公开(公告)号：WO2012054325A1

公开(公告)日：2012-04-26

申请号：PCT/US2011/056305

申请日：2011-10-14

Applicant: KRATON POLYMERS U.S. LLC ,  WILLIS, Carl Lesley

Inventor： WILLIS, Carl Lesley

IPC: C08F8/34 ,  C08F8/36

CPC classification number: C08F8/36 ,  C08F8/04 ,  C08F297/046

Abstract: Sulfonated block copolymer composition formed by dissolving in an aprotic polar solvent at least one sulfonated block copolymer having at least one end block A and at least one interior block B wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol% sulfonic acid or sulfonate ester functional groups based on the number of sulfonation susceptible monomer units of the B block.

Abstract translation: 通过将至少一种具有至少一个端嵌段A和至少一个内嵌块B的磺化嵌段共聚物溶解在非质子极性溶剂中形成的磺化嵌段共聚物组合物，其中每个A嵌段基本上不含磺酸或磺酸酯官能团，并且每个B嵌段 是基于B嵌段的磺化敏感性单体单元的数量含有约10至约100mol％磺酸或磺酸酯官能团的聚合物嵌段。

公开(公告)号：WO2013025271A1

公开(公告)日：2013-02-21

申请号：PCT/US2012/038762

申请日：2012-06-22

Applicant: KRATON POLYMERS U.S. LLC ,  WILLIS, Carl Lesley

Inventor： WILLIS, Carl Lesley

IPC: C08L81/04

CPC classification number: B01D71/80 ,  B01D61/445 ,  B01D61/48 ,  B01D71/28 ,  B01D71/68 ,  C02F1/441 ,  C02F1/445 ,  C02F1/4693 ,  C02F1/4695 ,  C08F8/36 ,  H01M8/1023 ,  H01M8/103 ,  Y10T442/20 ,  Y10T442/2762 ,  C08F297/02

Abstract: Described herein are modified sulfonated block copolymers which comprise at least two polymer end blocks A and at least one polymer interior block B, wherein each A block contains essentially no sulfonic acid or sulfonate functional groups and each B block comprises sulfonation susceptible monomer units and, based on the number of the sulfonation susceptible monomer units, from about 10 to about 100 mol% of a functional group of formula (I) -SO 2 -NR 1 R 2 or of a salt thereof, methods of making them as well as methods of using them, e.g., as membrane materials for electrically or osmotically driven applications.

Abstract translation: 本文描述的是改性的磺化嵌段共聚物，其包含至少两个聚合物端嵌段A和至少一个聚合物内部嵌段B，其中每个A嵌段基本上不含磺酸或磺酸盐官能团，并且每个B嵌段包含磺化敏感单体单元和基于 关于磺化易感单体单元的数量，约10至约100摩尔％的式（I）-SO 2 -NR 1 R 2的官能团或其盐，制备它们的方法以及使用它们的方法，例如 作为电气或渗透驱动应用的膜材料。

公开(公告)号：WO2013138146A1

公开(公告)日：2013-09-19

申请号：PCT/US2013/029506

申请日：2013-03-07

Applicant: KRATON POLYMERS U.S. LLC

Inventor： WILLIS, Carl Lesley ,  TAN, Kuitian

IPC: B01D71/68 ,  B01D71/80 ,  C08F8/36

CPC classification number: C08L53/005 ,  A62B17/006 ,  C08F8/36 ,  C08F297/046 ,  C08L53/025 ,  Y10T442/2762 ,  Y10T442/2861

Abstract: Blends comprising a sulfonated block copolymer and particulate carbon are useful materials for membranes, films and coatings in applications which require high dimensional stability, high water vapor transport, high conductivity, and low flammability. The sulfonated block copolymer comprises at least two polymer end blocks A and at least one polymer interior block B wherein each A block contains essentially no sulfonic acid or sulfonate functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate functional groups based on the number of monomer units of the B block.

Abstract translation: 包含磺化嵌段共聚物和颗粒碳的共混物是需要高尺寸稳定性，高水蒸汽输送，高导电性和低可燃性的应用中的膜，膜和涂料的有用材料。 磺化嵌段共聚物包含至少两个聚合物端嵌段A和至少一个聚合物内部嵌段B，其中每个A嵌段基本上不含磺酸或磺酸盐官能团，每个B嵌段是含有约10至约100摩尔％ 基于B嵌段的单体单元数目的磺酸或磺酸酯官能团。

公开(公告)号：WO2014110534A1

公开(公告)日：2014-07-17

申请号：PCT/US2014/011351

申请日：2014-01-13

Applicant: KRATON POLYMERS U.S. LLC

Inventor： WILLIS, Carl Lesley ,  HIDAJAT, Irwan ,  HENIFF, Mike

IPC: C08F4/46 ,  C08F212/00

CPC classification number: B01D71/82 ,  B01D53/228 ,  B01D61/44 ,  B01D65/10 ,  C08F8/02 ,  C08F8/24 ,  C08F8/30 ,  C08F8/40 ,  H01M8/1023 ,  Y02P70/56 ,  C08F297/00 ,  C08F297/04

Abstract: Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises at least one amino- or phosphino-functionalized polymer unit of formula (I) wherein Z is nitrogen or phosphorous; R 1 is hydrogen or alkyl; R 2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A 1 -NR a ) x R b ; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A 1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and R a and R b , each independently, is hydrogen or alkyl; or a corresponding onium salt.

Abstract translation: 选择性氨基或膦官能化嵌段共聚物及其制备，用作阴离子交换膜材料。 选择性官能化的嵌段共聚物具有至少两个端基A，其各自基本上不含氨基或膦基官能团，并且具有至少一个内部嵌段D，其包含至少一个式（I）的氨基或膦官能化聚合物单元 （I）其中Z是氮或磷; R1是氢或烷基; R2是氢或是叔烷基; R各自独立地为氢或任选被部分 - （Al-NR a）x R b取代的烷基; 或两个R基团与它们所键合的Z一起形成任选取代的环; x为1,2或3; A1是任选被一个或多个甲基和/或乙基取代的直链亚烷基; 和R a和R b各自独立地是氢或烷基; 或相应的鎓盐。

公开(公告)号：WO2013066550A1

公开(公告)日：2013-05-10

申请号：PCT/US2012/058577

申请日：2012-10-03

Applicant: KRATON POLYMERS U.S. LLC

Inventor： TAN, Kuitian ,  WILLIS, Carl Lesley

IPC: C08L53/02

CPC classification number: B32B38/164 ,  B32B15/08 ,  B32B37/0038 ,  B32B2038/166 ,  B32B2311/00 ,  C08J5/122 ,  F24F2203/1032 ,  F28D19/042 ,  Y10T428/31692

Abstract: A process for laminating a polar substrate with a film cast from a sulfonated block copolymer having at least one end block A and at least one interior block B wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units. The film is exposed to water and dried onto a polar or active metal substrate. The laminates do not delaminate in the presence of water and may be used for a variety of applications including energy exchange applications.

Abstract translation: 一种由具有至少一个端嵌段A和至少一个内部嵌段B的磺化嵌段共聚物的膜状浇铸的极性基材层压的方法，其中每个A嵌段基本上不含磺酸或磺酸酯官能团，并且每个B嵌段是 聚合物嵌段含有约10至约100摩尔％的基于单体数目的磺酸或磺酸酯官能团。 将该膜暴露于水中并干燥至极性或活性金属基底上。 层压板在水的存在下不会分层，可用于各种应用，包括能量交换应用。