公开(公告)号：WO2007014882A2

公开(公告)日：2007-02-08

申请号：PCT/EP2006064640

申请日：2006-07-25

Applicant: IBM ,  IBM UK ,  HEDRICK JAMES LUPTON ,  MAGBITANG TEDDIE PEREGRINO ,  SANKARAPANDIAN MUTHUMANICKAM ,  VOLKSEN WILLI ,  KIM HO-CHEOL ,  LEE VICTOR YEE-WAY ,  MILLER ROBERT DENNIS ,  SUNDBERG LINDA KARIN ,  DUBOIS GERAUD JEAN-MICHEL

Inventor： HEDRICK JAMES LUPTON ,  MAGBITANG TEDDIE PEREGRINO ,  SANKARAPANDIAN MUTHUMANICKAM ,  VOLKSEN WILLI ,  KIM HO-CHEOL ,  LEE VICTOR YEE-WAY ,  MILLER ROBERT DENNIS ,  SUNDBERG LINDA KARIN ,  DUBOIS GERAUD JEAN-MICHEL

CPC classification number: C08L101/12 ,  H01L21/02118 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02216 ,  H01L21/02282 ,  H01L21/31695 ,  H01L21/76807 ,  H01L21/7682 ,  H01L2221/1047

Abstract: A composition of matter and a structure fabricated using the composition. The composition comprising; a resin; polymeric nano-particles dispersed in the resin, each of the polymeric nano-particle comprising a multi-arm core polymer and pendent polymers attached to the multi-arm core polymer, the multi-arm core polymer immiscible with the resin and the pendent polymers miscible with the resin; and a solvent, the solvent volatile at a first temperature, the resin cross-linkable at a second temperature, the polymeric nano-particle decomposable at a third temperature, the third temperature higher than the second temperature, the second temperature higher than the first temperature, wherein a thickness of a layer of the composition shrinks by less than about 3.5% between heating the layer from the second temperature to the third temperature.

Abstract translation: 使用该组合物制造的物质组成和结构。 该组合物包含： 树脂; 分散在树脂中的聚合物纳米颗粒，每种聚合物纳米颗粒包含多臂芯聚合物和连接到多臂芯聚合物上的侧链聚合物，与树脂不混溶的多臂芯聚合物和可混溶的侧链聚合物 与树脂; 和溶剂，所述溶剂在第一温度下是挥发性的，所述树脂在第二温度下可交联，所述聚合物纳米颗粒可在第三温度下分解，所述第三温度高于所述第二温度，所述第二温度高于所述第一温度 其中在将所述层从所述第二温度加热到所述第三温度之间，所述组合物层的厚度收缩小于约3.5％。

公开(公告)号：WO2007096359A2

公开(公告)日：2007-08-30

申请号：PCT/EP2007/051622

申请日：2007-02-20

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  IBM UNITED KINGDOM LIMITED ,  HEDRICK, James, Lupton ,  FROMMER, Jane, Elizabeth ,  WINDELN, Johannes ,  DUERIG, Urs ,  LEE, Victor, Yee-Way ,  GOTSMANN, Bernd ,  MILLER, Robert, Dennis ,  HAGBERG, Erik ,  MAGBITANG, Teddie ,  KNOLL, Armin ,  PRATT, Russell, Clayton ,  WADE, Charles

Inventor： HEDRICK, James, Lupton ,  FROMMER, Jane, Elizabeth ,  WINDELN, Johannes ,  DUERIG, Urs ,  LEE, Victor, Yee-Way ,  GOTSMANN, Bernd ,  MILLER, Robert, Dennis ,  HAGBERG, Erik ,  MAGBITANG, Teddie ,  KNOLL, Armin ,  PRATT, Russell, Clayton ,  WADE, Charles

CPC classification number: G11B9/149 ,  B82Y10/00 ,  C08G73/101 ,  C08G73/1046 ,  C08G73/105 ,  C08G73/1053 ,  C08G73/1064 ,  G11B9/1409 ,  G11B9/1454 ,  G11B11/007 ,  G11B2005/0021 ,  Y10T428/265 ,  Y10T428/31721

Abstract: An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyimide oligomers are used as the recording layers in atomic force data storage device, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyimide oligomers may be tuned to match thermal and force parameters required in read-write-erase cycles. Additionally, the cross-linked polyimide oligomers are suitable for use in nano-scale imaging.

