公开(公告)号：WO2009036071A3

公开(公告)日：2009-06-25

申请号：PCT/US2008075866

申请日：2008-09-10

申请人： UNIV FLORIDA ,  RINZLER ANDREW GABRIEL ,  LIU BO ,  MCCARTHY MITCHELL AUSTIN ,  REYNOLDS JOHN ROBERT ,  SO FRANKY

发明人： RINZLER ANDREW GABRIEL ,  LIU BO ,  MCCARTHY MITCHELL AUSTIN ,  REYNOLDS JOHN ROBERT ,  SO FRANKY

IPC分类号： H05B33/00 ,  H01L29/00

CPC分类号： H01L51/5296 ,  B82Y10/00 ,  B82Y20/00 ,  B82Y30/00 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0048 ,  H01L51/0558 ,  H01L51/057 ,  H01L51/102 ,  H01L51/5203 ,  Y10S977/701 ,  Y10S977/742 ,  Y10S977/762 ,  Y10S977/767 ,  Y10S977/932 ,  Y10S977/936 ,  Y10S977/937 ,  Y10S977/938

摘要： Embodiments of the invention relate to vertical field effect transistor that is a light emitting transistor. The light emitting transistor incorporates a gate electrode for providing a gate field, a first electrode comprising a dilute nanotube network for injecting a charge, a second electrode for injecting a complementary charge, and an electroluminescent semiconductor layer disposed intermediate the nanotube network and the electron injecting layer. The charge injection is modulated by the gate field. The holes and electrons, combine to form photons, thereby causing the electroluminescent semiconductor layer to emit visible light. In other embodiments of the invention a vertical field effect transistor that employs an electrode comprising a conductive material with a low density of states such that the transistors contact barrier modulation comprises barrier height lowering of the Schottky contact between the electrode with a low density of states and the adjacent semiconductor by a Fermi level shift.

摘要翻译： 本发明的实施例涉及作为发光晶体管的垂直场效应晶体管。 发光晶体管包括用于提供栅极场的栅电极，包括用于注入电荷的稀释纳米管网络的第一电极，用于注入互补电荷的第二电极以及设置在纳米管网络和电子注入中间的电致发光半导体层 层。 电荷注入由门电场调制。 空穴和电子结合形成光子，从而使电致发光半导体层发射可见光。 在本发明的其他实施例中，采用包括具有低密度状态的导电材料的电极的垂直场效应晶体管使得晶体管接触势垒调制包括势垒高度降低具有低密度状态的电极之间的肖特基接触以及 相邻的半导体由费米能级移位。

公开(公告)号：WO2007137155A1

公开(公告)日：2007-11-29

申请号：PCT/US2007/069228

申请日：2007-05-18

申请人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. ,  REYNOLDS, John, Robert ,  WALCZAK, Ryan, Michael

发明人： REYNOLDS, John, Robert ,  WALCZAK, Ryan, Michael

IPC分类号： C08G61/12

CPC分类号： C08G61/125 ,  C08G61/124

摘要： A method to prepare halogen end-capped polypyrroles, polyfurans or copolymeric pyrroles and furans is presented that readily occurs in a liquid state as well as a solid state without the need of a catalyst from a dihalopyrrole monomer, dihalofuran monomer, or a mixture of monomers. The polymerization mixture can be modified to include a monohalo-monomer for the introduction of a specific end-group or a polyhalo-monomer to form a branched polymer or network. An initiating species can be included in the polymerization mixture to avoid an induction period or to commence the polymerization process on demand. The electroactive polymers can be formed as a bulk material, a coating, or as a film.

