LONG-TERM ANION-CONDUCTING COMPOUND, ITS PREPARATION AND ITS USE IN ELECTROCHEMISTRY

    公开(公告)号:WO2022194605A1

    公开(公告)日:2022-09-22

    申请号:PCT/EP2022/055824

    申请日:2022-03-08

    摘要: The present invention provides compounds, especially polymeric compounds, a process for preparation thereof and for the use of these compounds. Intended use is in the field of electro- chemistry. Anion-conducting properties of disclosed compounds making this material suitable for the preparation of anion-conducting membranes. The object of the present invention is therefore to provide material having an ionic conductivity that is stable over long period of time. This object is solved by compounds containing at least one unit of the formula (I) wherein X being a ketone or sulfone group, wherein Z being a structure element comprising at least one tertiary carbon atom and at least one aromatic 6-ring directly bonded to one of the oxygen atoms, and wherein Y being a structure element comprising at least one nitrogen atom with a positive charge and Y being bonded to said tertiary carbon atom of Z.

    一种用于制备分离膜的常温选择性溶胀开孔方法

    公开(公告)号:WO2021139094A1

    公开(公告)日:2021-07-15

    申请号:PCT/CN2020/097143

    申请日:2020-06-19

    摘要: 一种用于制备分离膜的常温选择性溶胀开孔方法,包括:将两亲嵌段共聚物致密膜在15-30℃下用复合溶胀剂处理1min-24h,然后去除残余溶剂,室温放置干燥得到双连续多孔结构的两亲嵌段共聚物分离膜;复合溶胀剂由60-96%的第一溶胀剂和4-40%的第二溶胀剂构成,第一溶胀剂为醇类溶剂,第二溶胀剂选自1,4-二氧六环、甲苯、苯乙烯或四氢呋喃等试剂中的任意一种或两种以上的混合物。通过调节溶胀剂中溶剂的组成以及溶胀剂中第二溶胀剂的含量可以调控溶胀程度以及形貌。