公开(公告)号：WO2017146800A2

公开(公告)日：2017-08-31

申请号：PCT/US2016/065698

申请日：2016-12-09

Applicant: PRAXAIR TECHNOLOGY, INC.

Inventor： KELLY, Sean, M. ,  SWAMI, Sadashiv, M. ,  PECK, John, D.

IPC: C01B3/38

CPC classification number: C01B3/382 ,  C01B13/0251 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0844 ,  C01B2203/142

Abstract: A method of operating an oxygen transport membrane based reforming system employing one or more packs of thermally coupled panels of reformer tubes and oxygen transport membrane ("OTM") reactors close to thermo-neutral point is provided. The method produces syngas by converting a hydrocarbon-containing feed, such as natural gas in the reformer tubes of a pack by endothermic steam reforming reactions. The heat required for endothermic reforming reactions is provided by exothermic oxidizing reactions occurring inside the OTM reactors of the pack. At a thermo-neutral point the heat released by exothermic reactions matches the heat required to support endothermic reactions and heat losses in the pack. The method modulates the flow rate of hydrocarbon-containing feed and/or steam-to- carbon ratio of the combined feed to the pack to maintain the surface temperature of oxygen transport membrane reactors below a target maximum temperature. The syngas product oxygen-to-carbon ratio is maintained within a desired target range such that the OTM based reforming system is operated close to thermo-neutral point.

Abstract translation: 提供了一种操作基于氧传输膜的重整系统的方法，该重整系统使用一个或多个重整器管的热耦合面板和接近热中性点的氧气传输膜（“OTM”）反应器 。 该方法通过吸热蒸汽重整反应转化包装的重整器管中的含碳氢化合物的进料如天然气来生产合成气。 吸热重整反应所需的热量由包装的OTM反应器内发生的放热氧化反应提供。 在热中性点，由放热反应释放的热量与支持吸热反应所需的热量和包装内的热量损失相匹配。 该方法调节组合进料到组件的含烃进料流速和/或蒸汽碳比，以将氧传输膜反应器的表面温度保持在目标最高温度以下。 合成气产物氧碳比保持在期望的目标范围内，使得基于OTM的重整系统运行在接近热中性点的位置。

公开(公告)号：WO2015054363A8

公开(公告)日：2015-11-19

申请号：PCT/US2014059654

申请日：2014-10-08

Applicant: PRAXAIR TECHNOLOGY INC

Inventor： KELLY SEAN M

IPC: B01J8/06 ,  B01J8/00 ,  B01J8/02 ,  C01B3/38 ,  C01B13/02

CPC classification number: B01D53/46 ,  B01D53/226 ,  B01J8/009 ,  B01J8/025 ,  B01J8/062 ,  B01J8/065 ,  B01J19/2475 ,  B01J2208/00176 ,  B01J2208/00371 ,  B01J2219/00006 ,  B01J2219/24 ,  C01B3/382 ,  C01B3/384 ,  C01B3/386 ,  C01B13/0251 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0805 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/148 ,  C07C1/041 ,  C07C1/0485

Abstract: A system and method for temperature control in an oxygen transport membrane based reactor is provided. The system and method involves introducing a specific quantity of cooling air or trim air in between stages in a multistage oxygen transport membrane based reactor or furnace to maintain generally consistent surface temperatures of the oxygen transport membrane elements and associated reactors. Each stage includes a cooling air inlet circuit operatively connected to cooling air distribution manifolds (312), cooling air distribution tubes (313). Systems and methods including air diffuser screens (325) disposed proximate the back window or distal end of the furnace segment (304) are also disclosed. The associated reactors may include reforming reactors, boilers or process gas heaters.

Abstract translation: 提供了一种基于氧传输膜的反应器中的温度控制系统和方法。 该系统和方法包括在基于多级氧传输膜的反应器或炉中的阶段之间引入特定量的冷却空气或修整空气，以保持氧传输膜元件和相关联的反应器的大致一致的表面温度。 每个阶段包括可操作地连接到冷却空气分配歧管（312），冷却空气分配管（313）的冷却空气入口回路。 还公开了包括邻近炉段（304）的后窗或远端设置的空气扩散器筛网（325）的系统和方法。 相关联的反应器可以包括重整反应器，锅炉或工艺气体加热器。

