公开(公告)号：WO2007125047A1

公开(公告)日：2007-11-08

申请号：PCT/EP2007/053871

申请日：2007-04-20

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  VAN DEN BERG, Robert Erwin ,  VAN DONGEN, Franciscus Gerardus ,  VON KOSSAK-GLOWCZEWSKI, Thomas Paul ,  ZUIDEVELD, Pieter Lammert

Inventor： VAN DEN BERG, Robert Erwin ,  VAN DONGEN, Franciscus Gerardus ,  VON KOSSAK-GLOWCZEWSKI, Thomas Paul ,  ZUIDEVELD, Pieter Lammert

IPC: C10J3/48

CPC classification number: C10J3/485 ,  C10J3/845 ,  C10J2200/09 ,  C10J2300/093 ,  C10J2300/0959 ,  C10J2300/1846 ,  C10K1/04 ,  C10K1/08 ,  C10K1/10 ,  C10K1/101

Abstract: The present invention relates to a Gasification reactor and its use, said reactor comprising: a pressure shell (31) for maintaining a pressure higher than atmospheric pressure; a slag bath located in a lower part of the pressure shell; a gasifier wall (32) arranged inside the pressure shell (31) defining a gasification chamber (33) wherein during operation the synthesis gas can be formed, a lower open part of the gasifier wall which is in fluid communication (7) with the slag bath and an open upper end (34) of the gasifier wall (32) which is in fluid communication with a quench zone (35); a quench zone (35) comprising a tubular formed part (36) positioned within the pressure shell (31), open at its lower and upper end and having a smaller diameter than the pressure shell (31) thereby defining an annular space (37) around the tubular part (36), wherein the lower open end of the tubular formed part (36) is fluidly connected to the upper end of the gasifier wall (32) and the upper open end of the tubular formed part is in fluid communication with the annular space (37); wherein at the lower end of the tubular part (36) injecting means (39) are present for injecting a liquid or gaseous cooling medium and wherein in the annular space (37) injecting means (40) are present to inject a liquid in the form of a mist and wherein an outlet (41) for synthesis gas is present in the wall of the pressure shell (31) fluidly connected to said annular space (37).

Abstract translation: 本发明涉及一种气化反应器及其用途，所述反应器包括：用于保持高于大气压力的压力的压力壳（31）; 位于压力壳的下部的渣槽; 设置在所述压力壳体内的气化器壁（32），其限定气化室（33），其中在操作期间可以形成所述合成气体，所述气化器壁的下开口部分与所述炉渣流体连通（7） 所述气化器壁（32）的开口上端（34）与骤冷区（35）流体连通; 位于所述压力壳体（31）内的管状形成部分（36）的骤冷区（35）在其下端和上端开口并且具有比所述压力壳（31）更小的直径从而限定环形空间（37） 围绕管状部分（36），其中管状形成部分（36）的下开口端流体地连接到气化器壁（32）的上端，并且管状形成部分的上开口端与流体连通 环形空间（37）; 其中在管状部分（36）的下端存在注射装置（39），用于注射液体或气体冷却介质，并且其中在环形空间（37）中存在注射装置（40）以注射形式的液体 并且其中用于合成气的出口（41）存在于与所述环形空间（37）流体连接的压力壳（31）的壁中。

公开(公告)号：WO2007003620A1

公开(公告)日：2007-01-11

申请号：PCT/EP2006/063789

申请日：2006-07-03

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  ZUIDEVELD, Pieter Lammert

Inventor： ZUIDEVELD, Pieter Lammert

IPC: C01B3/36 ,  C01B3/48 ,  C01B13/02

CPC classification number: C10J3/723 ,  C01B3/36 ,  C01B3/48 ,  C01B13/0229 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/065 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/84 ,  C01B2203/86 ,  C01B2210/0046 ,  C01B2210/0082 ,  C10J3/00 ,  C10J3/721 ,  C10J2300/093 ,  C10J2300/0959 ,  C10K1/08 ,  C10K3/04 ,  Y02P30/30

