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1.发明申请
公开(公告)号：WO2018113566A1
公开(公告)日：2018-06-28
申请号：PCT/CN2017/115938
申请日：2017-12-13
Applicant: BASF SE , XIAO, Fengshou
Inventor： XIAO, Fengshou , MCGUIRE, Robert , FEYEN, Mathias , MUELLER, Ulrich , BAO, Xinhe , ZHANG, Weiping , DE VOS, Dirk , GIES, Hermann , TOSHIYUKI, Yokoi , KOLB, Ute , MARLER, Bernd , SHI, Chuan , PAN, Xiulian , MENG, Xiangju , MAURER, Stefan , DAI, Yu , WANG, Yong , DE BAERDEMAEKER, Trees
Abstract: A process for the preparation of a zeolitic material comprising YO 2 and X 2 O 3 in its framework structure is provided, wherein Y stands for a tetravalent element and X stands for a trivalent element. The process comprises steps of (1) preparing a mixture comprising one or more structure directing agents, seed crystals, and a first zeolitic material comprising YO 2 and X 2 O 3 in its framework structure, wherein the first zeolitic material has a framework structure selected from the group consisting of FAU-, GIS-, MOR-, and LTA-type framework structures, including mixtures of two or more thereof; (2) heating the mixture obtained in (1) for obtaining a second zeolitic material comprising YO 2 and X 2 O 3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material contained in the mixture obtained in (1); wherein the mixture prepared in (1) and heated in (2) contains 1000 wt.% or less of H 2 O based on 100 wt.% of YO 2 in the framework structure of the first zeolitic material. As well as a zeolitic material obtainable and/or obtained according to the process and its use are provided.
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公开(公告)号：WO2019154081A1
公开(公告)日：2019-08-15
申请号：PCT/CN2019/072771
申请日：2019-01-23
Applicant: BASF SE , BASF (CHINA) COMPANY LIMITED
Inventor： FEYEN, Mathias , MUELLER, Ulrich , BAO, Xinhe , ZHANG, Weiping , DE VOS, Dirk , GIES, Hermann , XIAO, Feng-Shou , YOKOI, Toshiyuki , KOLB, Ute , MARLER, Bernd , WANG, Yong , DE BAERDEMAEKER, Trees , SHI, Chuan , MENG, Xiangju , PAN, Xiulian
Abstract: A process for preparing a zeolitic material comprising Ti, having framework type CHA and having a framework structure which comprises Si and O, said process comprising (i) preparing a pre-synthesis mixture comprising water, a CHA framework structure directing agent, and a zeolitic material comprising Ti, having framework type MFI and having a framework structure which comprises Si and O; (ii) removing water from the pre-synthesis mixture obtained from (i) by heating the pre-synthesis mixture to a temperature of less than 100°C at a pressure of less than 1 bar (abs); (iii) hydrothermally crystallizing the zeolitic material comprising Ti, having framework type CHA and having a framework structure which comprises Si and O.
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3.发明申请CATALYST COMPOSITE AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOx 审中-公开催化剂复合材料及其在选择性催化还原NOx中的应用
公开(公告)号：WO2017216012A1
公开(公告)日：2017-12-21
申请号：PCT/EP2017/063856
申请日：2017-06-07
Applicant: BASF SE
Inventor： TRUKHAN, Natalia , MALTRY, Michaela , MUELLER, Ulrich , MARX, Stefan , DUMBUYA, Karifala , FEYEN, Mathias
IPC: B01J29/72 , B01D53/86 , B01D53/94 , B01J29/76 , B01J37/08 , B01J37/10 , B01J37/02 , B01J35/10 , B01J35/04
Abstract: The present invention relates to a process for the preparation of a catalyst for selective catalytic reduction comprising • (i) preparing a mixture comprising a metal-organic framework material comprising an ion of a metal or metalloid selected from groups 2-5, groups 7-9, and groups 11-14 of the Periodic Table of the Elements, and at least one at least monodentate organic compound, a zeolitic material containing a metal as a non-framework element, optionally a solvent system, and optionally a pasting agent, • (ii) calcining of the mixture obtained in (i); and further relates to a catalyst per se comprising a composite material containing an amorphous mesoporous metal and/or metalloid oxide and a zeolitic material, wherein the zeolitic material contains a metal as non-framework element, as well as to the use of said catalyst.
Abstract translation: 本发明涉及制备用于选择性催化还原的催化剂的方法，其包括：（i）制备包含金属 - 有机骨架材料的混合物，所述金属 - 有机骨架材料包含选自以下的金属或准金属的离子： 组元素周期表的第2-5族，第7-9族和第11-14族，以及至少一种至少单齿有机化合物，包含金属作为非骨架元素的沸石材料，任选的溶剂体系 （ii）煅烧在（i）中获得的混合物;和（ii）煅烧在（i）中获得的混合物。 并且进一步涉及催化剂本身包括含有一种无定形孔金属和/或准金属氧化物和沸石材料，其中所述沸石材料中含有金属作为非骨架元素，以及对使用所述催化剂的复合材料。
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4.发明申请
公开(公告)号：WO2019024909A1
公开(公告)日：2019-02-07
申请号：PCT/CN2018/098471
申请日：2018-08-03
Applicant: BASF SE , BASF (CHINA) COMPANY LIMITED
Inventor： FEYEN, Mathias , MUELLER, Ulrich , BAO, Xinhe , ZHANG, Weiping , DE VOS, Dirk , GIES, Hermann , XIAO, Feng-Shou , YOKOI, Toshiyuki , KOLB, Ute , MARLER, Bernd , WANG, Tong , DE BAERDEMAEKER, Trees , SHI, Chuan , PAN, Xiulian , MENG, Xiangju
IPC: B01J29/064 , B01D53/94
Abstract: A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In.A process for preparing such a zeolitic material. Use of such a zeolitic material.