公开(公告)号：WO2015069907A3

公开(公告)日：2015-11-05

申请号：PCT/US2014064362

申请日：2014-11-06

Applicant: WATT FUEL CELL CORP

Inventor： FINNERTY CAINE M ,  DEWALD PAUL

IPC: B01J12/00 ,  B01J4/00 ,  B01J8/06 ,  B01J19/24 ,  C01B3/32 ,  C01B3/38 ,  H01M8/06 ,  H01M8/24

CPC classification number: C01B3/386 ,  B01J4/001 ,  B01J4/002 ,  B01J4/005 ,  B01J7/00 ,  B01J8/0285 ,  B01J8/065 ,  B01J8/067 ,  B01J8/1836 ,  B01J8/24 ,  B01J12/005 ,  B01J12/007 ,  B01J19/0013 ,  B01J19/0093 ,  B01J19/2415 ,  B01J19/2445 ,  B01J2208/00389 ,  B01J2208/00902 ,  B01J2208/00911 ,  B01J2219/00006 ,  B01J2219/00058 ,  B01J2219/00063 ,  B01J2219/00069 ,  B01J2219/00117 ,  B01J2219/00132 ,  B01J2219/00135 ,  B01J2219/00155 ,  B01J2219/00157 ,  B01J2219/00159 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00234 ,  B01J2219/00585 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/141

Abstract: A dual utilization liquid and gaseous fuel CPOX reformer that includes reaction zones for the CPOX reforming of liquid and gaseous reformable fuels. A reforming method is also provided. The method comprises reforming a first gaseous reformable reaction mixture comprising oxygen-containing gas and vaporized liquid fuel and before or after this step, reforming second gaseous reformable reaction mixture comprising oxygen~containing gas and gaseous fuel to produce a hydrogen-rich reformate.

Abstract translation: 一种双重利用液体和气态燃料CPOX重整器，其包括用于液体和气体可重整燃料的CPOX重整的反应区。 还提供了重整方法。 该方法包括重整包含含氧气体和蒸发的液体燃料的第一气体可重整反应混合物，并且在该步骤之前或之后，重整包含含氧气体和气态燃料的第二气态可重整反应混合物以产生富氢重整产物。

公开(公告)号：WO2015128395A1

公开(公告)日：2015-09-03

申请号：PCT/EP2015/053968

申请日：2015-02-26

Applicant: HALDOR TOPSØE A/S

Inventor： DYBKJÆR, Ib ,  AASBERG-PETERSEN, Kim

IPC: C01B3/38

CPC classification number: C01B3/48 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/04 ,  C01B2203/047 ,  C01B2203/062 ,  C01B2203/0844 ,  C01B2203/1205 ,  C01B2203/1235 ,  C01B2203/1258 ,  C01B2203/1264 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/148 ,  C01B2203/1671 ,  C10G2/30

Abstract: The invention relates to a process for the production of liquid hydrocarbons by Fischer-Tropsch synthesis in which the reforming section of the plant comprises a process line comprising autothermal reforming (ATR) (5) or catalytic partial oxidation (CPO), and a separate process line comprising steam methane reforming (SMR) (8).

Abstract translation: 本发明涉及一种通过费 - 托合成生产液态烃的方法，其中该装置的重整段包括一个包含自热重整（ATR）（5）或催化部分氧化（CPO）的工艺生产线，以及一个单独的工艺 包括蒸汽甲烷重整（SMR）（8）。

公开(公告)号：WO2015054363A3

公开(公告)日：2015-08-13

申请号：PCT/US2014059654

申请日：2014-10-08

Applicant: PRAXAIR TECHNOLOGY INC

Inventor： KELLY SEAN M

IPC: B01J8/06 ,  B01J8/00 ,  B01J8/02 ,  C01B3/38 ,  C01B13/02

CPC classification number: B01D53/46 ,  B01D53/226 ,  B01J8/009 ,  B01J8/025 ,  B01J8/062 ,  B01J8/065 ,  B01J19/2475 ,  B01J2208/00176 ,  B01J2208/00371 ,  B01J2219/00006 ,  B01J2219/24 ,  C01B3/382 ,  C01B3/384 ,  C01B3/386 ,  C01B13/0251 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0805 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/148 ,  C07C1/041 ,  C07C1/0485

Abstract: A system and method for temperature control in an oxygen transport membrane based reactor is provided. The system and method involves introducing a specific quantity of cooling air or trim air in between stages in a multistage oxygen transport membrane based reactor or furnace to maintain generally consistent surface temperatures of the oxygen transport membrane elements and associated reactors. Each stage includes a cooling air inlet circuit operatively connected to cooling air distribution manifolds (312), cooling air distribution tubes (313). Systems and methods including air diffuser screens (325) disposed proximate the back window or distal end of the furnace segment (304) are also disclosed. The associated reactors may include reforming reactors, boilers or process gas heaters.