Abstract: The present invention relates to a system (1) for producing synthesis gas (20, 40) comprising CO and H2 , the system (1) at least comprising: a first gasification reactor (2) having an inlet (7) for a first oxygen containing stream (60) , an inlet (6) for a first, particulate or liquid carbonaceous stream (10) , an outlet (8) for raw synthesis gas (20) produced in the first gasification reactor (2) ; a second gasification reactor (3) having an inlet (11) for a second oxygen containing stream (70) , an inlet (9) for a second carbonaceous stream (30) , and an outlet (12) for raw synthesis gas (40) produced in the second gasification reactor (3), the seccnd carbonaceous stream (30) being selected from the group consisting of a gaseous and liquid stream, or a mixture thereof ; a source (4) of an oxygen containing stream (50) ; and a distributor (25) for fluidly connecting the source (4) to the inlet (7) for the first, oxygen containing stream (60) of the first gasif ication reactor (2) and to the inlet (11) for the second oxygen containing stream (70) of the second gasif ication reactor (3) ; wherein the distributor (25) is arranged to selectively connect the source (4) to the first (2) or second (3) gasification reactor.

Abstract translation: 本发明涉及一种用于生产包含CO和H2的合成气（20,40）的系统（1），所述系统（1）至少包括：第一气化反应器（2），其具有用于第一氧气的入口（7） （60），用于第一颗粒或液体碳质物流（10）的入口（6），在第一气化反应器（2）中生产的用于原料合成气的出口（8）; 具有用于第二含氧物流（70）的入口（11）和用于第二含碳物流（30）的入口（9）和用于原料合成气（40）的出口（12）的第二气化反应器（3） 在第二气化反应器（3）中产生的第二碳质物流（30）选自气态和液态物流或其混合物; 含氧流（50）的源（4）; 以及用于将源（4）流体连接到用于第一气化反应器（2）的第一含氧流（60）的入口（7）和用于第二氧气的入口（11）的分配器（25） 含有第二气化反应器（3）的流（70）; 其中分配器（25）布置成选择性地将源（4）连接到第一（2）或第二（3）气化反应器。

公开(公告)号：WO2007039443A1

公开(公告)日：2007-04-12

申请号：PCT/EP2006/066473

申请日：2006-09-19

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL CANADA LIMITED ,  VAN DER PLOEG, Hendrik, Jan ,  TIO, Thian, Hoey ,  ZUIDEVELD, Pieter, Lammert

Inventor： VAN DER PLOEG, Hendrik, Jan ,  TIO, Thian, Hoey ,  ZUIDEVELD, Pieter, Lammert

IPC: E21B43/16

CPC classification number: E21B43/168

Abstract: The present invention relates to a method of producing a hydrocarbon containing stream (110) from a subterranean zone (100) wherein an injection fluid (50) is injected into the subterranean zone (100), the method at least comprising the steps of: (a) providing an injection fluid (50) comprising synthesis gas; (b) injecting the injection fluid (50) into a subterranean zone (100) for obtaining a desired pressure therein; (c) obtaining a hydrocarbon containing stream (110) from the subterranean zone (100).

Abstract translation: 本发明涉及一种从地下区域（100）生产含烃流体（100）的方法，其中将注入流体（50）注射到地下区域（100）中，所述方法至少包括以下步骤：（ a）提供包含合成气的注射流体（50）; （b）将注入流体（50）注入地下区域（100）以获得期望的压力; （c）从所述地下区域（100）获得含烃流（110）。

公开(公告)号：WO2006117355A1

公开(公告)日：2006-11-09

申请号：PCT/EP2006/061951

申请日：2006-05-01

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  VAN DEN BERG, Robert, Erwin ,  VAN DONGEN, Franciscus, Gerardus ,  VON KOSSAK-GLOWCZEWSKI, Thomas, Thomas ,  VAN DER PLOEG, Hendrik, Jan ,  ZUIDEVELD, Pieter, Lammert

Inventor： VAN DEN BERG, Robert, Erwin ,  VAN DONGEN, Franciscus, Gerardus ,  VON KOSSAK-GLOWCZEWSKI, Thomas, Thomas ,  VAN DER PLOEG, Hendrik, Jan ,  ZUIDEVELD, Pieter, Lammert

IPC: C10J3/84 ,  F28C3/06

CPC classification number: C10J3/845 ,  C10J3/466 ,  C10J3/84 ,  C10J2300/093 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/1807 ,  C10K1/101 ,  F28C3/06

Abstract: The present invention relates to a method of producing synthesis gas comprising CO, CO2 , and H2 from a carbonaceous stream (3) using an oxygen containing stream (4) , the method comprising at least the steps of : (a) injecting a carbonaceous stream (3) and an oxygen containing stream (4) into a gasification reactor (2) ; (b) at least partially oxidising the carbonaceous stream (3) in the gasification reactor (2) , thereby- obtaining a raw synthesis gas; (c) removing the raw synthesis gas obtained in step (b) from the gasification reactor (2) into a quenching section ( 6) ; and (d) injecting a liquid (17) , preferably water, into the quenching section (2) in the form of a mist. In a further aspect the present invention relates to a system (1) for performing the method.

