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公开(公告)号：WO2019118230A1
公开(公告)日：2019-06-20
申请号：PCT/US2018/063763
申请日：2018-12-04
发明人： KRAMER, Anatoly, I. , YU, Renyuan , LOVELESS, Brett, T. , LAI, Wenyih, F. , JANSSEN, Mechilium, J.G.
CPC分类号： C07C5/2518 , B01J29/06 , C07C2529/40 , C07C2529/65 , C07C2529/74 , C09K8/32 , C07C11/02
摘要： Processes are described for isomerizing one or more C4-C24 alpha olefins to produce an isomerization mixture comprising one or more C4-C24 internal olefins comprising contacting an olefinic feed comprising the one or more C4-C24 alpha olefins with a catalyst under isomerization conditions, wherein the catalyst comprises a microporous crystalline alummosilicate selected from the group consisting of ZSM-5, ZSM-23, ZSM-35, ZSM-11, ZSM-12, ZSM-48, ZSM-57, and mixtures or combinations thereof, and wherein the microporous crystalline aluminosilicate has a S1O2/AI2O3 molar ratio of less than or equal to about 100. The resulting isomerization mixture typically exhibits a lower pour point and maintained biodegradability properties as compared to the olefinic feed, and is particularly useful in drilling fluid and paper sizing compositions.
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2.发明申请
公开(公告)号：WO2018183012A1
公开(公告)日：2018-10-04
申请号：PCT/US2018/023091
申请日：2018-03-19
IPC分类号： B01J29/00 , C07C2/58 , C07C15/073 , C07C15/085
CPC分类号： C07C7/13 , B01J29/7007 , B01J29/7057 , B01J2229/42 , C07C2/58 , C07C2/66 , C07C6/126 , C07C15/073 , C07C15/085 , C07C2529/70 , Y02P20/52 , C07C15/04
摘要： Methods for removing impurities from a hydrocarbon stream using a guard bed material are disclosed. The guard bed material includes compositions which comprises a zeolite and a mesoporous support or binder. The zeolite has a Constraint Index of less than 3. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 μm at 50% of the cumulative pore size distribution (d 50 ), a pore volume of less than 1cc/g, and an alumina content of greater than 75%, by weight. Also disclosed are processes for producing mono-alkylated aromatic compounds (e.g., ethylbenzene or cumene) using impure feed streams that are treated by the disclosed methods to remove impurities which act as catalyst poisons to downstream alkylation and/or transalkylation catalysts.
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公开(公告)号：WO2018160327A1
公开(公告)日：2018-09-07
申请号：PCT/US2018/017245
申请日：2018-02-07
发明人： IDE, Matthew, S. , LEVIN, Doron , LAI, Wenyih, F. , JOHNSON, Ivy, D. , WEIGEL, Scott, J. , LOVELESS, Brett, T.
IPC分类号： B01J29/18 , B01J29/70 , C07C2/66 , B01J35/10 , B01J20/18 , B01J35/00 , B01J29/80 , C07C6/12 , C07C15/085 , B01J29/06 , B01J29/08
CPC分类号： B01J29/18 , B01J20/18 , B01J20/28004 , B01J20/28057 , B01J20/3007 , B01J20/3078 , B01J29/7007 , B01J29/80 , B01J35/0006 , B01J35/002 , B01J35/1023 , B01J35/1061 , B01J2220/42 , B01J2229/186 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C07C2/66 , C07C7/13 , C07C2529/18 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/02 , C07C15/085 , C07C11/02
摘要： Catalyst composition which comprises a first zeolite having a BEA* framework type and a second zeolite having a MOR framework type and a mesopore surface area of greater than 30 m 2 /g is disclosed. These catalyst compositions are used to remove catalyst poisons from untreated feed streams having one or more impurities which cause deactivation of the downstream catalysts employed in hydrocarbon conversion processes, such as those that produce mono-alkylated aromatic compounds.