Abstract translation: 提供了一种基于氧传输膜的反应器中的温度控制系统和方法。 该系统和方法包括在基于多级氧传输膜的反应器或炉中的阶段之间引入特定量的冷却空气或修整空气，以保持氧传输膜元件和相关联的反应器的大致一致的表面温度。 每个阶段包括可操作地连接到冷却空气分配歧管（312），冷却空气分配管（313）的冷却空气入口回路。 还公开了包括邻近炉段（304）的后窗或远端设置的空气扩散器筛网（325）的系统和方法。 相关联的反应器可以包括重整反应器，锅炉或工艺气体加热器。

公开(公告)号：WO2015069835A2

公开(公告)日：2015-05-14

申请号：PCT/US2014/064238

申请日：2014-11-06

Applicant: WATT FUEL CELL CORP.

Inventor： FINNERTY, Caine, M. ,  DeWALD, Paul

IPC: C01B3/32 ,  H01M8/06 ,  B01J19/00

CPC classification number: C01B3/386 ,  B01J4/001 ,  B01J4/002 ,  B01J4/005 ,  B01J7/00 ,  B01J8/0285 ,  B01J8/065 ,  B01J8/067 ,  B01J8/1836 ,  B01J8/24 ,  B01J12/005 ,  B01J12/007 ,  B01J19/0013 ,  B01J19/0093 ,  B01J19/2415 ,  B01J19/2445 ,  B01J2208/00389 ,  B01J2208/00902 ,  B01J2208/00911 ,  B01J2219/00006 ,  B01J2219/00058 ,  B01J2219/00063 ,  B01J2219/00069 ,  B01J2219/00117 ,  B01J2219/00132 ,  B01J2219/00135 ,  B01J2219/00155 ,  B01J2219/00157 ,  B01J2219/00159 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00234 ,  B01J2219/00585 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/141

Abstract: A multi-tubular chemical reactor includes an igniter for the initiation of gas phase exothermic reaction within the gas phase reaction zones of the tubular reactor units.

Abstract translation: 多管式化学反应器包括用于在管式反应器单元的气相反应区内启动气相放热反应的点火器。

公开(公告)号：WO2007142739A3

公开(公告)日：2013-08-29

申请号：PCT/US2007009256

申请日：2007-04-13

Applicant: EXXONMOBIL CHEM PATENTS INC ,  JENKINS CHRISTOPHER D W ,  LATTNER JAMES R ,  VERAA MICHAEL J ,  KUECHLER KEITH H

Inventor： JENKINS CHRISTOPHER D W ,  LATTNER JAMES R ,  VERAA MICHAEL J ,  KUECHLER KEITH H

IPC: C01B3/38 ,  C01B3/36 ,  C07C29/151

CPC classification number: C07C29/1518 ,  C01B3/36 ,  C01B3/382 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/061 ,  C01B2203/063 ,  C01B2203/0844 ,  C01B2203/142 ,  C01B2203/82 ,  C07C31/04

Abstract: A method of producing synthesis gas for methanol synthesis (7) that comprises the steps of: (a) obtaining a hydrogen stream that has greater than 5 mol% methane from an external process; (b) feeding into a reforming reactor (4): (i) a feed gas that comprises methane(l), (ii) water (2) in a specified amount, (Hi) oxygen (3) in a specified amount, and (iv) the hydrogen stream in a specified amount; (c) reacting the feed gas, water, oxygen and the hydrogen stream in the reactor; and (d) withdrawing from the reactor the synthesis gas (5) that is at a specific temperature, has less than 3 mol% methane, and has a stoichiometric number of from 1.9 to 2.3.

Abstract translation: 一种生产用于甲醇合成的合成气的方法（7），其包括以下步骤：（a）从外部工艺获得具有大于5mol％甲烷的氢气流; （b）进料到重整反应器（4）中：（i）包含甲烷（1），（ii）规定量的水（2），（ⅰ）规定量的氧（3））的原料气，以及 （iv）规定量的氢气流; （c）使反应器中的进料气体，水，氧气和氢气流反应; 和（d）从反应器中排出处于特定温度的合成气（5）具有小于3mol％的甲烷，化学计量数为1.9-2.3。

公开(公告)号：WO2010122025A1

公开(公告)日：2010-10-28

申请号：PCT/EP2010/055200

申请日：2010-04-20

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  BRACHT, Maarten ,  FERNIE, Martin John

Inventor： BRACHT, Maarten ,  FERNIE, Martin John

IPC: C01B3/36 ,  C01B3/38 ,  C10G2/00

CPC classification number: C01B3/384 ,  C01B3/36 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/062 ,  C01B2203/0844 ,  C01B2203/1017 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/143 ,  C01B2203/148 ,  C10G2/32 ,  C10G2/341 ,  Y02P20/52

Abstract: The invention is directed to a process for the production of hydrocarbon products from a methane comprising feedstock comprising of the steps of : preparing a feed syngas comprising hydrogen and carbon monoxide having a hydrogen/carbon monoxide molar feed ratio in a syngas manufacturing process and using the feed syngas in a Fischer-Tropsch process using one or more fixed bed catalyst beds as present in one or more syngas conversion reactors thereby obtaining the hydrocarbon product and an residual tail gas. The manufacturing process comprises of two parallel operated syngas manufacturing processes starting from the same gaseous methane comprising feedstock. One syngas manufacturing process is a partial oxidation (POX) process which prepares a syngas having a hydrogen/carbon monoxide [H 2 /CO] molar ratio below the molar feed ratio and The second syngas manufacturing process is a heat exchange reforming (HER) process, which prepares a syngas having a hydrogen/carbon monoxide [H 2 /CO] molar ratio above the molar feed ratio.

