公开(公告)号：WO2014170839A3

公开(公告)日：2014-10-23

申请号：PCT/IB2014/060759

申请日：2014-04-16

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： BRUDER, Ingmar ,  SENS, Rüdiger ,  WONNEBERGER, Henrike ,  BERGMANN, Hermann ,  SEND, Robert ,  GETAUTIS, Vytautas ,  DASKEVICIENE, Maryte ,  MALINAUSKAS, Tadas

IPC分类号： C07C211/20 ,  C07C211/39 ,  C07C211/43 ,  C07C211/61 ,  C09K11/06 ,  H01L31/04 ,  H01L51/42

摘要： The present invention relates to 9,9'-spirobifluorene compounds of general formula I wherein the variables have the meaning R 11 , R 12 , R 21 , R 22 ,R 31 , R 32 , R 41 and R 42 independently of each other aryl or hetaryl, S 1 , S 2 , S 3 and S 4 independently of each other π-conjugated, bivalent moieties, n 1 , n 2 , n 3 and n 4 independently of each other 0, 1, 2 or 3, with the proviso that n 1 + n 2 + n 3 + n 4 ≠ 0, in case n 1 ≥ 2, n 2 ≥ 2, n 3 ≥ 2 and/or n 4 ≥ 2 the moieties S 1 , S 2 , S 3 and S 4 are identical to or different from each other and in case n 1 + n 2 + n 3 + n 4 = 12 not all of the radicals R 11 , R 12 , R 21 , R 22 , R 31 , R 32 , R 41 and R 42 are identical, to the use of compounds of general formula I in organic electronics applications, especially in organic field effect transistors, in organic photodetectors and organic solar cells, specifically in dye-sensitized solar cells and bulk heterojunction solar cells, and to an organic field effect transistor, a dye-sensitized solar cell and a bulk heterojunction solar cell comprising compounds of general formula I.

摘要翻译： 本发明涉及通式I的9,9'-螺二芴化合物，其中变量具有R 11，R 12，R 12， R 21，R 22，R 31，R 32，R 41和 R 42彼此独立地为芳基或杂芳基，S 1，S 2，S 3和S ^{4彼此独立地为0,1,2或3，条件是n 1 + n 2 + n 3 + 3 > + n <4>≠0，如果n <1> 2，n <2>≥2，n <3> ≥ 2和/或n 4≥2的部分S 1，S 2，S 3和S 4 彼此相同或不同，并且在n <1> + n <2> + n <3> + n 4 = 12时，不是所有的基团R 11，R 12，R 21， R 22，R 31，R 32，R 41和R 42是 与在有机电子应用中，特别是在有机场效应晶体管中，在有机光电探测器和有机太阳能电池中，特别是在染料敏化太阳能电池和本体异质结太阳能电池中以及有机场效应中使用通式I化合物 晶体管，染料敏化太阳能电池和包含通式I化合物的本体异质结太阳能电池。}

公开(公告)号：WO2014037847A3

公开(公告)日：2014-03-13

申请号：PCT/IB2013/058018

申请日：2013-08-27

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： BRUDER, Ingmar ,  SENS, Rüdiger ,  SEND, Robert ,  WONNEBERGER, Henrike ,  BERGMANN, Hermann ,  GETAUTIS, Vytautas ,  DASKEVICIENE, Maryte ,  MALINAUSKAS, Tadas ,  TOMKUTE-LUKSIENE, Daiva

IPC分类号： C07C211/60 ,  C09K11/06 ,  H01G9/20 ,  H01L31/0232 ,  H01L31/0256 ,  H01L51/46

摘要： Disclosed are 9,9 '-spirobifluorene compounds of formula I wherein the variables R 11 , R 12 , R 21 , R 22 , R 31 , R 32 , R 41 and R 42 independently are aryl or hetaryl, with the proviso that not all of the radicals are identical, the use of compounds of formula I in organic electronics applications, especially in organic field effect transistors, organic photodetectors and organic solar cells, specifically in dye-sensitized solar cells and bulk heterojunction solar cells and organic field effect transistors, dye-sensitized solar cells and bulk heterojunction solar cells comprising of formula I.

