公开(公告)号：WO2014205802A1

公开(公告)日：2014-12-31

申请号：PCT/CN2013/078421

申请日：2013-06-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： WU, Shaofu ,  HUO, YanLi ,  GUO, Yongjin ,  YAO, Wenbin ,  LIN, Zhiqing ,  CAI, Jie ,  CHEN, Thomas ,  QI, Yudong ,  DU, Libo ,  CHEN, Hongyu

IPC: C08L23/10 ,  H02S20/30 ,  H01L31/042 ,  F24J2/52

CPC classification number: H02S30/10 ,  C08K7/14 ,  C08K2003/323 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L2203/204 ,  F24S25/13 ,  F24S25/632 ,  H02S20/10 ,  H02S20/24 ,  H02S20/30 ,  H02S40/34 ,  H02S40/425 ,  Y02B10/12 ,  Y02E10/47

Abstract: Photovoltaic or solar module frames, racks, or frame or rack components are made from a composition comprising (A) a thermoplastic polymer, particularly a thermoplastic polyolefin, (B) a reinforcing element, particularly glass fiber, (C) a non-halogen containing, intumescent flame retardant, (D) an impact-modifier, particularly a polyolefin elastomer, (E) a coupling agent, and, optionally, (F) one or more additives such as an antioxidant, UV-stabilizer, etc. These frames provide for easy assembly without the need for screws, bolts or other metal fasteners.

Abstract translation: 光伏或太阳能模块框架，机架或框架或机架部件由包含（A）热塑性聚合物，特别是热塑性聚烯烃，（B）增强元件，特别是玻璃纤维的组合物制成，（C）非卤素 膨胀型阻燃剂，（D）抗冲改性剂，特别是聚烯烃弹性体，（E）偶联剂，和任选的（F）一种或多种添加剂如抗氧化剂，UV稳定剂等。这些框架提供 为了方便组装而不需要螺丝，螺栓或其他金属紧固件。

公开(公告)号：WO2012087441A1

公开(公告)日：2012-06-28

申请号：PCT/US2011/059697

申请日：2011-11-08

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  WEAVER, John, D. ,  WU, Shaofu ,  DOOLEY, Joseph ,  HARRIS, William, J. ,  LEE, Chang, D.

Inventor： WEAVER, John, D. ,  WU, Shaofu ,  DOOLEY, Joseph ,  HARRIS, William, J. ,  LEE, Chang, D.

IPC: B32B27/00 ,  B32B27/32 ,  B32B17/06 ,  C08F255/00 ,  C08F255/02 ,  C08L23/08 ,  C08L51/06

CPC classification number: H01L31/0481 ,  B32B17/10018 ,  B32B27/08 ,  B32B27/30 ,  B32B27/32 ,  B32B27/327 ,  B32B2323/04 ,  B32B2457/12 ,  C08F255/00 ,  C08J3/247 ,  C08K5/0025 ,  C08K5/5419 ,  C08K5/57 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2312/08 ,  Y02E10/50 ,  Y10T156/10 ,  Y10T428/24992 ,  Y10T428/31612 ,  Y10T428/31663 ,  C08L23/0892 ,  C08F230/08

Abstract: Disclosed are polyolefin copolymer films comprising alkoxysilane groups and a catalyst for crosslinking the alkoxysilane groups; wherein the crosslinking catalyst is a Lewis or Bronsted acid or base compound that has a relatively high melting point and therefore initiates the crosslinking essentially only at the lamination temperature, preferably at or above at least 50° C. Also disclosed are films wherein (i) the layer or layers comprising the alkoxysilane groups, including surface layer(s), comprise the crosslinking catalyst; or (ii) layer or layers comprising alkoxysilane groups do not contain crosslinking catalyst and have a facial surface in adhering contact with a layer of a thermoplastic polyolefin copolymer comprising the crosslinking catalyst; or (iii) there is a combination of layers (i) and (ii). Also disclosed are laminated glass structures and processes for their preparation that employ such films. The disclosed laminate structures include safety glass and photovoltaic modules.

