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    SELECTIVE ALKYLATION OF DIAMONDOID COMPOUNDS WITH AN ALPHA-OLEFIN OVER A LEWIS ACID CATALYST
    1.
    发明申请
    SELECTIVE ALKYLATION OF DIAMONDOID COMPOUNDS WITH AN ALPHA-OLEFIN OVER A LEWIS ACID CATALYST 审中-公开
    二氧化钛化合物的选择性烷基化与乳酸催化剂中的ALPHA-烯烃

    公开(公告)号：WO1994029247A1

    公开(公告)日：1994-12-22

    申请号：PCT/US1994006184

    申请日：1994-06-02

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  SHEN, Dongming ,  WU, Margaret, May-Som

    IPC: C07C13/28

    CPC classification number: C07C2/54 ,  C07C2527/08 ,  C07C2527/125 ,  C07C2603/74 ,  C07C13/615

    Abstract: The invention provides a method for selectively alkylating a diamondoid compound comprising reacting at least one alpha -olefin containing at least six carbon atoms with at least one diamondoid compound in the presence of an acid catalyst selected from AlX3 and BX3 wherein X is a halogen, in the absence of added proton-donating catalyst promoter. The invention further provides a lubricant composition comprising alkyl-substituted adamantanes wherein the ratio of linear to branched alkyl substituents is at least 4:1 and wherein the average number of alkyl substitutions per diamondoid molecule is from 1.5 to 4.

    Abstract translation: 本发明提供了一种选择性烷基化金刚石化合物的方法，包括使至少一种含有至少6个碳原子的α-烯烃与至少一种类金刚石化合物在选自Al x 3和BX 3的酸催化剂（其中X为卤素）存在下反应， 没有添加质子递送催化剂促进剂。 本发明还提供了包含烷基取代的金刚烷的润滑剂组合物，其中直链与支链烷基取代基的比例为至少4:1，并且其中每个金刚石类分子的烷基取代的平均数为1.5至4。

    LUBRICANT COMPOSITION AND METHOD FOR INCREASING DIAMONDOID INCORPORATION IN POLYALPHAOLEFIN-CONTAINING LUBRICANT
    2.
    发明申请
    LUBRICANT COMPOSITION AND METHOD FOR INCREASING DIAMONDOID INCORPORATION IN POLYALPHAOLEFIN-CONTAINING LUBRICANT 审中-公开
    润滑剂组合物和增加含有多元醇的润滑剂中的金刚石混入物的方法

    公开(公告)号：WO1994029244A1

    公开(公告)日：1994-12-22

    申请号：PCT/US1994006185

    申请日：1994-06-02

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  SHEN, Dongming ,  WU, Margaret, May-Som

    IPC: C07C02/54

    CPC classification number: C10M105/02 ,  C10M2203/02 ,  C10M2203/022 ,  C10M2203/024 ,  C10M2203/04

    Abstract: This invention provides a method for incorporating a diamondoid compound into a lubricant stock comprising reacting at least one alpha -olefin containing at least six carbon atoms with at least one diamondoid compound in the presence of an acid catalyst selected from the group consisting of AlX3, BX3, and GaX3, wherein X is a halogen, together with at least one added proton-donating catalyst promoter. The invention further provides a lubricant composition comprising alkyl-substituted diamondoids wherein the ratio of linear to branched alkyl substituents is at least 4:1 and wherein the average number of alkyl substitutions per diamondoid molecule is from 1.5 to 4.

    Abstract translation: 本发明提供了一种将金刚石类化合物掺入润滑剂原料中的方法，包括使至少一种含有至少6个碳原子的α-烯烃与至少一种类金刚石化合物在选自AlX 3，BX 3 和GaX 3，其中X是卤素，以及至少一种添加的质子递送催化剂促进剂。 本发明还提供了包含烷基取代的金刚石的润滑剂组合物，其中直链与支链烷基取代基的比例为至少4:1，并且其中每个金刚石类分子的烷基取代的平均数为1.5至4。

    PROCESS FOR THE PRODUCTION OF TERTIARY ALKYL ETHERS AND TERTIARY ALKYL ALCOHOLS
    4.
    发明申请
    PROCESS FOR THE PRODUCTION OF TERTIARY ALKYL ETHERS AND TERTIARY ALKYL ALCOHOLS 审中-公开
    碱性烷基醇和仲烷基醇的生产方法

    公开(公告)号：WO1990011268A1

    公开(公告)日：1990-10-04

    申请号：PCT/US1990001494

    申请日：1990-03-20

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  CHUNG, Harold, Set ,  JACKSON, Andrew ,  WU, Margaret, May-Som

    IPC: C07C43/04

    CPC classification number: C07C2/10 ,  C07C29/04 ,  C07C41/06 ,  C07C2521/08 ,  C07C2523/26 ,  C07C31/12 ,  C07C31/125 ,  C07C43/046

    Abstract: A process for producing lower alkyl tertiary alkyl ethers or tertiary alkyl alcohol, such as methyl tertiary butyl ether (MTBE), methyl tertiary amyl ether (TAME) or tertiary butyl alcohol, wherein the 1-alkene component of the hydrocarbon feedstream to an etherification or olefin hydration process is separated by selective oligomerization in contact with a reduced chromium on silica support catalyst producing useful hydrocarbons of higher molecular weight, such as gasoline, distillate and lube range hydrocarbons. It has further been found that separation of the 1-alkene component of the hydrocarbon feedstream can be accomplished in an oligomerization process integrated either upstream or downstream of the etherification step.

