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    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS
    2.
    发明申请
    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS 审中-公开
    通过烯醇化合物从内部碱基合成终端碱

    公开(公告)号：WO2008046106A2

    公开(公告)日：2008-04-17

    申请号：PCT/US2007/081427

    申请日：2007-10-15

    申请人： MATERIA, INC. ,  SCHRODI, Yann ,  PEDERSON, Richard, L. ,  KAIDO, Hiroki ,  TUPY, Michael, J.

    发明人： SCHRODI, Yann ,  PEDERSON, Richard, L. ,  KAIDO, Hiroki ,  TUPY, Michael, J.

    IPC分类号： C07C67/347

    CPC分类号： B01J31/2278 ,  B01J2231/54 ,  B01J2531/821 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/22 ,  C07C2531/24 ,  C07C11/02 ,  C07C69/533 ,  C07C69/73

    摘要： This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35 °C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

    摘要翻译： 本公开一般涉及烯烃复分解，更具体地涉及使用由烯烃复分解催化剂催化的交叉复分解反应从内部烯烃合成末端烯烃。 根据一个方面，例如，提供了一种用于合成末端烯烃的方法，所述方法包括在钌亚烷基复分解催化剂存在下使由至少一种内烯烃组成的烯属基材与由 在有效允许发生交叉复分解的反应条件下，α烯烃反应物，其中反应条件包括至少35℃的反应温度。 本文公开的方法，组合物，反应和反应体系可用于催化，有机合成和工业化学领域。

    METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME
    5.
    发明申请
    METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME 审中-公开
    涉及相同的氢化和组成的多元方法

    公开(公告)号：WO2008063322A2

    公开(公告)日：2008-05-29

    申请号：PCT/US2007/021934

    申请日：2007-10-15

    申请人： CARGILL, INCORPORATED ,  MATERIA, INCORPORATED ,  KAIDO, Hiroki ,  TUPY, Michael, John ,  PEDERSON, Richard, L. ,  SCHRODI, Yann

    发明人： KAIDO, Hiroki ,  TUPY, Michael, John ,  PEDERSON, Richard, L. ,  SCHRODI, Yann

    IPC分类号： C07C31/125 ,  C07C69/533

    CPC分类号： C11C3/00

    摘要： Disclosed are improved methods for conducting metathesis utilizing polyunsaturated fatty acid compositions (e.g., polyunsaturated fatty acid polyol esters, polyunsaturated fatty acids, polyunsaturated fatty esters, and mixtures), such as those found in naturally occurring oils and fats, as the starting material. The inventive methods involve hydrogenation of polyunsaturated fatty acid compositions prior to metathesis, thereby providing partially-hydrogenation compositions having a relatively higher amount of monounsaturated fatty acid species. The partially hydrogenated composition can then be subjected to metathesis to provide a metathesis product composition containing industrially useful compounds.

    摘要翻译： 公开了利用多不饱和脂肪酸组合物（例如，多不饱和脂肪酸多元醇酯，多不饱和脂肪酸，多不饱和脂肪酸酯和混合物）进行复分解的改进方法，例如在天然存在的油中发现的那些和 脂肪作为起始材料。 本发明方法涉及在复分解之前氢化多不饱和脂肪酸组合物，由此提供具有相对较高量的单不饱和脂肪酸物种的部分氢化组合物。 然后可以使部分氢化的组合物经复分解以提供含有工业上有用的化合物的复分解产物组合物。

    IMPURITY INHIBITION IN OLEFIN METATHESIS REACTIONS
    8.
    发明申请
    IMPURITY INHIBITION IN OLEFIN METATHESIS REACTIONS 审中-公开
    OLEFIN METATHESIS反应中的抑制作用

    公开(公告)号：WO2002094748A1

    公开(公告)日：2002-11-28

    申请号：PCT/US2002/016372

    申请日：2002-05-24

    申请人： PEDERSON, Richard, L. ,  PAULSON, Basil, P.

    发明人： PEDERSON, Richard, L. ,  PAULSON, Basil, P.

    IPC分类号： C07C6/04

    CPC分类号： C07D303/04 ,  C07C6/04 ,  C07C67/293 ,  C07C67/297 ,  C07C67/475 ,  C07C2531/24 ,  C07D207/20 ,  C07C69/145

    摘要： Methods using catalysts and reaction conditions to produce signi ficantly improved yields (and thereby higher purity) of olefin metathesis products, with greatly reduced amounts of impurities. These techniques include in one instance reduction in temperature of reaction, and in another, the use of chemical compounds that act as reaction inhibitors of unwanted reactions to minimize or prevent formation of unwanted impurities.

    摘要翻译： 使用催化剂和反应条件的方法可以显着提高烯烃复分解产物的产率（从而提高纯度），大大降低杂质量。 这些技术包括一方面降低反应温度，另一方面包括使用化学化合物，其作为不希望的反应的反应抑制剂以最小化或防止形成不需要的杂质。

    METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME
    10.
    发明申请
    METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME 审中-公开
    涉及氢化和组合物的相关方法

    公开(公告)号：WO2008063322A3

    公开(公告)日：2008-08-21

    申请号：PCT/US2007021934

    申请日：2007-10-15

    申请人： ELEVANCE RENEWABLE SCIENCES ,  MATERIA INC ,  KAIDO HIROKI ,  TUPY MICHAEL JOHN ,  PEDERSON RICHARD L ,  SCHRODI YANN

    发明人： KAIDO HIROKI ,  TUPY MICHAEL JOHN ,  PEDERSON RICHARD L ,  SCHRODI YANN

    IPC分类号： C07C31/125 ,  C07C69/533

    CPC分类号： C11C3/00

    摘要： Disclosed are improved methods for conducting metathesis utilizing polyunsaturated fatty acid compositions (e.g., polyunsaturated fatty acid polyol esters, polyunsaturated fatty acids, polyunsaturated fatty esters, and mixtures), such as those found in naturally occurring oils and fats, as the starting material. The inventive methods involve hydrogenation of polyunsaturated fatty acid compositions prior to metathesis, thereby providing partially-hydrogenation compositions having a relatively higher amount of monounsaturated fatty acid species. The partially hydrogenated composition can then be subjected to metathesis to provide a metathesis product composition containing industrially useful compounds.

    摘要翻译： 公开了使用多不饱和脂肪酸组合物（例如，多不饱和脂肪酸多元醇酯，多不饱和脂肪酸，多不饱和脂肪酸酯和混合物）进行复分解的改进方法，例如在天然存在的油和脂肪中发现的那些作为起始原料。 本发明的方法包括在复分解之前加氢多不饱和脂肪酸组合物，从而提供具有相对较高量的单不饱和脂肪酸物质的部分氢化组合物。 然后可以对部分氢化的组合物进行复分解，以提供含有工业上有用的化合物的复分解产物组合物。