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    METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS
    1.
    发明申请
    METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS 审中-公开

    公开(公告)号：WO2011119778A3

    公开(公告)日：2011-09-29

    申请号：PCT/US2011/029690

    申请日：2011-03-24

    申请人： SCHRODI, Yann

    发明人： SCHRODI, Yann

    IPC分类号： C07F15/00 ,  C07F19/00 ,  B01J31/16 ,  C07C6/04

    摘要： Synthetic methods for the in-situ formation of olefin metathesis catalysts are disclosed, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. In one aspect, a method is provided for synthesizing an organometallic compound of the formula (I); comprising contacting a precursor compound of the formula (X 1 X 2 ML j L 1 k L 3 m ) i with an acetylenic compound of the formula comprising a chelating moiety, optionally, in the presence of a neutral electron donor, wherein M is a Group 8 transition metal, L, L 1 , L 2 , and L 3 are neutral electron donors, X 1 and X 2 are anionic ligands, j is 1, 2, or 3; k is zero, 1, or 2; m is zero or 1; n is 1 or 2; and i is an integer; with the proviso that k is zero when the precursor compound is contacted with the acetylenic compound in the presence of the neutral electron donor, and R 1 and R 2 are independently selected from hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, substituted heteroatom-containing hydrocarbyl, and functional groups, wherein R1 and R2 are linked and together form one or more cyclic groups, R 2 and L 2 are linked and together form one or more cyclic groups, and any other two or more of X 1 , X 2 , L 1 , L 2 , L 3 , R 1 , and R 2 can be taken together to form one or more cyclic groups. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.

    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS
    3.
    发明申请
    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS 审中-公开
    通过烯醇化合物从内部碱基合成终端碱

    公开(公告)号：WO2008046106A2

    公开(公告)日：2008-04-17

    申请号：PCT/US2007/081427

    申请日：2007-10-15

    申请人： MATERIA, INC. ,  SCHRODI, Yann ,  PEDERSON, Richard, L. ,  KAIDO, Hiroki ,  TUPY, Michael, J.

    发明人： SCHRODI, Yann ,  PEDERSON, Richard, L. ,  KAIDO, Hiroki ,  TUPY, Michael, J.

    IPC分类号： C07C67/347

    CPC分类号： B01J31/2278 ,  B01J2231/54 ,  B01J2531/821 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/22 ,  C07C2531/24 ,  C07C11/02 ,  C07C69/533 ,  C07C69/73

    摘要： This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35 °C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

    摘要翻译： 本公开一般涉及烯烃复分解，更具体地涉及使用由烯烃复分解催化剂催化的交叉复分解反应从内部烯烃合成末端烯烃。 根据一个方面，例如，提供了一种用于合成末端烯烃的方法，所述方法包括在钌亚烷基复分解催化剂存在下使由至少一种内烯烃组成的烯属基材与由 在有效允许发生交叉复分解的反应条件下，α烯烃反应物，其中反应条件包括至少35℃的反应温度。 本文公开的方法，组合物，反应和反应体系可用于催化，有机合成和工业化学领域。

    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS
    4.
    发明申请
    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS 审中-公开
    通过烯醇化合物从内部碱基合成终端碱

    公开(公告)号：WO2008046106A3

    公开(公告)日：2016-04-07

    申请号：PCT/US2007081427

    申请日：2007-10-15

    申请人： ELEVANCE RENEWABLE SCIENCES ,  SCHRODI YANN ,  PEDERSON RICHARD L ,  KAIDO HIROKI ,  TUPY MICHAEL J

    发明人： SCHRODI YANN ,  PEDERSON RICHARD L ,  KAIDO HIROKI ,  TUPY MICHAEL J

    IPC分类号： C08F2/04 ,  C08F4/26

    CPC分类号： B01J31/2278 ,  B01J2231/54 ,  B01J2531/821 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/22 ,  C07C2531/24 ,  C07C11/02 ,  C07C69/533 ,  C07C69/73

    摘要： This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35 °C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

    摘要翻译： 本公开一般涉及烯烃复分解，更具体地涉及使用由烯烃复分解催化剂催化的交叉复分解反应从内部烯烃合成末端烯烃。 根据一个方面，例如，提供了一种用于合成末端烯烃的方法，所述方法包括在钌亚烷基复分解催化剂存在下使由至少一种内烯烃组成的烯属基材与由 在有效允许发生交叉复分解的反应条件下，α烯烃反应物，其中反应条件包括至少35℃的反应温度。 本文公开的方法，组合物，反应和反应体系可用于催化，有机合成和工业化学领域。

    METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME
    7.
    发明申请
    METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME 审中-公开
    涉及氢化和组合物的相关方法

    公开(公告)号：WO2008063322A3

    公开(公告)日：2008-08-21

    申请号：PCT/US2007021934

    申请日：2007-10-15

    申请人： ELEVANCE RENEWABLE SCIENCES ,  MATERIA INC ,  KAIDO HIROKI ,  TUPY MICHAEL JOHN ,  PEDERSON RICHARD L ,  SCHRODI YANN

    发明人： KAIDO HIROKI ,  TUPY MICHAEL JOHN ,  PEDERSON RICHARD L ,  SCHRODI YANN

    IPC分类号： C07C31/125 ,  C07C69/533

    CPC分类号： C11C3/00

    摘要： Disclosed are improved methods for conducting metathesis utilizing polyunsaturated fatty acid compositions (e.g., polyunsaturated fatty acid polyol esters, polyunsaturated fatty acids, polyunsaturated fatty esters, and mixtures), such as those found in naturally occurring oils and fats, as the starting material. The inventive methods involve hydrogenation of polyunsaturated fatty acid compositions prior to metathesis, thereby providing partially-hydrogenation compositions having a relatively higher amount of monounsaturated fatty acid species. The partially hydrogenated composition can then be subjected to metathesis to provide a metathesis product composition containing industrially useful compounds.

    摘要翻译： 公开了使用多不饱和脂肪酸组合物（例如，多不饱和脂肪酸多元醇酯，多不饱和脂肪酸，多不饱和脂肪酸酯和混合物）进行复分解的改进方法，例如在天然存在的油和脂肪中发现的那些作为起始原料。 本发明的方法包括在复分解之前加氢多不饱和脂肪酸组合物，从而提供具有相对较高量的单不饱和脂肪酸物质的部分氢化组合物。 然后可以对部分氢化的组合物进行复分解，以提供含有工业上有用的化合物的复分解产物组合物。

    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES AND ETHYLENE VIA OLEFIN METATHESIS
    10.
    发明申请
    SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES AND ETHYLENE VIA OLEFIN METATHESIS 审中-公开
    内烯烃和乙烯通过烯烃合成终端烯烃

    公开(公告)号：WO2008010961A3

    公开(公告)日：2008-05-02

    申请号：PCT/US2007016010

    申请日：2007-07-13

    申请人： MATERIA INC ,  SCHRODI YANN

    发明人： SCHRODI YANN

    IPC分类号： C07C6/04 ,  C07C11/02 ,  C07C67/333 ,  C07C69/533 ,  C07C69/58 ,  C07C69/587 ,  H04N7/14 ,  H04N7/16 ,  H04N7/167 ,  H04N7/173

    CPC分类号： C07C6/04 ,  B01J31/12 ,  B01J31/2265 ,  B01J2231/543 ,  B01J2531/821 ,  C07C67/333 ,  C07C2531/18 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2531/28 ,  C07F15/0046 ,  C07C11/02 ,  C07C69/533

    摘要： This invention relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by a selected olefin metathesis catalyst. In one embodiment of the invention, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting an olefinic substrate comprised of at least one internal olefin with ethylene, in the presence of a metathesis catalyst, wherein the catalyst is present in an amount that is less than about 1000 ppm relative to the olefinic substrate, and wherein the metathesis catalyst has the structure of formula (II), wherein the various substituents are as defined herein. The invention has utility, for example, in the fields of catalysis, organic synthesis, and industrial chemistry.

    摘要翻译： 本发明一般涉及烯烃复分解，更具体地涉及使用由选择的烯烃复分解催化剂催化的交叉复分解反应从内部烯烃合成末端烯烃。 在本发明的一个实施方案中，例如，提供了合成末端烯烃的方法，该方法包括在易位催化剂存在下使包含至少一种内烯烃的烯烃基质与乙烯接触，其中催化剂存在 其量相对于所述烯烃底物小于约1000ppm，并且其中所述复分解催化剂具有式（II）的结构，其中各种取代基如本文所定义。 例如，本发明在催化，有机合成和工业化学领域具有实用性。