Abstract translation: 本发明涉及使用含氧流（4）从含碳流（3）生产包含CO，CO 2和H 2的合成气的方法，所述方法至少包括以下步骤：（a）将碳质流 （3）和含氧流（4）进入气化反应器（2）; （b）至少部分氧化气化反应器（2）中的碳质物流（3），从而获得原始合成气; （c）将从步骤（b）获得的原料合成气从气化反应器（2）中取出成淬火段（6）; 和（d）以雾的形式将液体（17），优选水注入淬火部分（2）中。 在另一方面，本发明涉及一种用于执行该方法的系统（1）。

公开(公告)号：WO2005108336A1

公开(公告)日：2005-11-17

申请号：PCT/EP2005/052043

申请日：2005-05-04

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  JENZER, Gregor, August ,  TIO, Thian, Hoey ,  ZUIDEVELD, Pieter, Lammert

Inventor： JENZER, Gregor, August ,  TIO, Thian, Hoey ,  ZUIDEVELD, Pieter, Lammert

IPC: C07C29/151

CPC classification number: C07C29/1518 ,  C07C31/04

Abstract: System and process for synthesising methanol out of a source gas containing light hydrocarbons. The system comprises - a hydrocarbon gas supply (3) for providing the source gas;- an oxygen supply (1) for providing an oxygen containing fluid;- a syngas reactor (2) in the form of a gasification reactor, arranged to receive the source gas from the hydrocarbon gas supply (3) and the oxygen containing fluid from the oxygen supply (1), the syngas reactor (2) being arranged to produce an intermediate reaction product from the source gas and the oxygen containing fluid, and to discharge the intermediate reaction product, the intermediate reaction product comprising syngas;- a methanol reactor (5), arranged to receive at least a fraction of the intermediate reaction product from the syngas reactor, and arranged to let the intermediate reaction product react into at least methanol via a methanol forming reaction, the methanol reactor being provided with a methanol outlet (11) for discharging the formed methanol and an offgas outlet (12) for discharging an offgas.

Abstract translation: 从含有轻质烃的源气体中合成甲醇的系统和方法。 该系统包括 - 用于提供源气体的烃气供应源（3）; - 用于提供含氧流体的氧气供应源（1）; - 气化反应器形式的合成气反应器（2） 来自烃气体源（3）的源气体和来自氧气供应源（1）的含氧流体，合成气反应器（2）被布置成从源气体和含氧流体产生中间反应产物，并且排出 中间反应产物，包含合成气的中间反应产物; - 甲醇反应器（5），其设置为从合成气反应器接收至少一部分中间反应产物，并且使中间反应产物反应成至少甲醇 通过甲醇形成反应，甲醇反应器设置有用于排出形成的甲醇的甲醇出口（11）和用于排出废气的废气出口（12）。

公开(公告)号：WO2004092060A1

公开(公告)日：2004-10-28

申请号：PCT/EP2004/050499

申请日：2004-04-13

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  BERGGREN, Wouter, Detlof ,  VAN DONGEN, Franciscus, Gerardus ,  TIO, Thian, Hoey ,  ZUIDEVELD, Pieter, Lammert

Inventor： BERGGREN, Wouter, Detlof ,  VAN DONGEN, Franciscus, Gerardus ,  TIO, Thian, Hoey ,  ZUIDEVELD, Pieter, Lammert

IPC: C01B3/38

CPC classification number: B01J8/067 ,  B01J8/008 ,  B01J8/0449 ,  B01J8/0496 ,  B01J8/062 ,  B01J2208/00309 ,  B01J2208/00495 ,  B01J2208/00504 ,  C01B3/382 ,  C01B3/384 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/0255 ,  C01B2203/0405 ,  C01B2203/042 ,  C01B2203/062 ,  C01B2203/0844 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/148 ,  C01B2203/82

