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公开(公告)号:WO2015000891A1
公开(公告)日:2015-01-08
申请号:PCT/EP2014/063946
申请日:2014-07-01
Applicant: AGFA-GEVAERT
Inventor: BOLLEN, Dirk , VRIAMONT, Nicolas , LOCCUFIER, Johan
CPC classification number: C09D11/52 , B22F1/0022 , B22F9/24 , C08K5/20 , C09D1/00 , C09D7/20 , C09D7/66 , C09D11/037 , H05K1/097
Abstract: A metallic nanoparticle dispersion comprising metallic nanoparticles characterized in that the dispersion comprises less than 50 μmol/g metal of an inorganic acid or a compound capable of generating such an acid during curing of a metallic layer or pattern formed from the dispersion. The presence of such small amounts an inorganic acid increases the conductivity of metallic layers or patterns formed from the metallic nanoparticle dispersions at moderate curing conditions.
Abstract translation: 一种包含金属纳米颗粒的金属纳米颗粒分散体,其特征在于,在由分散体形成的金属层或图案的固化期间,分散体包含小于50μmol/ g的无机酸金属或能够产生这种酸的化合物。 这种少量的无机酸的存在增加了在中等固化条件下由金属纳米颗粒分散体形成的金属层或图案的导电性。
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公开(公告)号:WO2016189016A1
公开(公告)日:2016-12-01
申请号:PCT/EP2016/061756
申请日:2016-05-25
Applicant: AGFA-GEVAERT
Inventor: BOLLEN, Dirk , VRIAMONT, Nicolas , VAN AERT, Hubertus
IPC: H05K1/09 , C09D11/101 , C09D11/52 , H01B1/22 , H05K3/12 , C09D127/08 , C09D167/00
CPC classification number: C09D11/52 , B41F15/00 , B41J2/01 , C08K2003/0806 , C09D11/033 , C09D11/037 , C09D11/101 , C09D11/104 , C09D11/106 , C09D11/322 , C09D11/36 , C09D127/08 , C09D167/00 , C23C14/5813 , H01B1/22 , H05K1/095 , H05K1/097 , H05K3/1283 , C08K3/08 , C08L67/00
Abstract: A metallic nanoparticle dispersion comprising metallic nanoparticles, a liquid carrier and an adhesion promoting compound, characterized in that the adhesion promoting compounds is an acidic polyester.
Abstract translation: 一种金属纳米颗粒分散体,其包含金属纳米颗粒,液体载体和粘合促进化合物,其特征在于所述粘附促进化合物是酸性聚酯。
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公开(公告)号:WO2015000937A1
公开(公告)日:2015-01-08
申请号:PCT/EP2014/064023
申请日:2014-07-02
Applicant: AGFA-GEVAERT
Inventor: LOCCUFIER, Johan , VRIAMONT, Nicolas , BOLLEN, Dirk
CPC classification number: B22F9/24 , B05D1/02 , B05D3/0254 , B22F1/0022 , B22F1/0044 , B22F1/0059 , B22F2301/255 , B22F2304/05 , B82Y30/00 , C09D1/00 , C09D5/00 , C09D5/24 , C09D7/40 , C09D11/037 , C09D11/52 , C09D17/00 , H05K1/097 , H05K2203/122
Abstract: A metallic nanoparticle dispersion comprising metallic nanoparticles characterized in that the dispersion comprises a compound according to Formula (I), wherein X represents the necessary atoms to form a substituted or unsubstituted ring. The presence of small amounts of the compound according to Formula (I) increases the conductivity of metallic layers or patterns formed from the metallic nanoparticle dispersions at moderate curing conditions.
Abstract translation: 一种包含金属纳米颗粒的金属纳米颗粒分散体,其特征在于分散体包含根据式(I)的化合物,其中X表示形成取代或未取代的环的必要原子。 根据式(I)的少量化合物的存在增加了在中等固化条件下由金属纳米颗粒分散体形成的金属层或图案的导电性。
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4.
公开(公告)号:WO2015000932A1
公开(公告)日:2015-01-08
申请号:PCT/EP2014/064015
申请日:2014-07-02
Applicant: AGFA-GEVAERT
Inventor: BOLLEN, Dirk , VRIAMONT, Nicolas
CPC classification number: C09D5/24 , B05D1/42 , B05D3/007 , B05D3/107 , H05K1/097 , H05K3/1208 , H05K3/1283 , H05K3/386 , H05K2203/1131
Abstract: A method of preparing a conductive metallic layer or pattern comprising the steps of: - applying a metallic nanoparticle dispersion on a support to obtain a metallic layer or pattern, - contacting the metallic layer or pattern with a solution containing an acid or an acid precursor capable of releasing the acid during curing of the metallic layer or pattern. It has been observed that by contacting the metallic layer or pattern with a solution containing an acid or an acid precursor capable of releasing the acid, higher conductivities at moderate curing conditions are obtained.
Abstract translation: 一种制备导电金属层或图案的方法,包括以下步骤: - 在支撑体上施加金属纳米颗粒分散体以获得金属层或图案, - 使金属层或图案与含有酸或酸前体的溶液接触 在金属层或图案的固化期间释放酸。 已经观察到,通过使金属层或图案与含有能够释放酸的酸或酸前体的溶液接触,获得在适度固化条件下的较高电导率。
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5.