    Abstract translation: 制备低级烷基叔烷基醚或叔烷基醇的方法，例如甲基叔丁基醚（MTBE），甲基叔戊基醚（TAME）或叔丁醇，其中烃进料流的1-烯烃组分进行醚化或 烯烃水合过程通过选择性低聚与二氧化硅载体催化剂上还原的铬接触而分离，产生有用的较高分子量的烃，例如汽油，馏出物和润滑油烃。 还已经发现，烃进料流的1-烯烃组分的分离可以在醚化步骤的上游或下游整合的低聚反应过程中完成。

    NOVEL HYDROCARBON LUBE AND DISTILLATE FUEL ADDITIVE
    6.
    发明申请
    NOVEL HYDROCARBON LUBE AND DISTILLATE FUEL ADDITIVE 审中-公开
    新型石油和稀释燃料添加剂

    公开(公告)号：WO1995018782A1

    公开(公告)日：1995-07-13

    申请号：PCT/US1995000069

    申请日：1995-01-05

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  CHU, Alice, Sheng ,  JACKSON, Andrew ,  WU, Margaret, May-Som

    IPC: C07C02/02

    CPC classification number: C10M143/08 ,  C08F210/14 ,  C10L1/1641 ,  C10M143/00 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/028 ,  C10N2220/02 ,  C08F4/22 ,  C08F2500/23 ,  C08F2500/02

    Abstract: A hydrocarbon oligomer and a process for its production is disclosed that is useful as a pour point depressant and as a combination pour point depressant and viscosity index improver for mineral oil or synthetic oil. The oligomer is also useful in modifying wax crystal formation at low temperature when added to distillate fuels. The oligomer is a near linear copolymer of a mixture of ethylene and C3-C28 1-alkenes, or only 1-alkenes, wherein a large proportion of the pendant alkyl groups of the recurring 1-alkene monomer units contain between 14 and 22 carbon atoms. The oligomer is produced by polymerization of mixed 1-alkenes with reduced chromium oxide catalyst on silica support.

    Abstract translation: 公开了一种烃低聚物及其生产方法，其用作矿物油或合成油的倾点下降剂和倾点下降剂和粘度指数改进剂的组合。 当加入到馏出燃料中时，低聚物也可用于在低温下修饰蜡晶形成。 低聚物是乙烯和C 3 -C 28 1-烯烃或仅仅1-烯烃的混合物的近似线性共聚物，其中重复的1-烯烃单体单元的大部分侧基烷基含有14至22个碳原子 。 低聚物通过在二氧化硅载体上与还原的氧化铬催化剂的混合的1-烯烃聚合来制备。

    FIBER OPTIC CABLE AND VISCOUS FILLER MATERIAL
    7.
    发明申请
    FIBER OPTIC CABLE AND VISCOUS FILLER MATERIAL 审中-公开
    光纤电缆和VISCOUS填充材料

    公开(公告)号：WO1995011472A1

    公开(公告)日：1995-04-27

    申请号：PCT/US1994009423

    申请日：1994-08-18

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  ASHJIAN, Henry ,  SHEN, Dong-Ming ,  WU, Margaret, May-Som

    IPC: G02B06/22

    CPC classification number: G02B6/4401 ,  G02B6/4496

    Abstract: The invention provides a fiber optic cable (10) comprising an optical fiber (12) and the grease (14) applied over the optic fiber (12). Surrounding grease (14) is a sheath (16). Additional layers of grease (18 and 22) may optionally be applied in sequence with outer sheaths (20 and 24), if desired. Furthermore, the invention provides a fiber optic cable (10) and a diamondoid-based viscous filling material for a fiber optic cable (10).

    Abstract translation: 本发明提供一种光纤电缆（10），其包括光纤（12）和涂覆在光纤（12）上的润滑脂（14）。 周围润滑脂（14）是护套（16）。 如果需要，额外的润滑脂层（18和22）可以任选地与外护套（20和24）按顺序施加。 此外，本发明提供一种用于光纤电缆（10）的光纤电缆（10）和基于金刚石的粘性填充材料。

    HIGH VI LUBRICANT BLENDS FROM SLACK WAX
    8.
    发明申请
    HIGH VI LUBRICANT BLENDS FROM SLACK WAX 审中-公开
    来自SLOW WAX的高VI润滑剂混合物

    公开(公告)号：WO1993014049A1

    公开(公告)日：1993-07-22

    申请号：PCT/US1992010373

    申请日：1992-12-02

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  BUCHANAN, John, Scott ,  WU, Margaret, May-Som

    IPC: C07C07/20

    CPC classification number: C10G57/02 ,  C10G2400/10

    Abstract: Lubricant compositions comprise blends or mixtures of low viscosity, 3-8 cS e.g. about 5 cS (100 DEG C), HVI lube basestock with higher viscosity, 15 cS+ e.g. 30+ cS (100 DEG C) HVI PAO lube basestock produced from slack wax by thermal cracking to alpha olefins followed by Lewis acid catalyzed oligomerization of the alpha olefin mixture to lube basestock. Blending these components in appropriate proportions produces lube basestock having viscosities in the range of 8-15 cS (100 DEG C) from which material suitable for the formulation of 10 W-30 automobile engine lube can be produced. The blends are notable for exhibiting high VI values greater than that of either component of the blend.