摘要翻译： 提出了制备卤素封端的聚吡咯，聚呋喃或共聚吡咯和呋喃的方法，其容易以液态和固态发生，而不需要来自二卤吡咯单体，二卤代呋喃单体或单体混合物的催化剂 。 可以将聚合混合物改性为包括用于引入特定末端基团或多卤代单体以形成支化聚合物或网络的单卤素单体。 引发物质可以包括在聚合混合物中以避免诱导期或根据需要开始聚合过程。 电活性聚合物可以形成为块状材料，涂层或膜。

公开(公告)号：WO2007087587A3

公开(公告)日：2007-11-15

申请号：PCT/US2007061016

申请日：2007-01-25

申请人： UNIV FLORIDA ,  REYNOLDS JOHN ROBERT ,  REEVES BENJAMIN DENNIS

发明人： REYNOLDS JOHN ROBERT ,  REEVES BENJAMIN DENNIS

IPC分类号： H01B1/12 ,  C08G61/00 ,  H01L51/30

CPC分类号： C08G61/122 ,  C08G61/124 ,  C08G61/125 ,  C08G61/126 ,  C08G2261/1426 ,  C08G2261/3223 ,  C08G2261/80 ,  H01B1/127 ,  H01L51/0037

摘要： A method for preparing a defunctionalized alkylenedioxyheterocycle polymer or copolymer involves providing a polycarboxylic acid derivative functionalizcd alkylenedioxyheterocycle polymer or copolymer and transforming the polymer or copolymer into a defunctionalized alkylenedioxyheterocycle polymer or copolymer which is a polyhydroxy, polythiol, polyamino, or polycarboxylic acid functionalizcd alkylenedioxyheterocycle polymer or copolymer. The monomers, homopolymers and copolymers for use in the method are new compositions of matter. The polymers containg polycarboxylic acid derivative functionalized alkylenedioxyheterocycle units are soluble polymers which are defunctionalized to yield insoluble polyhydroxy, polythiol, polyamino, or polycarboxylic acid functionalized alkylenedioxyheterocycle polymers. These polymers can be cast as films for use as: hole transport layers in organic light emitting diodes; active electrochrome in electrochromic windows, mirrors and displays; field effect transistors, supercapacitors, batteries, photovoltaic cells, and other electronic components; electronic paper; anti-stat conductors; and transparent conductors.

摘要翻译： 制备去官能化的亚烷基二氧杂环聚合物或共聚物的方法包括提供可聚酰亚胺官能化的亚烷基二氧杂环聚合物或共聚物，并将该聚合物或共聚物转化成去官能化的亚烷基二氧杂环聚合物或共聚物，其为多羟基，多硫醇，聚氨基或多官能亚烷基二氧杂环聚合物或 共聚物。 用于该方法的单体，均聚物和共聚物是新的物质组合物。 含有多元羧酸衍生物官能化的亚烷基二氧杂环单元的聚合物是可溶性聚合物，其被去官能化以产生不溶性多羟基，多硫醇，聚氨基或多元羧酸官能化的亚烷基二氧杂环聚合物。 这些聚合物可以铸造成薄膜用于：有机发光二极管中的空穴传输层; 电致变色窗户，镜子和显示器中的活性电子色素; 场效应晶体管，超级电容器，电池，光伏电池和其他电子组件; 电子纸; 反导体; 和透明导体。

公开(公告)号：WO2009036071A9

公开(公告)日：2009-03-19

申请号：PCT/US2008/075866

申请日：2008-09-10

申请人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. ,  RINZLER, Andrew, Gabriel ,  LIU, Bo ,  MCCARTHY, Mitchell, Austin ,  REYNOLDS, John, Robert ,  SO, Franky

发明人： RINZLER, Andrew, Gabriel ,  LIU, Bo ,  MCCARTHY, Mitchell, Austin ,  REYNOLDS, John, Robert ,  SO, Franky

IPC分类号： H05B33/00 ,  H01L29/00 ,  H01L33/00

摘要： Embodiments of the invention relate to vertical field effect transistor that is a light emitting transistor. The light emitting transistor incorporates a gate electrode for providing a gate field, a first electrode comprising a dilute nanotube network for injecting a charge, a second electrode for injecting a complementary charge, and an electroluminescent semiconductor layer disposed intermediate the nanotube network and the electron injecting layer. The charge injection is modulated by the gate field. The holes and electrons, combine to form photons, thereby causing the electroluminescent semiconductor layer to emit visible light. In other embodiments of the invention a vertical field effect transistor that employs an electrode comprising a conductive material with a low density of states such that the transistors contact barrier modulation comprises barrier height lowering of the Schottky contact between the electrode with a low density of states and the adjacent semiconductor by a Fermi level shift.