Abstract translation: 公开了包含烷氧基硅烷基团和用于交联烷氧基硅烷基团的催化剂的聚烯烃共聚物膜; 其中所述交联催化剂是具有较高熔点的路易斯或布朗斯台德酸或碱性化合物，因此基本上仅在层压温度，优选等于或高于至少50℃引发交联。还公开了其中（i） 包含烷氧基硅烷基团（包括表面层）的层包含交联催化剂; 或（ii）包含烷氧基硅烷基的层或层不含有交联催化剂，并且具有与包含交联催化剂的热塑性聚烯烃共聚物层粘合接触的面部表面; 或（iii）存在层（i）和（ii）的组合。 还公开了夹层玻璃结构及其制备方法，其采用这种膜。 公开的层压结构包括安全玻璃和光伏模块。

公开(公告)号：WO2011153540A1

公开(公告)日：2011-12-08

申请号：PCT/US2011/039305

申请日：2011-06-06

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu ,  NIEMANN, Debra, H.

Inventor： NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu ,  NIEMANN, Debra, H.

IPC: C08L23/00 ,  H01L31/00 ,  C08F210/02

CPC classification number: H05K1/0353 ,  B32B17/10018 ,  B32B17/1055 ,  B32B17/10697 ,  C08F210/16 ,  C08L23/08 ,  H01L31/0481 ,  Y02E10/50 ,  C08L2666/24 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/26

Abstract: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; and; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145°C) and 'H-NMR (125°C), (2) a graft polymer to enhance the adhesion, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt% based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.

Abstract translation: 一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含 总聚合物密度不大于0.905g / cm3; 总不饱和度不超过125 / 100,000个碳; 和; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 和总数（1000 / Mn）的乙烯基/ 1000个碳的总数，其中乙烯基-3含量和乙烯基测量通过凝胶渗透色谱法（145℃）和1 H-NMR（125° C），（2）接枝聚合物，以增加粘合力，（3）任选的自由基引发剂或光引发剂，其量为基于共聚物重量的至少约0.05重量％，和（3）任选地， 共混剂的量为至少约0.05重量％，基于共聚物的重量。

公开(公告)号：WO2012134992A2

公开(公告)日：2012-10-04

申请号：PCT/US2012/030276

申请日：2012-03-23

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  WU, Shaofu ,  CHEN, Xuming ,  DE GRAAF, Michael A. ,  ERSKINE, Steven R. ,  FEIST, Rebekah K.

Inventor： WU, Shaofu ,  CHEN, Xuming ,  DE GRAAF, Michael A. ,  ERSKINE, Steven R. ,  FEIST, Rebekah K.

IPC: H01L31/055

CPC classification number: C09K11/025 ,  B32B17/10669 ,  B32B17/10678 ,  B32B2457/12 ,  H01L31/0481 ,  H01L31/055 ,  Y02E10/52

Abstract: Disclosed are thermoplastic resin formulations for use as a light transmitting layer (e.g., encapsulant layer) in a photovoltaic module comprising: (a) a light transmitting thermoplastic resin, (b) at least one down conversion material that exhibits a maximum in incident radiation absorption in the range of 280 to 500 nm and a maximum in radiation emission at a relatively longer wavelength in the range of 400 to 900 nm and improves the efficiency of photovoltaic electric current generation in a photovoltaic module; and (c) a light stabilizer additive that transmits at least about 40 percent of the ultraviolet (UV) electromagnetic radiation having a wavelength in the range of from about 280 nm to about 380 nm. Also disclosed are sheet materials prepared from such resins and photovoltaic modules incorporating such sheet materials.

Abstract translation: 公开了用作光伏模块中的光透射层（例如，密封剂层）的热塑性树脂配方，其包括：（a）透光热塑性树脂，（b）至少一种在入射辐射吸收中呈现最大值的向下转换材料 在280〜500nm的范围内，并且在400〜900nm的范围内的相对较长的波长处的辐射发射最大，并且提高了光伏模块中的光电流产生的效率; 和（c）光透过至少约40％的紫外线（UV）电磁辐射的光稳定剂添加剂，其波长在约280nm至约380nm的范围内。 还公开了由这种树脂制备的片材和包含这种片材的光伏模块。

公开(公告)号：WO2012082261A1

公开(公告)日：2012-06-21

申请号：PCT/US2011/059690

申请日：2011-11-08

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  WU, Shaofu ,  CHU, Lih-Long ,  WEAVER, John, D. ,  NAUMOVITZ, John, A, ,  ABEL, Richard, C.