Abstract translation: 提出了一种用于设计用于纳米级热机械存储装置的聚合物层的方法。 交联聚酰亚胺低聚物用作原子力数据存储装置中的记录层，与先前报道的交联和线性聚合物相比，显着提高了性能。 可以调整聚酰亚胺低聚物的交联以匹配读写擦除周期中所需的热和强度参数。 另外，交联聚酰亚胺低聚物适用于纳米级成像。

公开(公告)号：WO2011135046A1

公开(公告)日：2011-11-03

申请号：PCT/EP2011/056778

申请日：2011-04-28

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  IBM UNITED KINGDOM LIMITED ,  CENTRAL GLASS CO LTD ,  SANDERS, Daniel, Paul ,  HEDRICK, James, Lupton ,  MANABU, Yasumoto ,  FUJIWARA, Masaki

Inventor： SANDERS, Daniel, Paul ,  HEDRICK, James, Lupton ,  MANABU, Yasumoto ,  FUJIWARA, Masaki

IPC: C07D317/36 ,  C07D319/04 ,  C08G64/30

CPC classification number: C07D319/04 ,  C07D317/36 ,  C08G64/0233 ,  C08G64/30 ,  Y02P20/582

Abstract: A one pot method of preparing cyclic carbonyl compounds comprising an active pendant pentafluorophenyl carbonate group is disclosed. The cyclic carbonyl compounds can be polymerized by ring opening methods to form ROP polymers comprising repeat units comprising a side chain pentafluorophenyl carbonate group. Using a suitable nucleophile, the pendant pentafluorophenyl carbonate group can be selectively transformed into a variety of other functional groups before or after the ring opening polymerization.

Abstract translation: 公开了一种制备包含活性五氟苯基碳酸酯基团的环状羰基化合物的一锅法。 环状羰基化合物可以通过开环方法聚合以形成包含包含侧链五氟苯基碳酸酯基团的重复单元的ROP聚合物。 使用合适的亲核试剂，可以在开环聚合之前或之后将五氟苯基五氟苯基碳酸酯基团选择性地转化成多种其它官能团。

公开(公告)号：WO2007096359A3

公开(公告)日：2008-01-10

申请号：PCT/EP2007051622

申请日：2007-02-20

Applicant: IBM ,  IBM UK ,  HEDRICK JAMES LUPTON ,  FROMMER JANE ELIZABETH ,  WINDELN JOHANNES ,  DUERIG URS ,  LEE VICTOR YEE-WAY ,  GOTSMANN BERND ,  MILLER ROBERT DENNIS ,  HAGBERG ERIK ,  MAGBITANG TEDDIE ,  KNOLL ARMIN ,  PRATT RUSSELL CLAYTON ,  WADE CHARLES

Inventor： HEDRICK JAMES LUPTON ,  FROMMER JANE ELIZABETH ,  WINDELN JOHANNES ,  DUERIG URS ,  LEE VICTOR YEE-WAY ,  GOTSMANN BERND ,  MILLER ROBERT DENNIS ,  HAGBERG ERIK ,  MAGBITANG TEDDIE ,  KNOLL ARMIN ,  PRATT RUSSELL CLAYTON ,  WADE CHARLES

IPC: C08G73/12 ,  G11B9/00

CPC classification number: G11B9/149 ,  B82Y10/00 ,  C08G73/101 ,  C08G73/1046 ,  C08G73/105 ,  C08G73/1053 ,  C08G73/1064 ,  G11B9/1409 ,  G11B9/1454 ,  G11B11/007 ,  G11B2005/0021 ,  Y10T428/265 ,  Y10T428/31721

Abstract: An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyimide oligomers are used as the recording layers in atomic force data storage device, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyimide oligomers may be tuned to match thermal and force parameters required in read-write-erase cycles. Additionally, the cross-linked polyimide oligomers are suitable for use in nano-scale imaging.

Abstract translation: 提出了一种用于设计用于纳米级热机械存储装置的聚合物层的方法。 交联聚酰亚胺低聚物用作原子力数据存储装置中的记录层，与先前报道的交联和线性聚合物相比，显着提高了性能。 可以调整聚酰亚胺低聚物的交联以匹配读写擦除周期中所需的热和强度参数。 另外，交联聚酰亚胺低聚物适用于纳米级成像。

公开(公告)号：WO2007014882A3

公开(公告)日：2007-02-08

申请号：PCT/EP2006/064640

申请日：2006-07-25

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  IBM UNITED KINGDOM LIMITED ,  HEDRICK, James, Lupton ,  MAGBITANG, Teddie, Peregrino ,  SANKARAPANDIAN, Muthumanickam ,  VOLKSEN, Willi ,  KIM, Ho-Cheol ,  LEE, Victor, Yee-Way ,  MILLER, Robert, Dennis ,  SUNDBERG, Linda, Karin ,  DUBOIS, Geraud, Jean-Michel