公开(公告)号：WO2013003548A3

公开(公告)日：2013-04-04

申请号：PCT/US2012044569

申请日：2012-06-28

申请人： UNIV FLORIDA ,  REYNOLDS JOHN ROBERT ,  WALCZAK RYAN MICHAEL ,  RINZLER ANDREW GABRIEL ,  VASILYEVA SVETLANA ,  DYER AUBREY LYNN

发明人： REYNOLDS JOHN ROBERT ,  WALCZAK RYAN MICHAEL ,  RINZLER ANDREW GABRIEL ,  VASILYEVA SVETLANA ,  DYER AUBREY LYNN

IPC分类号： G02F1/15 ,  E06B9/24

CPC分类号： G02F1/163 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y99/00 ,  G01J1/0407 ,  G01J1/44 ,  G02F1/15 ,  G02F1/155 ,  G02F1/157 ,  G02F2001/1515 ,  G02F2001/1536 ,  G02F2201/16 ,  G02F2201/58 ,  G02F2202/28 ,  G02F2202/36 ,  G02F2203/11 ,  Y02A30/257 ,  Y02B80/50 ,  Y10S977/742

摘要： An electrochromic device (ECD) includes an electrochromic cell and, optionally, one or more additional electrochromic cells where all cells are parallel, and where at least one of the electrodes of one of the cells comprises a single-walled carbon nanotube (SWNT) film. The electrochromic cells allow the control of transmittance of two or more di fferent portions of the electromagnetic spectrum through the ECD. One cell can control the transmittance of visible radiation while the other cell can control the transmittance of IR radiation. The ECD can be employed as a "smart window" to control the heat and light transmission through the window. The ECD can be in the form of a laminate that can be added to an existing window.

摘要翻译： 电致变色装置（ECD）包括电致变色电池和任选的一个或多个附加的电致变色细胞，其中所有细胞平行，并且其中一个电池的至少一个电极包括单壁碳纳米管（SWNT）膜 。 电致变色细胞允许通过ECD控制电磁光谱的两个或更多个不同部分的透射率。 一个电池可以控制可见光的透射率，而另一个电池可以控制IR辐射的透射率。 ECD可以用作“智能窗口”来控制通过窗户的热和光透射。 ECD可以是可以添加到现有窗口的层压板的形式。

公开(公告)号：WO2009036071A2

公开(公告)日：2009-03-19

申请号：PCT/US2008075866

申请日：2008-09-10

申请人： UNIV FLORIDA ,  RINZLER ANDREW GABRIEL ,  LIU BO ,  MCCARTHY MITCHELL AUSTIN ,  REYNOLDS JOHN ROBERT ,  SO FRANKY

发明人： RINZLER ANDREW GABRIEL ,  LIU BO ,  MCCARTHY MITCHELL AUSTIN ,  REYNOLDS JOHN ROBERT ,  SO FRANKY

IPC分类号： H01L33/00

CPC分类号： H01L51/5296 ,  B82Y10/00 ,  B82Y20/00 ,  B82Y30/00 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0048 ,  H01L51/0558 ,  H01L51/057 ,  H01L51/102 ,  H01L51/5203 ,  Y10S977/701 ,  Y10S977/742 ,  Y10S977/762 ,  Y10S977/767 ,  Y10S977/932 ,  Y10S977/936 ,  Y10S977/937 ,  Y10S977/938