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公开(公告)号：WO2018140149A1
公开(公告)日：2018-08-02
申请号：PCT/US2017/066633
申请日：2017-12-15
发明人： LOVELESS, Brett, T. , BEECKMAN, Jean, W. , OLIVERI, Christopher, G. , WEIGEL, Scott, J. , IDE, Matthew, S. , BAUMRUCKER, Theresa, A.
IPC分类号： C07C6/12
CPC分类号： C07C6/126 , C07C6/12 , C07C2529/08 , C07C15/073 , C07C15/085
摘要： The present disclosure relates to a process for producing a mono-alkylated aromatic compound, such as, for example, ethylbenzene or cumene, in which an alkylatable aromatic compound stream, such as, for example, benzene, and an alkylation agent stream, such as, for example, poly-ethylbenzene or poly-isopropylbenzene, are contacted in the presence of a trans alkylation catalyst and under at least partial liquid phase transalkylation conditions. The trans alkylation catalyst comprises a zeolite having a framework structure selected from the group consisting of FAU, BEA*, MOR, MWW and mixtures thereof. The zeolite has a silica- alumina molar ratio in a range of 10 to 15. The transalkylation catalyst composition has an external surface area/volume ratio in the range of 30 cm 1 to 85 cm 1.
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公开(公告)号：WO2017213749A1
公开(公告)日：2017-12-14
申请号：PCT/US2017/027322
申请日：2017-04-13
摘要： The present disclosure relates to a process for producing a mono-alkylated aromatic compound using a treated catalyst made by a method of this invention is disclosed. The method comprises the steps of heating an untreated catalyst in the presence of a gaseous stream having a dew point temperature less than about 5°C to form a treated catalyst. The treatment is effective to improve the activity and selectivity of the catalyst.
摘要翻译： 本发明涉及使用通过本发明方法制备的处理过的催化剂制备单烷基化芳族化合物的方法。 该方法包括以下步骤：在露点温度低于约5℃的气流存在下加热未处理的催化剂以形成处理过的催化剂。 该处理对于提高催化剂的活性和选择性是有效的。
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公开(公告)号：WO2018183009A1
公开(公告)日：2018-10-04
申请号：PCT/US2018/023077
申请日：2018-03-19
发明人： IDE, Matthew, S. , LOVELESS, Brett, T. , LEVIN, Doron , LONERGAN, William, W. , VINCENT, Matthew, J. , TAI, Wei-Ping , BARRAI, Federico
IPC分类号： B01J29/00 , B01J29/03 , B01J29/08 , B01J29/70 , B01J29/80 , C07C2/66 , B01J29/18 , B01J35/10 , B01J37/00 , B01J35/02
CPC分类号： B01J35/109 , B01J29/005 , B01J29/0308 , B01J29/084 , B01J29/088 , B01J29/18 , B01J29/7007 , B01J29/7038 , B01J29/80 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0009 , C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2529/03 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： Catalyst compositions comprising a zeolite and a mesoporous support or binder are disclosed. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 μm at 50% of the cumulative pore size distribution (d 50 ). Also disclosed are processes for producing a mono-alkylated aromatic compound (e.g., ethylbenzene or cumene) which exhibit improved yield of the mono- alkylated aromatic compound using alkylation catalysts comprising one or more of these catalyst compositions.
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公开(公告)号：WO2018067281A1
公开(公告)日：2018-04-12
申请号：PCT/US2017/051179
申请日：2017-09-12
CPC分类号： C07C2/864 , B01J8/0278 , B01J29/70 , B01J29/7007 , B01J29/7034 , B01J29/7038 , C07C2/865 , C07C5/2737 , C07C2529/70 , Y02P20/52 , C07C15/08
摘要： In a process for producing paraxylene, a hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index ≤ 5, and the alkylation conditions comprise a temperature less than 500°C. At least part of the alkylated product is supplied to a paraxylene recovery unit to recover paraxylene and produce a paraxylene- depleted stream, which is then contacted with a xylene isomerization catalyst under conditions effective to isomerize xylenes in the paraxylene-depleted stream and produce an isomerized stream having a higher concentration of paraxylene than the paraxylene-depleted stream. At least part of the isomerized stream is then recycled to the paraxylene recovery unit to recover the paraxylene therein.