公开(公告)号:WO2013087376A1
公开(公告)日:2013-06-20
申请号:PCT/EP2012/073145
申请日:2012-11-21
Applicant: AGFA GRAPHICS NV , AGFA-GEVAERT
Inventor: LOCCUFIER, Johan , VRIAMONT, Nicolas , CALLANT, Paul
CPC classification number: C09B68/4257 , C09B67/0009 , C09B67/0086 , C09D11/101 , C09D11/322 , C09D11/36
Abstract: A method for preparing a surface modified organic pigment comprising the steps of a) reacting the organic pigment in an aromatic hydrocarbon solvent with a surface modifying reagent to form a surface modified organic pigment; and b) washing and drying the surface modified organic pigment; wherein the surface modifying reagent is represented by Formula (I): wherein, X is selected from the group consisting of O, S and N-R3; Y is selected from the group consisting of O, NR4; R1 to R4 are each independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkynyl group, a aralkyl group, an alkaryl group and an aryl group and heteroaryl group; with the proviso that when Y-R1 is different from OH that at least one of R2 to R4 is substituted by at least one functional group having a pKa between 2.5 and 9. Surface modified organic pigments are also disclosed.
Abstract translation: 一种制备表面改性有机颜料的方法,包括以下步骤:a)使芳族烃溶剂中的有机颜料与表面改性剂反应形成表面改性的有机颜料; 和b)洗涤和干燥表面改性有机颜料; 其中所述表面改性剂由式(I)表示:其中X选自O,S和N-R 3; Y选自O,NR4; R 1至R 4各自独立地选自氢,烷基,烯基,炔基,芳烷基,烷芳基和芳基和杂芳基; 条件是当Y-R 1不同于OH时,R 2至R 4中的至少一个被至少一个pKa在2.5和9之间的官能团取代。还公开了表面改性的有机颜料。
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公开(公告)号:WO2016189015A1
公开(公告)日:2016-12-01
申请号:PCT/EP2016/061750
申请日:2016-05-25
Applicant: AGFA-GEVAERT
Inventor: BOLLEN, Dirk , VRIAMONT, Nicolas , VAN AERT, Hubertus
IPC: H05K1/09 , C09D11/101 , C09D11/52 , H01B1/22 , H05K3/12 , C09D167/00 , C09D127/08
CPC classification number: C09D11/52 , B41F17/00 , C08K3/08 , C08K3/22 , C08K7/18 , C08K2003/0806 , C08K2003/2286 , C08K2201/005 , C08K2201/011 , C09D11/033 , C09D11/037 , C09D11/101 , C09D11/104 , C09D11/106 , C09D11/322 , C09D11/36 , H01B1/22 , H05K1/095 , H05K1/097 , H05K3/1283 , C09D127/08 , C08L67/02 , C08L27/08
Abstract: A metallic nanoparticle dispersion comprising metallic nanoparticles, a binder and a liquid carrier, characterized in that the binder is a vinylidene chloride copolymer comprising 90 wt % or less of vinylidene chloride based on the total weight of the binder.
Abstract translation: 一种包含金属纳米颗粒,粘合剂和液体载体的金属纳米颗粒分散体,其特征在于粘合剂是基于粘合剂总重量的90重量%或更少的偏二氯乙烯的偏二氯乙烯共聚物。
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7.
公开(公告)号:WO2014147079A1
公开(公告)日:2014-09-25
申请号:PCT/EP2014/055429
申请日:2014-03-18
Applicant: AGFA-GEVAERT
Inventor: BOLLEN, Dirk , VRIAMONT, Nicolas , KATONA, Jaroslav
CPC classification number: C09D5/24 , B22F9/24 , C09D11/037 , C09D11/52 , C09D17/004 , H05K1/097 , H05K3/10
Abstract: A method to prepare a metallic nanoparticle dispersion comprising the steps of: - forming a metallic precursor dispersion or solution by adding a metallic precursor to a dispersion medium comprising; (a) a solvent according to Formula I, and wherein R 1 and R 2 represent an optionally substituted alkyl group, R 1 and R 2 may form a ring, (b) a carboxylic acid according to Formula II: R-COOH wherein R is an optionally substituted C2-C7 alkyl, alkenyl or alkynyl group, - reducing the metallic precursor with a reducing agent to form metallic nanoparticles, - sedimenting the metallic nanoparticles to obtain a highly concentrated metallic nanoparticle dispersion comprising at least 15 wt % of metallic nanoparticles.
Abstract translation: 一种制备金属纳米颗粒分散体的方法,包括以下步骤: - 通过向分散介质中加入金属前体形成金属前体分散体或溶液,所述分散体包含: (a)根据式I的溶剂,并且其中R 1和R 2表示任选取代的烷基,R 1和R 2可以形成环,(b)根据式II的羧酸:R-COOH其中R是任选取代的 C 2 -C 7烷基,烯基或炔基, - 用还原剂还原金属前体以形成金属纳米颗粒, - 沉积金属纳米颗粒,以获得包含至少15重量%金属纳米颗粒的高度浓缩的金属纳米颗粒分散体。
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