Abstract: Reactor vessel for performing a steam reforming reaction comprising: a vessel inlet for natural gas and steam (2), a vessel inlet for a hot gaseous medium (3), a vessel outlet for a gaseous product comprising the steam reforming product (4), and a reactor space (7) comprising of a bed of steam reforming catalyst (8), which reactor space inlet is fluidly connected to the inlet for natural gas and steam and at its outlet end fluidly connected with the outlet for the gaseous product, wherein inside the catalyst bed a passageway (9) is provided fluidly connected to the vessel inlet for the hot gaseous medium for passage of hot gaseous mixture counter currently to the flow of reactants in the catalyst bed.

Abstract translation: 用于执行蒸汽重整反应的反应器容器包括：用于天然气和蒸汽的容器入口（2），用于热气体介质（3）的容器入口，用于包含蒸汽重整产物（4）的气态产物的容器出口， 以及包括蒸汽重整催化剂床（8）的反应器空间（7），所述反应器空间入口流体地连接到用于天然气和蒸汽的入口，并且其出口端与气态产物的出口流体连接，其中 在催化剂床内部，通道（9）被提供流体地连接到用于热气态介质的容器入口，用于使当前热的气体混合物计数器通过催化剂床中的反应物流。

公开(公告)号：WO2008043833A3

公开(公告)日：2008-04-17

申请号：PCT/EP2007/060876

申请日：2007-10-12

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  LAU, Teck-Soon ,  VAN DER PLOEG, Hendrik Jan ,  VAN DE RIJT, Jeroen ,  ZUIDEVELD, Pieter Lammert

Inventor： LAU, Teck-Soon ,  VAN DER PLOEG, Hendrik Jan ,  VAN DE RIJT, Jeroen ,  ZUIDEVELD, Pieter Lammert

IPC: C01B3/36 ,  C07C1/04 ,  C10B13/00 ,  F01K23/06 ,  C01B13/00 ,  B01D53/00

Abstract: Process to produce a hydrocarbon product from a subsurface reservoir by injecting into the reservoir the gaseous mixture obtained by the below process to obtain a desired pressure in said reservoir such to enhance the recovery of the hydrocarbon containing stream, wherein the process to prepare the gaseous mixture comprises (a) partial oxidation of a carbonaceous feed and a gas mixture comprising nitrogen and oxygen thereby obtaining the gaseous mixture comprising of nitrogen, carbon dioxide, carbon monoxide and hydrogen, (b) cooling of the gaseous mixture of step (a) by indirect heat exchange against evaporating water obtaining steam, (c) providing to a gas turbine a methane comprising feed thereby obtaining a source of power and an exhaust gas or providing to a fired steam boiler a methane comprising feed thereby obtaining steam and an exhaust gas, and (d) using the exhaust gas as obtained in step (c) as the gas mixture comprising nitrogen and oxygen in step (a).

公开(公告)号：WO2008043833A2

公开(公告)日：2008-04-17

申请号：PCT/EP2007060876

申请日：2007-10-12

Applicant: SHELL INT RESEARCH ,  LAU TECK-SOON ,  VAN DER PLOEG HENDRIK JAN ,  VAN DE RIJT JEROEN ,  ZUIDEVELD PIETER LAMMERT

Inventor： LAU TECK-SOON ,  VAN DER PLOEG HENDRIK JAN ,  VAN DE RIJT JEROEN ,  ZUIDEVELD PIETER LAMMERT

IPC: C01B3/36 ,  C07C1/04 ,  C10B13/00 ,  F01K23/06

CPC classification number: C01B3/36 ,  C01B3/52 ,  C01B13/0248 ,  C01B2203/0255 ,  C01B2203/049 ,  C01B2203/0894 ,  C01B2203/1235 ,  C01B2203/1241 ,  C10G1/04 ,  C10J3/00 ,  C10J3/04 ,  C10J3/78 ,  C10J2300/0916 ,  C10J2300/092 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/0956 ,  C10J2300/1609 ,  C10J2300/165 ,  C10J2300/1671 ,  C10J2300/1675 ,  C10J2300/1807 ,  C10K1/08 ,  Y02E20/16 ,  Y02E20/18 ,  Y02P20/145