Inventor： WU, Shaofu ,  CHU, Lih-Long ,  WEAVER, John, D. ,  NAUMOVITZ, John, A, ,  ABEL, Richard, C.

IPC: C08F255/00 ,  C08F255/02 ,  B32B27/00 ,  C08L51/06 ,  C09D151/06 ,  C09J151/06 ,  C08L23/08

CPC classification number: H01L31/1876 ,  B32B17/10018 ,  B32B2323/04 ,  B32B2457/12 ,  C08F255/02 ,  C08J5/18 ,  C08J2351/06 ,  H01L31/0481 ,  Y02E10/50 ,  C08F230/08

Abstract: Disclosure are films based on alkoxysilane -containing polyolefin resins with reduced melt strength, photovoltaic cell laminate structures and methods for their preparation. In the disclosed alkoxysilane -containing polyolefin resin films according to the invention, reduced melt strength is provided by, among other things, using optimized silane initiator ratios and is shown to reduce detrimental film shrinkage and provide improved photovoltaic laminate structures.

Abstract translation: 公开的是基于具有降低的熔体强度的含烷氧基硅烷的聚烯烃树脂的膜，光伏电池层压结构及其制备方法。 在所公开的根据本发明的含烷氧基硅烷的聚烯烃树脂膜中，通过使用优化的硅烷引发剂比率提供降低的熔体强度，并且显示出减少有害的膜收缩并提供改进的光伏层压结构。

公开(公告)号：WO2012039914A1

公开(公告)日：2012-03-29

申请号：PCT/US2011/050330

申请日：2011-09-02

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  NIEMANN, Debra, H. ,  NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu

Inventor： NIEMANN, Debra, H. ,  NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu

IPC: B32B27/32 ,  B32B27/20 ,  B32B17/10 ,  H01L31/048

CPC classification number: H01L31/0481 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/1055 ,  B32B2457/12 ,  Y02E10/50

Abstract: An electronic device module such as a solar cell is described. The electronic device module is made using a polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising a tapered block copolymer comprising an A block, and a B block.

Abstract translation: 描述了诸如太阳能电池的电子设备模块。 电子器件模块使用与电子器件的至少一个表面紧密接触的聚合物材料制成，聚合物材料包含包含A嵌段和B嵌段的渐缩嵌段共聚物。

公开(公告)号：WO2011163025A1

公开(公告)日：2011-12-29

申请号：PCT/US2011/040492

申请日：2011-06-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu ,  NIEMANN, Debra, H.

Inventor： NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu ,  NIEMANN, Debra, H.

IPC: B32B17/10 ,  H01L31/048

CPC classification number: H01L31/0203 ,  B32B17/10018 ,  B32B17/1055 ,  B32B17/10697 ,  B32B17/10788 ,  C08L23/0815 ,  C08L2203/204 ,  H01L31/0481 ,  H05K1/032 ,  Y02E10/50

Abstract: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer characterized as having has an average Mv and a valley temperature between the interpolymer and high crystalline fraction, The, such that the average Mv for a fraction above ThC from ATREF divided by average Mv of the whole polymer from ATREF (MhC/Mp) is less than about 1.95 and wherein the copolymer has a CDBI of less than 60%, (2) optionally, a vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt% based on the weight of the copolymer, and (4) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.

Abstract translation: 一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合物材料包括（1）聚烯烃共聚物， 由于在互聚物和高结晶部分之间具有平均Mv和谷值温度，所以来自ATREF的高于ThC的馏分的平均Mv除以ATREF（MhC / Mp）之外的整个聚合物的平均Mv小于 约1.95，并且其中所述共聚物的CDBI小于60％，（2）任选的乙烯基硅烷，（3）任选的自由基引发剂或光引发剂，其量为至少约0.05重量％ 共聚物，和（4）任选地，基于共聚物的重量，至少约0.05重量％的助剂。

公开(公告)号：WO2011153541A1

公开(公告)日：2011-12-08

申请号：PCT/US2011/039307

申请日：2011-06-06

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu ,  NIEMANN, Debra, H.

