公开(公告)号：WO2015010991A1

公开(公告)日：2015-01-29

申请号：PCT/EP2014/065244

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： TELES, Joaquim Henrique ,  SEELIG, Bianca ,  RIEDEL, Dominic ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  MÜLLER, Ulrich ,  PARVULESCU, Andrei-Nicolae ,  GUMLICH, Kai ,  BASSLER, Peter ,  BARTOSCH, Christian ,  JACUBINAS, Richard ,  WEIDENBACH, Meinolf ,  WITZL, Werner

IPC: B01J29/89 ,  B01J37/02 ,  C07D301/12 ,  B01J27/16

CPC classification number: C07D301/12 ,  B01J27/18 ,  B01J27/188 ,  B01J29/7038 ,  B01J29/7088 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/186 ,  Y02P20/52

Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MVVW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，任选的丙烷和至少一种溶解的含磷酸钾的液体进料流，其中钾相对的摩尔比 在磷氧基酸的至少一种钾盐中的磷在0.6至1.4的范围内; （ii）将（i）中提供的液体进料流送入包含催化剂的环氧化反应器中，所述催化剂包含含锌的结构型MVVW的钛沸石，并使液体进料流在环氧化反应器中进行环氧化反应条件，得到反应混合物 包括环氧丙烷，乙腈，水，所述至少一种溶解的含磷酸的钾盐，任选的丙烯，以及任选的丙烷; （iii）从环氧化反应器中除去流出物流，所述流出物流包含环氧丙烷，乙腈，水，所述至少一种溶解的含磷酸的钾盐，任选的丙烯和任选的丙烷的至少一部分。

公开(公告)号：WO2014177507A1

公开(公告)日：2014-11-06

申请号：PCT/EP2014/058579

申请日：2014-04-28

Applicant: BASF SE ,  THE DOW CHEMICAL COMPANY

Inventor： TELES, Joaquim Henrique ,  RIEDEL, Dominic ,  SEELIG, Bianca ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  SCHRÖDER, Alexander ,  PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  WEIDENBACH, Meinolf ,  WITZL, Werner ,  BÄR, Holger

IPC: C07D301/12

CPC classification number: C07D301/12 ,  B01D3/143 ,  C07D301/32

Abstract: A continuous process for the preparation of propylene oxide, comprising(a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log K ow ) of the at least one component B is greater than zero; (b) separating propylene oxidefrom S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3;(d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).

Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（a）在乙腈作为溶剂的存在下，在反应装置中将丙烯任选与丙烷混合，与过氧化氢反应，得到含有环氧丙烷，乙腈，水的流S0 至少一种另外的组分B，任选的丙烯和任选的丙烷，其中至少一种组分B的标准沸点高于乙腈的标准沸点，其中辛醇 - 水分配系数（log Kow）的十进制对数 所述至少一个组分B大于零; （b）从S0分离环氧丙烷，得到含有乙腈，水和至少一种其它组分B的料流S1; （c）将S1分成两股流S2和S3;（d）对S3进行分馏装置中的气 - 液分馏，得到耗尽至少一种B成分的蒸汽馏分流S4; （e）将至少一部分S4，任选地在后处理之后再循环至（a）。

公开(公告)号：WO2013160345A1

公开(公告)日：2013-10-31

申请号：PCT/EP2013/058481

申请日：2013-04-24

Applicant: BASF SE ,  BASF SCHWEIZ AG

Inventor： FEYEN, Mathias ,  MÜLLER, Ulrich ,  PARVULESCU, Andrei-Nicolae ,  SCHAACK, Bernd, Bastian ,  AHRENS, Sebastian ,  GERHARD, Dirk ,  SON, Sunghee ,  IFFLAND, Gabriele ,  SEELIG, Bianca

IPC: C01B37/02 ,  B01J29/89 ,  C01B39/08 ,  C01B39/12 ,  C01B39/40

CPC classification number: B01J29/89 ,  B01J29/40 ,  B01J29/405 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/70 ,  B01J29/88 ,  B01J35/002 ,  C01B37/02 ,  C01B39/082 ,  C01B39/12 ,  C01B39/40

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO 2 and one or more alkenyltrialkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R 1 , R 2 , and R 3 independently from one another stand for alkyl; and R 4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备沸石材料的方法，包括以下步骤：（1）提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和（2）使步骤（1）中获得的混合物结晶以获得沸石材料; 其中Y是四价元素，并且其中R 1，R 2和R 3彼此独立地代表烷基; 并且R4代表烯基，以及可以根据本发明方法获得的沸石材料及其用途。

公开(公告)号：WO2018145973A1

公开(公告)日：2018-08-16

申请号：PCT/EP2018/052409

申请日：2018-01-31

Applicant: BASF SE ,  BASF INTERSERVICIOS S.A. DE C.V. ,  BASF ESPANOLA S.L. ,  BASF PLC

Inventor： HOESSEL, Peter ,  SCHADE, Christian ,  AMELA CONESA, Cristina ,  IBARRA, Luis-Angel ,  SEELIG, Bianca ,  TOMLINSON, Andrea ,  WENDEL, Volker ,  WERNER, Rolf