摘要： Embodiments of the invention relate to vertical field effect transistor that is a light emitting transistor. The light emitting transistor incorporates a gate electrode for providing a gate field, a first electrode comprising a dilute nanotube network for injecting a charge, a second electrode for injecting a complementary charge, and an electroluminescent semiconductor layer disposed intermediate the nanotube network and the electron injecting layer. The charge injection is modulated by the gate field. The holes and electrons, combine to form photons, thereby causing the electroluminescent semiconductor layer to emit visible light. In other embodiments of the invention a vertical field effect transistor that employs an electrode comprising a conductive material with a low density of states such that the transistors contact barrier modulation comprises barrier height lowering of the Schottky contact between the electrode with a low density of states and the adjacent semiconductor by a Fermi level shift.

摘要翻译： 本发明的实施例涉及作为发光晶体管的垂直场效应晶体管。 发光晶体管包括用于提供栅极场的栅电极，包括用于注入电荷的稀释纳米管网络的第一电极，用于注入互补电荷的第二电极和设置在纳米管网络之间的电致发光半导体层和电子注入 层。 电荷注入由栅极场调制。 空穴和电子结合形成光子，从而使电致发光半导体层发射可见光。 在本发明的其它实施例中，采用包括具有低密度状态的导电材料的电极的垂直场效应晶体管，使得晶体管接触势垒调制包括具有低密度状态的电极之间的肖特基接触的势垒高度降低;以及 相邻的半导体通过费米能级移位。

公开(公告)号：WO2007087587A2

公开(公告)日：2007-08-02

申请号：PCT/US2007/061016

申请日：2007-01-25

申请人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. ,  REYNOLDS, John, Robert ,  REEVES, Benjamin, Dennis

发明人： REYNOLDS, John, Robert ,  REEVES, Benjamin, Dennis

IPC分类号： H01B1/12 ,  C08G61/00 ,  H01L51/30

CPC分类号： C08G61/122 ,  C08G61/124 ,  C08G61/125 ,  C08G61/126 ,  C08G2261/1426 ,  C08G2261/3223 ,  C08G2261/80 ,  H01B1/127 ,  H01L51/0037

摘要： A method for preparing a defunctionalized alkylenedioxyheterocycle polymer or copolymer involves providing a polycarboxylic acid derivative functionalizcd alkylenedioxyheterocycle polymer or copolymer and transforming the polymer or copolymer into a defunctionalized alkylenedioxyheterocycle polymer or copolymer which is a polyhydroxy, polythiol, polyamino, or polycarboxylic acid functionalizcd alkylenedioxyheterocycle polymer or copolymer. The monomers, homopolymers and copolymers for use in the method are new compositions of matter. The polymers containg polycarboxylic acid derivative functionalized alkylenedioxyheterocycle units are soluble polymers which are defunctionalized to yield insoluble polyhydroxy, polythiol, polyamino, or polycarboxylic acid functionalized alkylenedioxyheterocycle polymers. These polymers can be cast as films for use as: hole transport layers in organic light emitting diodes; active electrochrome in electrochromic windows, mirrors and displays; field effect transistors, supercapacitors, batteries, photovoltaic cells, and other electronic components; electronic paper; anti-stat conductors; and transparent conductors.

摘要翻译： 制备非官能化的亚烷基二氧杂环聚合物或共聚物的方法包括提供功能化的亚烷基二氧代杂环聚合物或共聚物的多元羧酸衍生物，并将聚合物或共聚物转化为功能化的亚烷基二氧杂环合聚合物或共聚物，其是多羟基，多硫醇，聚氨基或多元羧酸官能化亚烷基二氧杂环化合物或 共聚物。 用于该方法的单体，均聚物和共聚物是物质的新组合物。 包含多元羧酸衍生物官能化亚烷基二氧杂环单元的聚合物是可溶性聚合物，其被去官能化以产生不溶性多羟基，多硫醇，聚氨基或多元羧酸官能化的亚烷基二氧杂环聚合物。 这些聚合物可以浇铸成膜，用作有机发光二极管中的空穴传输层; 电致变色窗户，镜子和显示器中的主动电镀; 场效应晶体管，超级电容器，电池，光伏电池等电子部件; 电子纸; 防静电导体; 和透明导体。