Abstract: Process to produce a hydrocarbon product from a subsurface reservoir by injecting into the reservoir the gaseous mixture obtained by the below process to obtain a desired pressure in said reservoir such to enhance the recovery of the hydrocarbon containing stream, wherein the process to prepare the gaseous mixture comprises (a) partial oxidation of a carbonaceous feed and a gas mixture comprising nitrogen and oxygen thereby obtaining the gaseous mixture comprising of nitrogen, carbon dioxide, carbon monoxide and hydrogen, (b) cooling of the gaseous mixture of step (a) by indirect heat exchange against evaporating water obtaining steam, (c) providing to a gas turbine a methane comprising feed thereby obtaining a source of power and an exhaust gas or providing to a fired steam boiler a methane comprising feed thereby obtaining steam and an exhaust gas, and (d) using the exhaust gas as obtained in step (c) as the gas mixture comprising nitrogen and oxygen in step (a).

Abstract translation: 通过将通过下述方法获得的气体混合物注入储层中以从地下储层产生烃产物的过程，以在所述储层中获得期望的压力，以提高含烃流体的回收率，其中制备气态混合物的方法 包括（a）含碳进料和含氮和氧的气体混合物的部分氧化，从而获得包含氮气，二氧化碳，一氧化碳和氢气的气体混合物，（b）通过间接冷却步骤（a）的气体混合物 （c）向燃气轮机提供包含甲烷的进料，由此获得动力源和废气或向燃烧的蒸汽锅炉提供包含甲烷的进料，从而获得蒸汽和废气，以及 （d）在步骤（a）中使用如步骤（c）中获得的废气作为包含氮气和氧气的气体混合物。

公开(公告)号：WO2007125046A1

公开(公告)日：2007-11-08

申请号：PCT/EP2007/053869

申请日：2007-04-27

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  VAN DEN BERG, Robert Erwin ,  VAN DONGEN, Franciscus Gerardus ,  VON KOSSAK-GLOWCZEWSKI, Thomas Paul ,  VAN DER PLOEG, Hendrik Jan ,  ZUIDEVELD, Pieter Lammert

Inventor： VAN DEN BERG, Robert Erwin ,  VAN DONGEN, Franciscus Gerardus ,  VON KOSSAK-GLOWCZEWSKI, Thomas Paul ,  VAN DER PLOEG, Hendrik Jan ,  ZUIDEVELD, Pieter Lammert

IPC: C10J3/48 ,  C10J3/78 ,  C10J3/82

CPC classification number: C10J3/485 ,  C10J3/78 ,  C10J3/82 ,  C10J2200/09 ,  C10J2300/093 ,  C10J2300/0959 ,  C10J2300/1846 ,  C10K1/08 ,  C10K1/10 ,  C10K1/101 ,  C10K1/16

Abstract: The present invention relates to a gasification system and its use, said gasification system comprising a gasification reactor (43) and a synthesis gas cooling vessel (44), wherein the gasification reactor (43) comprises: a pressure shell for maintaining a pressure higher than atmospheric pressure; a slag bath located in a lower part of the pressure shell; a gasifier wall arranged inside the pressure shell defining a gasification chamber (47) wherein during operation the synthesis gas can be formed, a lower open part of the gasifier wall which is in fluid communication with the slag bath and an open upper end of the gasifier wall which is in fluid communication with the synthesis gas cooling vessel via a connecting conduit (51); and wherein the synthesis gas cooling vessel (44) comprises an inlet for hot synthesis gas, an outlet (49) for cooled synthesis gas and means (46) to, in use, directly contact liquid water with the hot synthesis gas as formed in the gasification reactor.

Abstract translation: 本发明涉及一种气化系统及其用途，所述气化系统包括气化反应器（43）和合成气冷却容器（44），其中气化反应器（43）包括：压力壳，用于保持高于 气压; 位于压力壳的下部的渣槽; 设置在所述压力壳内的气化器壁，其限定气化室（47），其中在操作期间可以形成合成气体，气化器壁的下开口部分与炉渣槽流体连通，并且气化器的敞开的上端 经由连接导管（51）与合成气冷却容器流体连通的壁; 并且其中所述合成气冷却容器（44）包括用于热合成气的入口，用于冷却的合成气的出口（49）和在使用中与在所述热合成气中形成的热合成气直接接触液态水的装置（46） 气化反应器。