Abstract:
The present invention relates generally to catalysts and processes for the formation of terminal olefin(s) from internal olefin(s) via ethenolysis reactions. The ethenolysis reactions may proceed with high conversion, high turnover, and/or high selectivity.
Abstract:
In an embodiment, a conductive suicide nanostructure (200) includes a plurality of two-dimensional nanonet sheets (201), wherein each of the nanonet sheets (201) include connected and spaced-apart nanobeams (202) linked together at an about 90-degree angle. In an embodiment, the plurality of nanonet sheets (201) are stacked approximately horizontally. In an embodiment, the plurality of nanonet sheets (201) have an electrical resistivity of approximately 10 µO-cm. In an embodiment, a method of fabricating a two-dimensional conductive suicide includes performing chemical vapor deposition, wherein one or more gas or liquid precursor materials carried by a carrier gas stream react to form a nanostructure (200) having a mesh-like appearance and including a plurality of connected and spaced-apart nanobeams (202) linked together at an about 90-degree angle.
Abstract:
An apparatus and method for solar conversion using nanocoax structures are disclosed herein. A nano-optics apparatus (100) for use as a solar cell comprises a plurality of nano-coaxial structures comprising an internal conductor (120) surrounded by a semiconducting material (180) coated with an outer conductor (160); a film (140) having the plurality of nano-coaxial structures; and a protruding portion (110) of the an internal conductor (120) extending beyond a surface of the film (140). A method of fabricating a solar cell comprises coating a substrate (190) with a catalytic material; growing a plurality of carbon nanotubes (120) as internal cores of nanocoax units on the substrate (190); oxidizing the substrate (190); coating with a semiconducting film (180); and filling with a metallic medium(160) that wets the semiconducting film (180) of the nanocoax units.
Abstract:
An apparatus and methods for solar conversion using nanoscale cometal structures are disclosed herein. The cometal structures may be coaxial and coplanar. A nanoscale optics apparatus (100) for use as a solar cell comprises a plurality of nanoscale cometal structures each including a photovoltaic material (180) located between a first electrical conductor (120) and a second electrical conductor (160). A method of fabricating solar cells comprises preparing a plurality of nanoscale planar structures; coating a plurality of planar surfaces of the plurality of planar structures with a photovoltaic semiconductor (180) while leaving space between the plurality of planar surfaces; and coating the photovoltaic semiconductor (180) with an outer electrical conductor layer, wherein a portion of the outer electrical conductor layer is located between the planar structures to form coplanar structures.
Abstract:
A cost-effective and highly reproducible method of fabricating nanowires, and small gaps or spacings in nanowires is disclosed. The nanogaps bridge an important size regime between 1 nm and 100 ran. The nanogaps can be selectively predetermined to be as small as 1.0 nm, or larger than 1000 nm. These electrode gaps can be useful in preparing molecular electronic devices that involve making electrical contact to individual molecules, such as biomolecules, or small clusters of molecules. Microelectrodes having nanogaps for electrical and magnetic applications formed by the method, and as well as biosensors and their use in detecting a biological species, such as DNA, are also disclosed.
Abstract:
The present invention provides methods, compositions and systems for silylation of substrates, including direct asymmetric silylation of a substrate to provide enantiomerically enriched silylated products.
Abstract:
Methods for producing nanocrystals comprising metallic materials utilizing an inverse micelle solvothermal process are disclosed. Nanocrystals comprising well-ordered, single-crystalline germanium (Ge) materials with predeterminable morphologies in relatively high purity are produced by suspending a Ge salt material comprising a metal ion in a non-aqueous inverse micelle solvent comprising at least one surfactant, and introducing a reducing agent to the non-aqueous inverse micelle solvent to reduce a plurality of metal ions to form a ordered single-crystalline Ge nanocrystal.
Abstract:
The present invention is generally directed to nanocomposite thermoelectric materials that exhibit enhanced thermoelectric properties. The nanocomposite materials include two or more components, with at least one of the components forming nanosized structures within the composite material. The components are chosen such that thermal conductivity of the composite is decreased without substantially diminishing the composite's electrical conductivity. Suitable component materials exhibit similar electronic band structures. For example, a band-edge gap between at least one of a conduction band or a valence band of one component material and a corresponding band of the other component material at interfaces between the components can be less than about 5k B T, wherein k B is the Boltzman constant and T is an average temperature of said nanocomposite composition.
Abstract:
The present invention relates to a novel and useful way of generating a strong source of doubly or multiply entangled photons. To generate a high flux of such photons we propose the use of a parametric process, or a set of simultaneous parametric processes, in conjunction with laser-type action and nonlinear optical processes in an optical cavity. This can be achieved via an optical-system configuration in which two, three or more processes take place simultaneously: the generation of light by stimulated emission or other means from an active medium in a cavity; the nonlinear-optical production of higher optical harmonics in the same or in a n auxiliary cavity; and the generation of spontaneous parametric downconversion in the same or in an auxiliary cavity. Laser action can be achieved via the usual stimulated-emission mechanisms associated with a pumped active medium in a cavity or, more generally, via schemes that produce laser light without population inversion by virtue of quantum-interference effects or other optical processes. The generation of high-flux entangled-photon beams can take the form of continuous wave (cw) or pulsed light, the latter can be achieved by means of any number of mechanisms including gain switching, cavity dumping, Q-switching, mode-locking, or any combination thereof. Parametrically downconverted radiation generated in the manner described above is expected to have novel, unusual, and useful statistical, entanglement, and hyperentanglement properties. It is expected to find use in a large number of applications, including new forms of optical measurements; new forms of optical spectroscopy; new forms of quantum imaging including entangled-photon microscopy, spectroscopy, and display; quantum information; as well as offering new ways of examining quantum paradoxes.