IPC: A61Q5/06 ,  A61K8/81

Abstract: The present invention relates to a polymer comprising the following monomers in polymerized form (in weight %): A) 49 - 60 % of a first monomer which is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, C3-alkyl acrylate, C3-alkyl methacrylate, C4-alkyl acrylate, C4-alkyl methacrylate and mixtures thereof, B) 30 - 40 % methacrylic acid, C) 4 -15 % acrylic acid, and D) 0.02-0.30 % of a crosslinking agent which is a compound having at least two allyl moieties, wherein the sum of the amounts of monomers A to D is 100 %. Furthermore, the present invention relates to a hair styling composition comprising the polymer and to the use of the polymer or of the hair styling composition for styling hair.

公开(公告)号：WO2013117536A2

公开(公告)日：2013-08-15

申请号：PCT/EP2013/052223

申请日：2013-02-05

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  TELES, Joaquim Henrique ,  SEELIG, Bianca ,  KAMPE, Philip ,  WEBER, Markus ,  BAYER, Robert ,  SEIDEL, Karsten ,  RESCH, Peter

CPC classification number: B01J29/7088 ,  B01J29/7476 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/42 ,  C01B37/005 ,  C01B39/026 ,  C01B39/06 ,  C01B39/085 ,  C01B39/12 ,  C07D301/12 ,  Y02P20/52

Abstract: The present invention relates to a micropowder, wherein the particles of the micropowder have a Dv10 value of at least 2 micrometer and the micropowder comprises mesopores which have an average pore diameter in the range of from 2 to 50 nm and comprise, based on the weight of the micropowder, at least 95 weight-% of a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc.

Abstract translation: 本发明涉及一种微粉，其中微粉的颗粒具有至少2微米的Dv10值，并且该微粉包括平均孔径在2至50nm范围内的介孔，并且基于重量 的微粉末，至少95重量％的含有钛和锌的结构型MWW的微孔无铝沸石材料。

公开(公告)号：WO2015128204A1

公开(公告)日：2015-09-03

申请号：PCT/EP2015/053066

申请日：2015-02-13

Applicant: BASF SE

Inventor： GRAHAM, David ,  SEELIG, Bianca ,  MACK, Sandra ,  TONHAUSER, Christoph ,  HAAKE, Hans-Martin ,  WENDEL, Volker ,  GRUND, Patricia ,  HAUKE, Martin ,  JECK, Sylvia ,  SCHRÖDER, Björn

IPC: C08F220/54 ,  C08F2/04

CPC classification number: A61K8/8158 ,  A61K8/88 ,  A61Q5/06 ,  C08F2/04 ,  C08F220/54 ,  C08F220/56 ,  C08F220/58 ,  C08F2220/1808 ,  C08F220/06

Abstract: The present invention relates to a method for making a copolymer comprising polymerizing the monomers in a solution comprising the monomers and a solvent, wherein the solvent comprises water and an alcohol. Furthermore, the present invention relates to the copolymer obtainable by this method ("the copolymer according to the present invention") and to the use of the copolymer according to the present invention for styling or for fixing human hair. Furthermore, the present invention relates to the use of a more generally defined copolymer for styling or for fixing human hair, and for providing high gloss to the hair that is styled or fixed.

Abstract translation: 本发明涉及一种制备共聚物的方法，其包括使单体在包含单体和溶剂的溶液中聚合，其中溶剂包括水和醇。 此外，本发明涉及通过该方法获得的共聚物（“本发明的共聚物”）以及根据本发明的共聚物用于造型或固定人发的用途。 此外，本发明涉及更一般地限定的共聚物用于造型或固定人发，以及为被定型或固定的头发提供高光泽度的用途。

公开(公告)号：WO2013113578A1

公开(公告)日：2013-08-08

申请号：PCT/EP2013/051034

申请日：2013-01-21

Applicant: BASF SE ,  BASF SCHWEIZ AG

Inventor： TELES, Joaquim Henrique ,  KLOPSCH, Rainer ,  SEELIG, Bianca

IPC: C07D301/12 ,  C07D303/48

CPC classification number: C07D303/48 ,  C07D301/12

Abstract: Verfahren zur Herstellung von Epoxiden der Formel (I) worin R für eine organische Gruppe mit 1 bis 10 C-Atomen steht, durch Umsetzung von Verbindungen der Formel (II) mit einem Oxidationsmittel, dadurch gekennzeichnet, dass die Herstellung kontinuierlich in einem Rohreaktor erfolgt.