    Abstract translation: 润滑剂组合物包含低粘度的混合物或混合物，例如3-8cS。 约5cS（100℃），具有较高粘度的HVI润滑油基础油，15cS + 30℃cS（100℃）HVI PAO润滑油基础油由松散的蜡通过热裂解生成α-烯烃，随后路易斯酸催化低聚α-烯烃混合物至润滑油基础油。 以适当的比例混合这些组分产生粘度在8-15cS（100℃）范围内的润滑油基础油，由此可以制备适合于配制10W-30汽车发动机润滑油的材料。 共混物显示出高于混合物的任一组分的高VI值。

    WELL FLUIDS BASED ON LOW VISCOSITY SYNTHETIC HYDROCARBONS
    9.
    发明申请
    WELL FLUIDS BASED ON LOW VISCOSITY SYNTHETIC HYDROCARBONS 审中-公开
    基于低粘度合成烃的良好流体

    公开(公告)号：WO1996011174A1

    公开(公告)日：1996-04-18

    申请号：PCT/US1995011295

    申请日：1995-09-06

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  ASHJIAN, Henry ,  HO, Suzzy, Chen, Hsi ,  WU, Margaret, May-Som

    IPC: C07C05/23

    CPC classification number: C09K8/34 ,  C07C5/2518 ,  C07C2529/06 ,  C07C11/02

    Abstract: Solid, waxy 1-olefins may be converted to low viscosity liquid products by carrying out a double bond isomerization in the presence of a solid acidic catalyst such as an acidic clay or a zeolite under mild conditions. The olefin isomer products are useful in the formulation of well fluids such as drilling muds, especially useful in offshore drilling. The preferred oils for making up the well fluids are formulated with a hydrocarbon oil blend of the low viscosity olefin isomer together with a C12 to C18 paraffinic hydrocarbon of petroleum origin and a C10 to C32 olefin such as tetradecene-1. The fluids exhibit good biodegradability and are non-toxic to marine organisms; they also meet viscosity and pour points specifications for formulation into oil-based muds.

    Abstract translation: 固体蜡状1-烯烃可以在温和条件下在固体酸性催化剂如酸性粘土或沸石的存在下进行双键异构化而转化为低粘度液体产物。 烯烃异构体产物可用于诸如钻井泥浆的井液制备，特别适用于海上钻井。 用于制备井液的优选油用低粘度烯烃异构体的烃油共混物与石油来源的C 12至C 18链烷烃和诸如十四碳烯-1的C 10至C 32烯烃一起配制。 液体表现出良好的生物降解性，对海洋生物无毒; 它们也符合粘度和倾点规格，用于配制成油基泥浆。

    LIQUID LUBRICANTS FROM ALPHA-OLEFIN AND STYRENE COPOLYMERS
    10.
    发明申请
    LIQUID LUBRICANTS FROM ALPHA-OLEFIN AND STYRENE COPOLYMERS 审中-公开
    来自ALPHA-OLEFIN和苯乙烯共聚物的液体润滑剂

    公开(公告)号：WO1991003532A1

    公开(公告)日：1991-03-21

    申请号：PCT/US1990005011

    申请日：1990-09-05

    Applicant: MOBIL OIL CORPORATION

    Inventor： MOBIL OIL CORPORATION ,  WU, Margaret, May-Som

    IPC: C10M107/12

    CPC classification number: C10M107/12 ,  C08F210/14 ,  C10M107/10 ,  C10M2205/0285 ,  C10M2205/04 ,  C10M2205/043 ,  C08F212/08 ,  C08F2500/17

    Abstract: Alpha-olefins such as 1-decene are copolymerized with vinylaromatic monomers, especially styrene or the alkylstyrenes, to produce liquid lubricant oligomers having a broad range of viscosities, high viscosity index(VI), improved thermal stability and additive solubility characteristics. The lubricant oligomers are random copolymers containing recurring units of 1-alkene and vinyl aromatic monomer in mole ratios between 2:1 and 500:1, but preferably between 5:1 and 100:1 and more preferably from about 10:1 to 50:1. The recurring 1-alkene units of the copolymer have a branch ratio of less than 0.19, indicative of a poly 1-alkene segment of the copolymer chain or backbone that is essentially linear. The copolymerization catalyst is a reduced Group VIB metal catalyst on porous support, preferably reduced chromium oxide on a silica support.

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