of up to 100 DEG C are formed by the reaction of an one amine salt of formula (I) R R R R N X , such as choline chloride with an organic compound (II) capable of forming a hydrogen bond with X , such as urea, wherein the molar ratio of I to II is from 1:1.5 to 1:2.5. R , R , R and R may be H, optionally substituted C1 to C5 alkyl, optionally substituted C6 to C10 cycloalkyl, optionally substituted C6 to C12 aryl, optionally substituted C7 to C12 alkaryl, or R and R taken together may represent a C4 to C10 optionally substituted alkylene group, thereby forming with the N atom of formula I a 5 to 11-membered heterocyclic ring and all of R , R , R and R are not identical, X may be NO3 , F, CI , Br , I , BF4 , CIO4 , CN , SO3CF3 , or COOCF3 . The ionic compounds are useful as solvents, and electrolytes for example in electroplating, electrowinning, and electropolishing, and as catalysts.

Abstract translation: 通过一种式（I）的胺盐R 1 R 2 R 3，R 4，N +，X 4， >，如具有与X'形成氢键的有机化合物（II）的氯化胆碱，例如脲，其中I与II的摩尔比为1:1.5至1:2.5。 R 1，R 2，R 3和R 4可以是H，任选取代的C 1 -C 5烷基，任选取代的C 6至C 10环烷基，任选取代的C 6至C 12芳基，任选取代的C 7至C 12烷芳基 或R 1和R 2一起可以表示C4至C10任选取代的亚烷基，从而与式I的N原子形成5至11元杂环，并且所有R 1，R R 3和R 4不相同，X可以是NO 3 - ，F，Cl - ，Br - ，I - ，BF 4 - ， - CIO4 - ，CN - ，SO3CF3 - 或COOCF3 - 。 离子化合物可用作溶剂，例如在电镀，电解冶金和电解抛光中的电解质，以及作为催化剂。