Inventor： HEDRICK, James, Lupton ,  MAGBITANG, Teddie, Peregrino ,  SANKARAPANDIAN, Muthumanickam ,  VOLKSEN, Willi ,  KIM, Ho-Cheol ,  LEE, Victor, Yee-Way ,  MILLER, Robert, Dennis ,  SUNDBERG, Linda, Karin ,  DUBOIS, Geraud, Jean-Michel

IPC: C08L101/12 ,  H01L21/312

Abstract: A composition of matter and a structure fabricated using the composition. The composition comprising; a resin; polymeric nano-particles dispersed in the resin, each of the polymeric nano-particle comprising a multi-arm core polymer and pendent polymers attached to the multi-arm core polymer, the multi-arm core polymer immiscible with the resin and the pendent polymers miscible with the resin; and a solvent, the solvent volatile at a first temperature, the resin cross-linkable at a second temperature, the polymeric nano-particle decomposable at a third temperature, the third temperature higher than the second temperature, the second temperature higher than the first temperature, wherein a thickness of a layer of the composition shrinks by less than about 3.5% between heating the layer from the second temperature to the third temperature.

公开(公告)号：WO2011078805A1

公开(公告)日：2011-06-30

申请号：PCT/SG2010/000487

申请日：2010-12-23

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH ,  FUKUSHIMA, Kazuki ,  HEDRICK, James Lupton ,  YANG, Yi Yan

Inventor： FUKUSHIMA, Kazuki ,  HEDRICK, James Lupton ,  YANG, Yi Yan

IPC: C08G64/18 ,  C08G64/38

CPC classification number: C08G63/64 ,  A61K47/34 ,  C08G63/06 ,  C08G63/912 ,  C08G64/0208 ,  C08G64/0241 ,  C08G64/18 ,  C08G64/30 ,  C08G64/38 ,  C08G64/42 ,  C08G2261/126 ,  C12N5/0068 ,  C12N15/88 ,  C12N2533/30 ,  Y02P20/582

Abstract: A biodegradable cationic polymer is disclosed, comprising first repeat units derived from a first cyclic carbonyl monomer by ring-opening polymerization, wherein more than 0% of the first repeat units comprise a side chain moiety comprising a quaternary amine group; a subunit derived from a monomeric diol initiator for the ring-opening polymerization; and an optional endcap group. The biodegradable cationic polymers have low cytotoxicity and form complexes with biologically active materials useful in gene therapeutics and drug delivery.

Abstract translation: 公开了可生物降解的阳离子聚合物，其包含通过开环聚合衍生自第一环状羰基单体的第一重复单元，其中多于0％的第一重复单元包含包含季胺基团的侧链部分; 衍生自用于开环聚合的单体二醇引发剂的亚单位; 和可选的端帽组。 可生物降解的阳离子聚合物具有低的细胞毒性，并与用于基因治疗和药物递送的生物活性物质形成复合物。

公开(公告)号：WO2011078804A1

公开(公告)日：2011-06-30

申请号：PCT/SG2010/000486

申请日：2010-12-23

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH ,  HEDRICK, James Lupton ,  FUKUSHIMA, Kazuki ,  YANG, Yi-Yan

Inventor： HEDRICK, James Lupton ,  FUKUSHIMA, Kazuki ,  YANG, Yi-Yan

IPC: C08G64/18

CPC classification number: C08G63/64 ,  A61K9/1075 ,  A61K31/14 ,  C08G64/18 ,  C08G64/30 ,  Y10S977/773 ,  Y10S977/904

Abstract: Biodegradable cationic block copolymers are disclosed, comprising a hydrophilic block comprising first repeat units derived from a first cyclic carbonyl monomer by ring-opening polymerization, wherein more than 0% of the first repeat units comprise a side chain moiety comprising a quaternary amine group; a hydrophobic block comprising second repeat units derived from a second cyclic carbonyl monomer by ring-opening polymerization; an optional endcap group; and a chain fragment derived from an initiator for the ring opening polymerization. The cationic block copolymers form aqueous micelle mixtures suitable for antimicrobial applications.

