摘要:
Additive manufacturing compositions and methods may include a resin stabilized pigment. The pigment may be easily combined with at least one component of a co-reactive system, such as a co-reactive prepolymer formulation, via solid mixing without the need for grinding or additional solvents. The prepolymer formulation may be pigmented, printed, and cured under ambient conditions, and one or more pigments may be incorporated into the composition to change the color of the composition during printing and/or to selectively change the color of the printed article among several colors.
摘要:
Tin-containing catalysts are provided comprising a compound of formula I. L1, L2, L3, and L4 are each independently selected from -O-, -S-, -OC(=O)-, -OC(=S)-, -SC(=O)-, -SC(=S)-, -OS(=O) 2 O-, -OS(=O) 2 - -N(R6)-, and -OP(=O)(R6)-, wherein R6 represents hydrogen or a monovalent aliphatic, araliphatic, cycloaliphatic or aromatic group having up to 20 carbon atoms. R1, R2, R3, R1', R2', and R3' each independently represent a divalent aliphatic, araliphatic, cycloaliphatic or aromatic group having up to 20 carbon atoms; and R4, R5, R4', and R5' each independently represent hydrogen or a monovalent residue derived from reaction of a respective N-H group with an isocyanate, an ethylenically unsaturated compound, a lactone, a dilactone, a thiolactone, a lactam, a thiolactam, a carboxylic acid or derivative thereof, or an epoxide. Also provided are curable compositions containing these catalysts and methods of controlling the rate of cure of curable compositions.
摘要:
The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising at least one polymeric resin having reactive functional groups; (b) a curing agent containing functional groups that are reactive with the reactive functional groups of (a); an d (c) silica particles that have been functionalized on their surfaces with an amino silane so as to impart the surfaces with primary amino functional groups. After application to a substrate as a coating and after curing, the curable film-forming composition demonstrates an initial 85 gloss of less than 30 and an increase in 85 gloss of no more than 15 gloss units when subjected to various ABRASION TEST METHODS as defined herein.
摘要:
Radar transmissive pigments, coatings, films, articles, method of manufacture thereof, and methods of use thereof are provided. The pigment comprises a non-conductive composite. The non-conductive composite comprises a semiconductor and/or a dielectric, and a metal dispersed in and/or on the semiconductor and/or dielectric. The pigment has an aspect ratio of at least 5 as measured by the Aspect Ratio Test.
摘要:
The present invention is directed to a method of mitigating ice build-up on a substrate, comprising applying to the substrate curable film-forming compositions comprising isocyanate-functional curing agents, film-forming compositions with functional groups reactive with the isocyanates, acrylic polymers having polysiloxane side chains, and polysiloxanes.
摘要:
A coating composition is disclosed comprising a film-forming resin and a catalyst component. The catalyst component comprises a catalyst contained within or encapsulated by a carrier; at least some of the catalyst is capable of being released from the carrier via diffusion through the carrier and into the coating composition. Methods of controlling the rate of cure of a curable film-forming composition and increasing the pot life of the composition by adding such catalyst components are also disclosed.
摘要:
Coating compositions comprising a film-forming resin and catalyst associated with a carrier, wherein at least some of the catalyst can be released from the carrier upon application of shear force is disclosed. Methods of coating a substrate and substrates coated at least in part with such coatings are also disclosed.
摘要:
The present invention is directed to curable film-forming compositions and coating kits, each comprising: (a) a polyepoxide functional polymer; (b) a polythiol functional compound, wherein the polythiol functional compound comprises at least two or at least three thiol functional groups and wherein if the polythiol functional compound contains hydroxyl functional groups, the ratio of thiol functional groups to hydroxyl functional groups within the polythiol functional compound is not 1:1; (c) a reactive compound different from the polythiol functional compound (b), containing multiple pendant and/or terminal functional groups selected from carboxylic acid, anhydride, amine and phenol that are reactive with epoxide functional groups; and (d) a pigment. The curable film-forming composition demonstrates a pigment to binder ratio greater than or equal to 2 and less than 3, adhesion to diverse substrates, and fast sandability. The present invention is further directed to coated articles and methods of forming them.
摘要:
The present invention is directed to catalytic compositions and to curable compositions containing them. Catalytic compositions of the present invention consist essentially of: (i) a metal compound; and (ii) a compound different from (i) that catalyzes an addition reaction between an ethylenically unsaturated compound and a thiol, wherein said catalytic composition is essentially free of vanadium compounds. Curable compositions according to the present invention comprise: (a) a polyene, (b) a polythiol, and (c) a catalytic component, which consists of the afore-mentioned catalytic composition.
摘要:
Curable film-forming compositions are provided. The compositions comprise (a) a curing agent comprising reactive functional groups; (b) a film-forming compound comprising functional groups reactive with the reactive functional groups in (a); and (c) a catalyst component added to the curable film-forming composition as a dispersion of micelles in a continuous phase. The catalyst component (c) comprises a catalyst compound contained within or encapsulated by a carrier, and the catalyst compound and carrier together form the micelles in the continuous phase. The carrier comprises block copolymers that comprise at least one hydrophobic block derived from hydrophobic monomers and at least one hydrophilic block derived from (1) hydrophilic monomers and/or (2) monomers containing groups that may be rendered hydrophilic after polymerization.