IRON- AND COPPER-CONTAINING ZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOX
    1.
    发明申请
    IRON- AND COPPER-CONTAINING ZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOX 审中-公开
    含钴和铜含量的沸石合成及其在选择性催化还原NOX中的应用

    公开(公告)号:WO2013118063A1

    公开(公告)日:2013-08-15

    申请号:PCT/IB2013/050984

    申请日:2013-02-06

    摘要: The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of (1) preparing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , and seed crystals comprising one or more zeolitic materials having a BEA-type framework structure; (2) crystallizing the mixture obtained in step (1); and (3) subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu and/or Fe; wherein Y is a tetravalent element, and X is a trivaient element, wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as structure-directing agent, and wherein the total amount of Cu and/or Fe in the ion-exchanged material obtained in step (3) ranges from 0.1 to 25 wt.-% calculated as Fe 2 O 3 and CuO, as well as to a zeolitic material having a BEA-type framework structure which may be obtained according to said process, and to a method for the treatment of NO x by selective catalytic reduction (SCR) using said zeolitic material.

    摘要翻译: 本发明涉及一种生产具有包含YO 2和X 2 O 3的BEA型骨架结构的沸石材料的方法,其中所述方法包括以下步骤:(1)制备包含一种或多种Y 2 O 2源,一种或多种 X2O3的来源,以及包含一种或多种具有BEA型骨架结构的沸石材料的晶种; (2)使步骤(1)中获得的混合物结晶; 和(3)使具有步骤(2)中获得的BEA型骨架结构的沸石材料与Cu和/或Fe进行离子交换程序; 其中Y是四价元素,X是三元素,其中在步骤(1)中提供并在步骤(2)中结晶的混合物不含作为结构导向剂的有机模板,并且其中Cu和/ 在步骤(3)中获得的离子交换材料中的Fe或Fe按照Fe 2 O 3和CuO计算为0.1至25重量%,以及具有BEA型骨架结构的沸石材料,其可以根据所述 方法以及使用所述沸石材料通过选择性催化还原(SCR)处理NOx的方法。