Abstract translation: 本发明涉及从包含原料的甲烷生产烃产物的方法，包括以下步骤：在合成气制备过程中制备包含氢气和一氧化碳摩尔进料比的氢气和一氧化碳的进料合成气，并使用 在一种或多种合成气转化反应器中使用一种或多种固定床催化剂床在费 - 托工艺中进料合成气，从而获得烃产物和残余尾气。 该制造方法包括从包含原料的相同气态甲烷开始的两个平行操作的合成气制造方法。 一种合成气制造方法是部分氧化（POX）方法，其制备具有低于摩尔进料比的氢/一氧化碳[H 2 / CO]摩尔比的合成气，第二合成气制备方法是热交换重整（HER）方法， 其制备具有高于摩尔进料比的氢/一氧化碳[H 2 / CO]摩尔比的合成气。

公开(公告)号：WO2010037093A3

公开(公告)日：2010-07-22

申请号：PCT/US2009058769

申请日：2009-09-29

Applicant: GTLPETROL LLC ,  ALLAM RODNEY J

Inventor： ALLAM RODNEY J

IPC: C10J3/20 ,  C10J3/86

CPC classification number: C01B3/38 ,  C01B3/36 ,  C01B3/382 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/0844 ,  C01B2203/0894 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/1282 ,  C01B2203/141 ,  C01B2203/82 ,  Y02P20/129 ,  Y02P20/142

Abstract: In various systems and processes, synthesis gas generation may be combined. A partial oxidation reactor (POX) and a gas convectively heated steam/hydrocarbon catalytic reformer (GHR) may be combined to produce synthesis gas. In some implementations, a partial oxidation reactor, a gas convectively heated steam/catalytic reformer, and a waste hat boiler may be combined to produce synthesis gas.

Abstract translation: 在各种系统和方法中，可以组合合成气生成。 可以组合部分氧化反应器（POX）和气体对流加热的蒸汽/烃催化重整器（GHR）以产生合成气。 在一些实施方案中，可以组合部分氧化反应器，气体对流加热的蒸汽/催化重整器和废帽式锅炉，以产生合成气。

公开(公告)号：WO2009079434A1

公开(公告)日：2009-06-25

申请号：PCT/US2008/086771

申请日：2008-12-15

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  CUI, Jingyu ,  ENGWALL, Erik Edwin ,  JOSHI, Mahendra Ladharam ,  WELLINGTON, Scott Lee

Inventor： CUI, Jingyu ,  ENGWALL, Erik Edwin ,  JOSHI, Mahendra Ladharam ,  WELLINGTON, Scott Lee

IPC: H01M8/06

CPC classification number: H01M8/0662 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/041 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/066 ,  C01B2203/0833 ,  C01B2203/0844 ,  C01B2203/1058 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/86 ,  H01M8/04097 ,  H01M8/0618 ,  Y02P30/30

Abstract: The present invention is directed to a process for generating electricity in a solid oxide fuel cell system. A mixture of steam and a hydrocarbon containing feed is reformed to produce a reformed product gas containing hydrogen. A first gas stream containing at least 0.6 mole fraction hydrogen is separated from the reformed product gas and fed to the anode of a solid oxide fuel cell. The first gas stream is mixed with an oxidant at one or more anode electrodes in the fuel cell to generate electricity. An anode exhaust stream comprising hydrogen and water is separated from the fuel cell. The anode exhaust stream and/or a cathode exhaust stream from the fuel cell is fed into the reforming reactor, where heat is exchanged between the hot anode and/or cathode exhaust streams and the reactants in the reforming reactor.

Abstract translation: 本发明涉及一种在固体氧化物燃料电池系统中发电的方法。 将蒸汽和含烃进料的混合物重整以产生含氢的重整产物气体。 将含有至少0.6摩尔分数氢的第一气流与重整产物气体分离，并送入固体氧化物燃料电池的阳极。 将第一气流与燃料电池中的一个或多个阳极电极上的氧化剂混合以发电。 包含氢和水的阳极废气流与燃料电池分离。 来自燃料电池的阳极排气流和/或阴极排气流被供给到重整反应器中，其中在热阳极和/或阴极排气流与重整反应器中的反应物之间进行热交换。