摘要翻译： 在生产对二甲苯的方法中，使包含苯和/或甲苯的烃原料在烷基化反应区中在烷基化条件下在含有甲醇和/或二甲醚的烷基化试剂存在下与烷基化试剂 烷基化催化剂以生成包含二甲苯的烷基化产物。 烷基化催化剂包含约束指数≤5的分子筛，烷基化条件包括低于500℃的温度。 将至少一部分烷基化产物供给对二甲苯回收单元以回收对二甲苯并产生贫对二甲苯流，然后在有效使异构化对二甲苯流中的二甲苯异构化的条件下与二甲苯异构化催化剂接触并产生异构化 具有比对二甲苯去除物流更高浓度的对二甲苯的物流。 然后将至少一部分异构化物流循环到对二甲苯回收装置中以回收其中的对二甲苯。
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公开(公告)号：WO2017172067A8
公开(公告)日：2017-10-05
申请号：PCT/US2017/017300
申请日：2017-02-10
发明人： CHEN, Tan-jen , LAI, Wenyih, F. , LOVELESS, Brett, T. , IDE, Matthew, S. , ABICHANDANI, Jeevan, S.
IPC分类号： C07C6/12 , C07C15/08 , C07C15/06 , C07C15/24 , C07C7/20 , B01J29/74 , B01J29/035 , B01J29/08
摘要： Systems and methods are provided for an improved transalkylation process that better tolerates the presence of C 10+ aromatics and may be conducted substantially in the liquid phase. The transalkylation feedstock may comprise alkyl-substituted benzenes and naphthalene and the transalkylation effluent comprises alkyl-substituted naphthalene and benzene, toluene, and/or xylenes.
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公开(公告)号：WO2020009750A1
公开(公告)日：2020-01-09
申请号：PCT/US2019/033316
申请日：2019-05-21
发明人： KRAMER, Anatoly, I. , YU, Renyuan , LOVELESS, Brett, T. , KEUSENKOTHEN, Paul, F. , LATTNER, James, R.
摘要： Terminal olefins (alpha olefins) may be isomerized to internal olefins using a catalyst composition comprising sodium oxide on a solid support. Isomerization of alpha olefins takes place under a variety of mild heterogeneous reaction conditions. Linear alpha olefins (LAOs) may be isomerized without substantial cracking or branching to form the corresponding linear internal olefins (LIOs). The LIOs may be incorporated in drilling fluids, particularly those intended for use in a subsea environment, due to their favorable environmental profile and low pour point values. Compositions comprising C 14 -C 20 LIOs produced from the corresponding C 14 -C 20 LAOs may exhibit anaerobic biodegradability and pour point values of about -6°C or lower.
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公开(公告)号：WO2017172067A1
公开(公告)日：2017-10-05
申请号：PCT/US2017/017300
申请日：2017-02-10
发明人： ABICHANDANI, Jeevan, S. , CHEN, Tan-jen , LAI, Wenyih, F. , IDE, Matthew, S. , LOVELESS, Brett, T.
IPC分类号： C07C6/12 , C07C15/08 , C07C15/06 , C07C15/24 , C07C7/20 , B01J29/74 , B01J29/035 , B01J29/08
CPC分类号： C07C6/126 , B01J29/08 , B01J29/12 , B01J29/7007 , B01J29/7038 , B01J29/7415 , B01J29/7476 , B01J29/80 , B01J2229/42 , C07C2529/74 , C07C15/24
摘要： Systems and methods are provided for an improved transalkylation process that better tolerates the presence of C 10+ aromatics and may be conducted substantially in the liquid phase. The transalkylation feedstock may comprise alkyl-substituted benzenes and naphthalene and the transalkylation effluent comprises alkyl-substituted naphthalene and benzene, toluene, and/or xylenes.
摘要翻译： 提供了用于改进的烷基转移过程的系统和方法，其更好地容忍C 10+芳族化合物的存在并且可以基本在液相中进行。 烷基转移原料可以包含烷基取代的苯和萘，并且烷基转移流出物包含烷基取代的萘和苯，甲苯和/或二甲苯。
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