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5.发明申请CHA TYPE ZEOLITIC MATERIALS AND METHODS FOR THEIR PREPARATION USING COMBINATIONS OF CYCLOALKYL- AND TETRAALKYLAMMONIUM COMPOUNDS 审中-公开CHA类型的ZEOLITIC材料及其使用环己基 - 和四氨基亚甲基化合物的组合制备方法
公开(公告)号：WO2015185625A2
公开(公告)日：2015-12-10
申请号：PCT/EP2015/062377
申请日：2015-06-03
Applicant: BASF SE
Inventor： FEYEN, Mathias , YANG, Jeff , RUETZ, Roger , MÜLLER, Ulrich
IPC: C01B39/48
CPC classification number: C01B39/48 , B01J20/18 , B01J20/3057 , B01J20/3085 , B01J29/7015 , B01J29/763 , B01J35/002 , B01J35/023 , B01J37/0018 , B01J37/0246 , B01J39/02 , B01J39/14 , B01J2229/186 , B01J2229/42
Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , one or more tetraalkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds, and one or more tetraalkylammonium cation R 5 R 6 R 7 R 8 N + -containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 independently from one another stand for alkyl, and wherein R 8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
Abstract translation: 本发明涉及一种制备具有包含YO 2和X 2 O 3的CHA型骨架结构的沸石材料的方法，其中所述方法包括以下步骤：（1）提供包含一种或多种YO 2， 更多的X2O3，一种或多种四烷基铵阳离子R1R2R3R4N +的化合物来源，以及一种或多种四烷基铵阳离子R5R6R7R8N +化合物作为结构导向剂; （2）使步骤（1）中得到的混合物结晶得到具有CHA型骨架结构的沸石材料; 其中Y是四价元素，X是三价元素，其中R 1，R 2，R 3，R 4，R 5，R 6和R 7彼此独立地代表烷基，并且其中R8代表环烷基，以及沸石材料， 可以根据本发明的方法和它们的用途获得。
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Patent Agency Ranking6.发明申请PROCESS FOR THE OXYGEN FREE CONVERSION OF METHANE TO ETHYLENE ON ZEOLITE CATALYSTS 审中-公开甲醇在乙酸乙酯中自由转化成沸石催化剂的方法
公开(公告)号：WO2015018807A2
公开(公告)日：2015-02-12
申请号：PCT/EP2014/066757
申请日：2014-08-05
Applicant: BASF SE , TOKYO INSTITUTE OF TECHNOLOGY
Inventor： FEYEN, Mathias , MÜLLER, Ulrich , BAO, Xinhe , ZHANG, Weiping , DE VOS, Dirk , GIES, Hermann , TATSUMI, Takashi , XIAO, Feng-Shou , GUO, Xiaoguang
IPC: B01J29/04
CPC classification number: C07C2/76 , B01J29/0358 , B01J29/061 , B01J29/48 , B01J29/72 , B01J29/78 , B01J29/7815 , B01J29/80 , B01J29/85 , B01J29/90 , B01J38/10 , B01J2229/186 , C07C2529/74 , C07C2529/76 , C07C2529/78 , C07C2529/80 , Y02P20/52 , Y02P20/582 , Y02P20/584 , Y02P20/588 , C07C11/04
Abstract: The present invention relates to a process for the oxygen free conversion of methane to ethylene on zeolite catalysts and catalysts comprising a zeolite, a metal and a further component.
Abstract translation: 本发明涉及一种在沸石催化剂上甲烷无氧转化成乙烯的方法和包含沸石，金属和其它组分的催化剂。
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公开(公告)号：WO2014154429A1
公开(公告)日：2014-10-02
申请号：PCT/EP2014/053702
申请日：2014-02-26
Applicant: BASF SE
Inventor： FEYEN, Mathias , SCHAACK, Bernd Bastian , MÜLLER, Ulrich , HEIDEMANN, Thomas , WILL, Veronika , SENK, Rainer
CPC classification number: C07C2/76 , B01J29/405 , B01J29/42 , B01J29/46 , B01J29/48 , B01J29/90 , B01J33/00 , B01J38/10 , B01J2229/123 , B01J2229/186 , B01J2229/32 , C07C2527/24 , C07C2529/46 , C07C2529/48 , Y02P20/52 , Y02P20/584 , C07C15/04
Abstract: Verfahren zur Herstellung eines passivierten Katalysators, der einen Zeolith und mindestens ein aktives Metall enthält, dadurch gekennzeichnet, dass - der Katalysator in einer Wirbelschicht gehalten wird und - in der Wirbelschicht mit einer Siliciumverbindung passiviert wird.
