公开(公告)号：WO2015195374A1

公开(公告)日：2015-12-23

申请号：PCT/US2015/034512

申请日：2015-06-05

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： BODAY, Dylan, J. ,  GARCIA, Jeannette, M. ,  HEDRICK, James, L. ,  WOJTECKI, Rudy, J. ,  JONES, Gavin, O.

IPC: B01D15/22 ,  C02F5/12 ,  C07D251/04

CPC classification number: B01J20/262 ,  B01D15/08 ,  C02F1/285 ,  C02F1/683 ,  C02F2101/20 ,  C02F2201/002 ,  C02F2303/16

Abstract: Method and apparatus for controlling metals in a liquid are described. The liquid is contacted with a hexahydrotriazine and/or a hemiaminal material, and metal is adsorbed from the liquid onto the material. The hexahydrotriazine and/or hemiaminal material may be made from a diamine and an aldehyde.

Abstract translation: 描述了用于控制液体中金属的方法和装置。 液体与六氢三嗪和/或半固体材料接触，金属从液体吸附到材料上。 六氢三嗪和/或半固体材料可以由二胺和醛制成。

公开(公告)号：WO2015187980A1

公开(公告)日：2015-12-10

申请号：PCT/US2015/034252

申请日：2015-06-04

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： BODAY, Dylan, J. ,  GARCIA, Jeannette, M. ,  HEDRICK, James, L. ,  WOJTECKI, Rudy, J. ,  ZIMMERMAN, Thomas

IPC: G01N21/76 ,  C07D265/14

CPC classification number: G01N21/59 ,  G01N21/33 ,  G01N33/20 ,  G01N2201/061

Abstract: Method and apparatus for detecting metals in a liquid are described. The liquid is contacted with a hexahydrotriazine and/or a hemiaminal material, and a UV absorption spectrum of the material before and after exposure to the liquid is examined to determine whether metals are present in the liquid.

Abstract translation: 描述了用于检测液体中的金属的方法和装置。 将液体与六氢三嗪和/或半固体材料接触，并且检查在暴露于液体之前和之后的材料的UV吸收光谱，以确定金属是否存在于液体中。

公开(公告)号：WO2015200634A1

公开(公告)日：2015-12-30

申请号：PCT/US2015/037690

申请日：2015-06-25

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： BODAY, Dylan, J. ,  GARCIA, Jeannette, M. ,  HEDRICK, James, L. ,  WOJTECKI, Rudy, J.

IPC: C08G12/08

CPC classification number: C09D179/04 ,  B05D1/30 ,  C08G12/08 ,  C08G73/0273 ,  C08G73/0638 ,  C09D161/22

Abstract: Polyhexahydrotriazine (PHT) and polyhemiaminal (PHA) materials incorporating divalent or trivalent bridging groups tend to form highly cross-linked polymers. While highly cross-linked polymers have certain advantageous with respect to stability and various physical characteristics, they are difficult to process once formed. PHA and PHT materials incorporating a plurality of trivalent PHA/PHT groups, a plurality of divalent bridging groups, and a plurality of monovalent end groups are disclosed. According to an embodiment, the cross-link density and molecular weight can be controlled by the inclusion of the end groups. Lower cross-link density and molecular weight give PHA and PHT materials improved characteristics with respect to film and fiber formation methods. A method of coating a component or substrate with a polymer is also disclosed. Embodiments of the method can be used to form either a PHA or PHT film on a substrate, such as microelectronic component.

Abstract translation: 掺有二价或三价桥连基团的聚六氢三嗪（PHT）和聚甲氨基（PHA）材料倾向于形成高度交联的聚合物。 虽然高度交联的聚合物在稳定性和各种物理特性方面具有一定的优势，但一旦形成就难以加工。 公开了包含多个三价PHA / PHT基团，多个二价桥连基团和多个一价端基的PHA和PHT材料。 根据一个实施方案，交联密度和分子量可以通过包含端基来控制。 较低的交联密度和分子量使得PHA和PHT材料相对于膜和纤维形成方法改善了特性。 还公开了用聚合物涂覆组分或底物的方法。 该方法的实施方案可用于在基底上形成PHA或PHT膜，例如微电子元件。

公开(公告)号：WO2015195911A1

公开(公告)日：2015-12-23

申请号：PCT/US2015/036423

申请日：2015-06-18

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： BODAY, Dylan, J. ,  GARCIA, Jeannette, M. ,  HEDRICK, James, L. ,  WOJTECKI, Rudy, J.

IPC: C09D179/04 ,  A61K31/53 ,  C08G12/42

CPC classification number: A01N55/02 ,  A01N35/02 ,  A01N43/64 ,  A01N43/66 ,  A01N59/16 ,  B05D3/104 ,  B05D3/107 ,  B05D5/00 ,  C09D5/14 ,  C09D5/16 ,  C09D5/1693 ,  A01N25/12 ,  A01N59/20

Abstract: Methods for making antimicrobial coating materials are described. Antimicrobial materials and antimicrobial material precursors are formed from hexahydrotriazine and/or a hemiaminal material and a non-fouling material and adhesive material may be incorporated into the antimicrobial materials and antimicrobial material precursors. The hexahydrotriazine and/or hemiaminal material may be made from a diamine and an aldehyde. Metal ions are also incorporated into the antimicrobial material precursors to form an antimicrobial material.

Abstract translation: 描述了制备抗微生物涂层材料的方法。 抗微生物材料和抗微生物材料前体由六氢三嗪和/或半固体材料形成，并且非结垢材料和粘合剂材料可以并入抗微生物材料和抗微生物材料前体中。 六氢三嗪和/或噻嗪类材料可以由二胺和醛制成。 金属离子也并入抗微生物材料前体以形成抗微生物材料。