Inventor： NAUMOVITZ, John, A. ,  PATEL, Rajen, M. ,  WU, Shaofu ,  NIEMANN, Debra, H.

IPC: C08F210/02 ,  C08L23/00 ,  H01L31/00

CPC classification number: H01L31/0203 ,  B32B17/10018 ,  B32B17/1055 ,  C08F210/16 ,  C08L23/08 ,  H01L23/293 ,  H01L31/0481 ,  H01L2924/0002 ,  Y02E10/50 ,  C08L2666/24 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/26 ,  H01L2924/00

Abstract: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm 3 ; total unsaturation of not more than 125 per 100,000 carbons;; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/M n ), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145°C) and 1 H-NMR (125°C), (2) grafted vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt% based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.

Abstract translation: 一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含 总聚合物密度不大于0.905g / cm3; 总不饱和度不超过每100,000个碳原子的125个; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 以及小于量（8000 / Mn）的乙烯基/ 1000个碳数的总数，其中通过凝胶渗透色谱法（145℃）和1 H-NMR（125℃）测量乙烯基-3含量和乙烯基测量值 ），（2）接枝的乙烯基硅烷，（3）任选的自由基引发剂或光引发剂，其量基于共聚物的重量为至少约0.05重量％，和（3）任选地， 至少约0.05重量％，基于共聚物的重量。

公开(公告)号：WO2011119486A1

公开(公告)日：2011-09-29

申请号：PCT/US2011/029201

申请日：2011-03-21

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  WALTON, Kim, L. ,  MARCHAND, Gary, R. ,  DHODAPKAR, Shrikant ,  KAPUR, Mridula ,  WU, Shaofu

Inventor： WALTON, Kim, L. ,  MARCHAND, Gary, R. ,  DHODAPKAR, Shrikant ,  KAPUR, Mridula ,  WU, Shaofu

IPC: C08L23/06 ,  C08L23/10 ,  C08L67/00 ,  C08L69/00

CPC classification number: C08L67/00 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/10 ,  C08L51/06 ,  C08L69/00 ,  C08L101/00 ,  C08L2314/06 ,  C08L2666/06

Abstract: Impact modified compositions having good impact performance can be made from a thermoplastic ( e.g. , α polyolefin such as polypropylene or HDPE) and a multi-block ethylene/α- olefin interpolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.

Abstract translation: 具有良好冲击性能的冲击改性组合物可由热塑性塑料（例如，聚烯烃如聚丙烯或HDPE）和多嵌段乙烯/α-烯烃互聚物制成。 组合物易于模塑，并且通常在制备例如汽车面漆，部件和其它家用制品中具有特别的用途。

公开(公告)号：WO2011084323A1

公开(公告)日：2011-07-14

申请号：PCT/US2010/059458

申请日：2010-12-08

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  WU, Shaofu ,  MARTIN, Peter, S. ,  CHEN, Xuming ,  BOVEN, Michelle, L. ,  ZHOU, Weijun ,  KUZNETSOVA, Valentina, A.

Inventor： WU, Shaofu ,  MARTIN, Peter, S. ,  CHEN, Xuming ,  BOVEN, Michelle, L. ,  ZHOU, Weijun ,  KUZNETSOVA, Valentina, A.

IPC: B32B17/10 ,  B32B27/32 ,  H01L31/048

CPC classification number: B32B27/32 ,  B32B17/064 ,  B32B2457/12 ,  Y10T428/24967 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/31507 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31573 ,  Y10T428/31598 ,  Y10T428/31645

Abstract: The present invention generally relates to composite glass laminates and uses thereof in articles in need of protection from mechanical damage and water or oxygen based degradation.

Abstract translation: 本发明一般涉及复合玻璃层压板及其在需要防止机械损伤和水或氧气降解的制品中的用途。