Abstract translation: 公开了可生物降解的阳离子嵌段共聚物，其包含亲水性嵌段，其包含通过开环聚合衍生自第一环状羰基单体的第一重复单元，其中多于0％的第一重复单元包含包含季胺基团的侧链部分; 疏水性嵌段，其包含通过开环聚合衍生自第二环状羰基单体的第二重复单元; 可选端帽组; 和衍生自用于开环聚合的引发剂的链片段。 阳离子嵌段共聚物形成适用于抗微生物应用的水性胶束混合物。

公开(公告)号：WO2011078803A1

公开(公告)日：2011-06-30

申请号：PCT/SG2010/000485

申请日：2010-12-23

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH ,  HEDRICK, James Lupton ,  NELSON, Alshakim ,  YANG, Chuan ,  YANG, Yi Yan

Inventor： HEDRICK, James Lupton ,  NELSON, Alshakim ,  YANG, Chuan ,  YANG, Yi Yan

IPC: C08G64/18 ,  C08G65/00

CPC classification number: C12N5/0068 ,  A61K9/1075 ,  A61K47/34 ,  A61K47/549 ,  A61K47/6801 ,  A61K47/6907 ,  C08G63/664 ,  C08G64/183 ,  C08G2261/126 ,  C08L71/02 ,  C08L2203/02 ,  C08L2205/05 ,  C12N2533/30 ,  Y02P20/582 ,  C08L69/00

Abstract: A biodegradable block copolymer is disclosed, comprising a hydrophilic block derived from a polyether alcohol; and a hydrophobic block comprising a first repeat unit derived by ring opening polymerization of a first cyclic carbonyl monomer initiated by the polyether alcohol, the first repeat unit comprising a side chain moiety comprising a functional group selected from the group consisting of urea groups, a carboxylic acid groups, and mixtures thereof. No side chain of the hydrophobic block comprises a covalently bound biologically active material. The block copolymer self-assembles in water forming micelles suitable for sequestering a biologically active material by a non-covalent interaction, and the block copolymer is 60% biodegraded within 180 days in accordance with ASTM D6400.

Abstract translation: 公开了一种可生物降解的嵌段共聚物，其包含衍生自聚醚醇的亲水性嵌段; 和疏水性嵌段，其包含通过由所述聚醚醇引发的第一环状羰基单体的开环聚合得到的第一重复单元，所述第一重复单元包含侧链部分，所述侧链部分包含选自脲基的官能团， 酸基团，及其混合物。 疏水嵌段的侧链不包括共价结合的生物活性材料。 嵌段共聚物在水形成胶束中自组装，适合于通过非共价相互作用螯合生物活性材料，并且嵌段共聚物根据ASTM D6400在180天内生物降解60％。

公开(公告)号：WO2010143163A1

公开(公告)日：2010-12-16

申请号：PCT/IB2010/052618

申请日：2010-06-11

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  DUERIG, Urs T ,  FROMMER, Jane Elizabeth ,  GOTSMANN, Bernd W ,  HEDRICK, James Lupton ,  KNOLL, Armin W ,  MILLER, Robert Dennis ,  PIRES, David Santos ,  WADE, Charles Gordon

Inventor： DUERIG, Urs T ,  FROMMER, Jane Elizabeth ,  GOTSMANN, Bernd W ,  HEDRICK, James Lupton ,  KNOLL, Armin W ,  MILLER, Robert Dennis ,  PIRES, David Santos ,  WADE, Charles Gordon

IPC: G03F7/00 ,  G01Q80/00 ,  C08G2/06 ,  C08G2/14

CPC classification number: C08G2/06 ,  C08G2/14 ,  G01Q80/00 ,  G03F7/0002 ,  G03F7/0392 ,  G03F7/16 ,  G03F7/2049

Abstract: The invention concerns a method for patterning a surface of a material. A substrate having a polymer film thereon is provided. The polymer is a selectively reactive polymer (e.g. thermodynamically unstable): it is able to unzip upon suitable stimulation. A probe is used to create patterns on the film. During the patterning, the film is locally stimulated for unzipping polymer chains. Hence, a basic idea is to provide a stimulus to the polymeric material, which in turn spontaneously decomposes e.g. into volatile constituents. For example, the film is thermally stimulated in order to break a single bond in a polymer chain, which is sufficient to trigger the decomposition of the entire polymer chain.

Abstract translation: 本发明涉及用于图案化材料表面的方法。 提供其上具有聚合物膜的基板。 聚合物是选择性反应性聚合物（例如热力学不稳定的）：它能够在合适的刺激下解压缩。 探针用于在电影上创建图案。 在图案化期间，膜被局部刺激用于解链聚合物链。 因此，基本思想是向聚合物材料提供刺激，其又自发分解，例如， 变成挥发性成分。 例如，为了破坏聚合物链中的单键，该膜被热刺激，这足以引发整个聚合物链的分解。