公开(公告)号：WO2014006544A2

公开(公告)日：2014-01-09

申请号：PCT/IB2013/055252

申请日：2013-06-26

申请人： BASF SE ,  BASF SCHWEIZ AG ,  BASF (CHINA) COMPANY LIMITED

发明人： BRUDER, Ingmar ,  SEND, Robert ,  URNIKAITE, Simona ,  MALINAUSKAS, Tadas ,  DASKEVICIENE, Maryte ,  GETAUTIS, Vytautas

CPC分类号： H01G9/2059 ,  C09B26/02 ,  C09B26/04 ,  C09B57/008 ,  H01L51/006 ,  H01L51/0064 ,  Y02E10/542 ,  Y02E10/549

摘要： The present invention relates to compounds of general formula (I) wherein R 100 and R 200 are each independently hydrogen, C 1 -C 10 -alkyl which in case of C 2 -alkyl may be interrupted by one and in case of C 3 -C 10 -alkyl by one or two non- adjacent oxygen atoms, C 5 -C 7 -cycloalkyl, aryl, aryl-C 1 -C 10 -alkyl or aryloxy-C 1 -C 10 -alkyl, D is an m-valent (m = 1, 2 or 3) donor moiety which comprises at least one carbon- carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, A is an acceptor moiety which comprises at least one carbon- carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, and the donor moiety D and the acceptor moiety A are π- conjugated to one another. Furthermore, the present invention relates to the use of compounds of formula (I) for producing dye-sensitized solar cells and to dye-sensitized solar cells comprising compounds of formula (I).

摘要翻译： 本发明涉及通式（I）的化合物，其中R100和R200各自独立地为氢，在C2-烷基的情况下，C1-C10-烷基可以被一个间隔，在C3-C10-烷基的情况下， 两个不相邻的氧原子，C 5 -C 7 - 环烷基，芳基，芳基-C 1 -C 10 - 烷基或芳氧基-C 1 -C 10 - 烷基，D是m价（m = 1,2或3）供体部分，其包含 至少一个碳 - 碳或碳 - 杂原子双键和/或至少一个未融合或稠合的碳 - 或杂环，A是受体部分，其包含至少一个碳 - 碳或碳 - 杂原子双键和/或 至少一个未融合或融合的碳环或杂环，并且供体部分D和受体部分A彼此结合。 此外，本发明涉及式（I）化合物用于生产染料敏化太阳能电池和包含式（I）化合物的染料敏化太阳能电池的用途。

公开(公告)号：WO2015161989A1

公开(公告)日：2015-10-29

申请号：PCT/EP2015/056960

申请日：2015-03-31

申请人： BASF SE

发明人： SEND, Robert ,  BRUDER, Ingmar ,  WONNEBERGER, Henrike ,  AGARI, Michaela ,  GETAUTIS, Vytautas ,  DASKEVICIENE, Maryte ,  MALINAUSKAS, Tadas

IPC分类号： C09K11/06 ,  C07C211/00 ,  H05B33/10 ,  H01L31/0224

CPC分类号： C09K11/06 ,  C07C217/92 ,  C07C217/94 ,  C07C2603/18 ,  C07D279/22 ,  C07D333/20 ,  C09B21/00 ,  C09B23/04 ,  C09B23/141 ,  C09B57/008 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  H01G9/20 ,  H01L51/42 ,  H05B33/10

摘要： The present invention relates to hole-transport materials for organic solar cells or organic optical sensors. In particular the present invention relates to a compound of general formula (I), wherein A is a group which connects all L moieties by a π-conjugated system which is formed by olefinic groups, aromatic groups, heteroaromatic groups, sandwich groups, atoms with unbound electron pairs, or combinations thereof, Z is hydrogen, an alkyl group, an aryl group, or a heteroaryl group, R 1 , R 2 , R 3 , R 4 are independent of each other alkyl groups, aryl groups, or heteroaryl groups, n is an integer of at least 2.

摘要翻译： 本发明涉及有机太阳能电池或有机光学传感器的空穴传输材料。 具体而言，本发明涉及通式（I）的化合物，其中A是通过π-共轭体系连接所有L部分的基团，其通过烯属基团，芳族基团，杂芳族基团，夹心基团，原子与 未结合的电子对或其组合，Z是氢，烷基，芳基或杂芳基，R 1，R 2，R 3，R 4彼此独立地是烷基，芳基或杂芳基，n是 至少2的整数。