Abstract translation: 所述催化剂被保持在流化床和 - - 一种含有沸石和至少一种活性金属，其特征在于，一个钝化的催化剂过程在流化床与硅化合物钝化。
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8.发明申请CATALYTICALLY ACTIVE BODY FOR THE SYNTHESIS OF DIMETHYL ETHER FROM SYNTHESIS GAS 审中-公开合成气体合成二甲醚的催化活性体
公开(公告)号：WO2013160133A1
公开(公告)日：2013-10-31
申请号：PCT/EP2013/057763
申请日：2013-04-15
Applicant: BASF SE , BASF SCHWEIZ AG
Inventor： SCHÄFER, Alexander , FEYEN, Mathias , PARVULESCU, Andrei-Nicolae , MüLLER, Ulrich , SCHAACK, Bernd Bastian
CPC classification number: B01J29/76 , B01J23/80 , B01J29/06 , B01J29/40 , B01J29/46 , C07C41/01 , C07C41/09 , C07C43/043
Abstract: The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.
Abstract translation: 本发明涉及从合成气合成二甲醚的催化活性体。 特别地，本发明涉及用于合成二甲醚的改进的催化活性体，其中活性体的组分包含甲醇活性组分和酸组分，该组分包含通过一个或多个烯基三烷基铵阳离子R1R2R3R4N +结晶的沸石材料， 作为结构导向剂的化合物。 此外，本发明涉及制备催化活性体的方法，催化活性体的用途以及从合成气中制备二甲醚的方法。
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9.发明申请
公开(公告)号：WO2019085800A1
公开(公告)日：2019-05-09
申请号：PCT/CN2018/111618
申请日：2018-10-24
Applicant: BASF SE , BASF (CHINA) COMPANY LTD.
Inventor： MCGUIRE, Robert , FEYEN, Mathias , MUELLER, Ulrich , ZHANG, Weiping
Abstract: The present invention relates to a process for the production of a transition metal containing zeolite comprising expanding a layered silicate with a swelling agent and introducing the transition metal into the interlayer expanded silicate prior to calcination thereof for obtaining the transition metal containing zeolite. The present invention further relates to a zeolite containing transition metal nanoparticles as obtainable or obtained according to the inventive process, as well as to a zeolite containing nanoparticles per se. Finally the present invention relates to the use of a zeolite containing transition metal nanoparticles as obtainable or obtained according to the inventive process, as well as to the use of a zeolite containing nanoparticles per se.
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10.发明申请PROCESS FOR THE PREPARATION OF A DEALUMINATED ZEOLITIC MATERIAL HAVING THE BEA FRAMEWORK STRUCTURE 审中-公开用于制备具有骨架结构的脱铝沸石材料的方法
公开(公告)号：WO2016128917A1
公开(公告)日：2016-08-18
申请号：PCT/IB2016/050715
申请日：2016-02-11
Applicant: BASF SE , BASF (CHINA) COMPANY LIMITED , TOKYO INSTITUTE OF TECHNOLOGY
Inventor： FEYEN, Mathias , MAURER, Stefan , MUELLER, Ulrich , BAO, Xinhe , ZHANG, Weiping , DE VOS, Dirk , GIES, Hermann , XIAO, Feng-Shou , TOSHIYUKI, Yokoi , YILMAZ, Bilge , OTOMO, Ryoichi
CPC classification number: C01B39/026 , B01J29/7007 , B01J35/002 , B01J2229/36 , B01J2229/37 , B01J2229/40 , C01B39/46 , C07C1/20 , C07C2529/70 , C07C11/02
Abstract: The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure comprising the steps of: (i) providing a zeolitic material having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, and wherein the zeolitic material having a BEA framework structure is obtainable and/or obtained from an organotemplate-free synthetic process; (ii) calcining the zeolitic material provided in step (i) at a temperature of 650°C or more; and (iii) treating the calcined zeolitic material obtained from step (ii) with an aqueous solution having a pH of 5 or less, as well as to zeolitic materials per se preferably obtainable according to the inventive method and to their use, and to a process for converting oxygenates to olefins employing the inventive zeolitic materials.
Abstract translation: 本发明涉及一种制备具有BEA骨架结构的经处理的沸石材料的方法，包括以下步骤：（i）提供具有BEA骨架结构的沸石材料，其中BEA骨架结构包含YO 2和X 2 O 3，其中Y 是四价元素，X是三价元素，并且其中具有BEA骨架结构的沸石材料可以从有机无模板合成方法获得和/或获得; （ii）在650℃以上的温度下煅烧步骤（i）中提供的沸石材料; 和（iii）用pH为5以下的水溶液以及根据本发明方法可获得的沸石材料本身及其用途来处理由步骤（ii）获得的煅烧沸石材料及其用途 使用本发明的沸石材料将含氧物转化为烯烃的方法。
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