公开(公告)号：WO2013003548A2

公开(公告)日：2013-01-03

申请号：PCT/US2012/044569

申请日：2012-06-28

申请人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. ,  REYNOLDS, John, Robert ,  WALCZAK, Ryan, Michael ,  RINZLER, Andrew, Gabriel ,  VASILYEVA, Svetlana ,  DYER, Aubrey, Lynn

发明人： REYNOLDS, John, Robert ,  WALCZAK, Ryan, Michael ,  RINZLER, Andrew, Gabriel ,  VASILYEVA, Svetlana ,  DYER, Aubrey, Lynn

CPC分类号： G02F1/163 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y99/00 ,  G01J1/0407 ,  G01J1/44 ,  G02F1/15 ,  G02F1/155 ,  G02F1/157 ,  G02F2001/1515 ,  G02F2001/1536 ,  G02F2201/16 ,  G02F2201/58 ,  G02F2202/28 ,  G02F2202/36 ,  G02F2203/11 ,  Y02A30/257 ,  Y02B80/50 ,  Y10S977/742

摘要： An electrochromic device (ECD) includes an electrochromic cell and, optionally, one or more additional electrochromic cells where all cells are parallel, and where at least one of the electrodes of one of the cells comprises a single-walled carbon nanotube (SWNT) film. The electrochromic cells allow the control of transmittance of two or more di fferent portions of the electromagnetic spectrum through the ECD. One cell can control the transmittance of visible radiation while the other cell can control the transmittance of IR radiation. The ECD can be employed as a "smart window" to control the heat and light transmission through the window. The ECD can be in the form of a laminate that can be added to an existing window.

摘要翻译： 电致变色装置（ECD）包括电致变色电池和任选地其中所有电池平行的一个或多个另外的电致变色电池，并且其中一个电池的至少一个电极包括单个 壁碳纳米管（SWNT）膜。 电致变色电池允许通过ECD控制电磁波谱的两个或更多个不同部分的透射率。 一个细胞可以控制可见辐射的透射率，而另一个细胞可以控制IR辐射的透射率。 ECD可以用作“智能窗口” 以控制通过窗户的热量和光线传输。 ECD可以是可以添加到现有窗口的层压板的形式。

公开(公告)号：WO2007041724A1

公开(公告)日：2007-04-12

申请号：PCT/US2006/039958

申请日：2006-10-06

申请人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. ,  REYNOLDS, John, Robert ,  WALCZAK, Ryan, Michael ,  COWART, John, Sigure., II

发明人： REYNOLDS, John, Robert ,  WALCZAK, Ryan, Michael ,  COWART, John, Sigure., II

IPC分类号： C07D207/36 ,  C07D491/04

CPC分类号： C07D207/416 ,  C07D491/04

摘要： A family of N -substituted 3,4-allcylenedioxypyrrole includes monomers for of formula (I) electropolymerization to conjugated polymers and key intermediates for the preparation of the monomers. The preparation of the //-substituted 3,4-aJkylenedioxypyrτoles is carried out via a synthetic intermediate, an ester substituted dihydroxypyrrole. The synthetic method to prepare the //-substituted 3,4-alkylenedioxypyrrole intermediates and ultimately the N- substituted 3,4-alkylenedioxypyrrole monomers begins with a reaction to form the ester substituted dihydroxypyrrole.

摘要翻译： 一种N-取代的3,4-全酰基二氧吡咯包括式（I）单体与共轭聚合物的电聚合和用于制备单体的关键中间体。 取代的3,4-亚烷基二氧基吡啶的制备通过合成中间体酯取代的二羟基吡咯进行。 制备N-取代的3,4-亚烷基二氧吡咯中间体和最终得到的N-取代的3,4-亚烷基二氧基吡咯单体的合成方法是从形成酯取代的二羟基吡咯的反应开始。