Abstract translation: 一种制备式（I）其中R表示碳原子数1〜10的有机基团，环氧化物的通过与氧化剂反应式（II）的化合物的方法，其特征在于，生产连续发生在管状反应器。

公开(公告)号：WO2012065879A1

公开(公告)日：2012-05-24

申请号：PCT/EP2011/069626

申请日：2011-11-08

Applicant: BASF SE ,  MILLER, Jeremie ,  TELES, Joaquim Henrique ,  KLOPSCH, Rainer ,  SEELIG, Bianca

Inventor： MILLER, Jeremie ,  TELES, Joaquim Henrique ,  KLOPSCH, Rainer ,  SEELIG, Bianca

IPC: C07D317/34

CPC classification number: C07D317/34

Abstract: A process for the preparation of 2-oxo-[1,3] dioxolane-4-carboxylic acid esters of formula (I) with R being an organic group comprising 1 to 10 carbon atoms, wherein an oxirane-2-carboxylic acid ester of formula (II) is reacted with carbon dioxide (CO 2 ) at a pressure of at least 35 bars and a temperature of 60 to 80°C.

Abstract translation: 一种制备式（I）的2-氧代 - [1,3]二氧戊环-4-羧酸酯的方法，其中R是含1-10个碳原子的有机基团，其中环氧乙烷-2-羧酸酯是 式（II）在至少35巴的压力和60至80℃的温度下与二氧化碳（CO 2）反应。

公开(公告)号：WO2015059171A1

公开(公告)日：2015-04-30

申请号：PCT/EP2014/072609

申请日：2014-10-22

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  LÜTZEL, Hans-Jürgen ,  TELES, Joaquim Henrique ,  RIEDEL, Dominic ,  SEELIG, Bianca ,  URBANCZYK, Daniel ,  WEGERLE, Ulrike ,  HESSE, Michael ,  WALCH, Andreas ,  BENDIG, Volker ,  STEGMANN, Veit ,  ALTHÖFER, Henning ,  GASPAR, Boris ,  STALLMACH, Frank ,  PUSCH, Anne Kristin

IPC: B01J29/89 ,  B01J29/035 ,  B01J35/10 ,  B01J37/00 ,  C01B39/08 ,  B01J37/10 ,  B01J39/14 ,  B01J20/10 ,  B01J35/02

CPC classification number: B01J29/89 ,  B01J20/183 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28059 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3085 ,  B01J29/035 ,  B01J35/002 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0018 ,  B01J37/10 ,  B01J39/14 ,  B01J2229/183 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/085 ,  C01B39/40

Abstract: The present invention relates to A process for the production of a molding, comprising (I) providing a zeolitic material; (II) mixing the zeolitic material provided in step (I) with one or more binders; (III) kneading of the mixture obtained in step (II); (IV) molding of the kneaded mixture obtained in step (III) to obtain one or more moldings; (V) drying of the one or more moldings obtained in step (IV); and (VI) calcining of the dried molding obtained in step (V); wherein the zeolitic material provided in step (I) displays a water adsorption ranging from 1 to 15 wt.-% when exposed to a relative humidity of 85%, as well as to a molding obtainable or obtained according to the inventive process in addition to a molding per se and to their respective use.

Abstract translation: 本发明涉及一种用于生产模制品的方法，包括（I）提供沸石材料; （II）将步骤（I）中提供的沸石材料与一种或多种粘合剂混合; （III）捏合步骤（II）中获得的混合物; （IV）成型步骤（III）中获得的捏合混合物以获得一种或多种模制品; （V）干燥步骤（IV）中获得的一种或多种模制品; 和（VI）煅烧步骤（V）中获得的干燥模塑物; 其中步骤（I）中提供的沸石材料当暴露于85％的相对湿度时显示出1至15重量％的水吸附，以及根据本发明方法获得或获得的模制物，除了 成型本身及其各自的用途。

公开(公告)号：WO2015010994A1

公开(公告)日：2015-01-29

申请号：PCT/EP2014/065256

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  TELES, Joaquim Henrique ,  SEELIG, Bianca ,  KAMPE, Philip ,  WEBER, Markus ,  RESCH, Peter ,  BARTOSCH, Christian ,  RIEDEL, Dominic ,  URBANCZYK, Daniel ,  SCHRÖDER, Alexander ,  WEGERLE, Ulrike

IPC: B01J29/90 ,  B01J29/89 ,  B01J37/06 ,  C07D301/12 ,  C07D303/04 ,  B01J38/48 ,  B01J37/10 ,  B01J29/70 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J29/90 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/00 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  B01J38/02 ,  B01J38/06 ,  B01J38/48 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/42 ,  C07D301/12 ,  C07D303/04 ,  Y02P20/584

Abstract: The present invention relates to a process for the regeneration of a catalyst comprising a titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than 300 °C; (d) calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300 °C.

Abstract translation: 本发明涉及一种用于再生包含含钛沸石的催化剂的方法，所述催化剂已用于制备烯烃氧化物并沉积有磷酸盐的方法中，所述再生方法包括以下步骤： （a）将反应混合物与催化剂分离，（b）用液体水系洗涤由（a）获得的催化剂; （c）任选地在低于300℃的温度下将包含惰性气体的气流中的（b）得到的催化剂干燥; （d）在至少300℃的温度下，将由（c）得到的催化剂在包含氧的气​​流中煅烧。