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    METHOD AND COMPOSITION FOR REDUCING NITRATES, NITRITES, AND/OR HYDROXYLAMINE IN WATER USING A HOMOGENEOUS REDUCED COPPER TETRA-SUBSTITUTED FLUORINATED PINACOLATE LIGAND CATALYST COMPLEX
    1.
    发明申请
    METHOD AND COMPOSITION FOR REDUCING NITRATES, NITRITES, AND/OR HYDROXYLAMINE IN WATER USING A HOMOGENEOUS REDUCED COPPER TETRA-SUBSTITUTED FLUORINATED PINACOLATE LIGAND CATALYST COMPLEX 审中-公开
    使用均相还原铜取代的氟化锑酸锂配位催化剂复合物在水中还原硝酸盐，硝酸盐和/或羟基胺的方法和组合物

    公开(公告)号：WO2016123443A1

    公开(公告)日：2016-08-04

    申请号：PCT/US2016/015571

    申请日：2016-01-29

    申请人： TRUSTEES OF BOSTON UNIVERSITY

    发明人： DOERRER, Linda, H. ,  HANNIGAN, Steven, F. ,  TAHSINI, Laleh ,  KOTYK, Christopher, M.

    IPC分类号： C02F1/467

    CPC分类号： C02F1/70 ,  B01J31/1625 ,  B01J31/1633 ,  B01J31/223 ,  B01J37/348 ,  B01J2231/70 ,  B01J2531/16 ,  C02F1/4676 ,  C02F1/4678 ,  C02F1/705 ,  C02F2101/16 ,  C02F2101/163 ,  C02F2101/166 ,  C02F2103/007 ,  C02F2103/06

    摘要： A method for reducing nitrates, nitrites, and/or hydroxylaminc in water using a homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex. The method includes dissolving a copper(II) tetra-substituted fluorinated pinacolate ligand pre-catalyst complex in water having an excess amount of nitrates, nitrites, and/or hydroxylamine therein. The dissolved copper(II) tetra-substituted fluorinated pinacolate ligand pre-catalyst complex in the water is subjected to electrochemical reduction to form a homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex. The homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex reduces the nitrates, nitrites, and/or hydroxylamine in the water to compounds with nitrogen in a lower oxidation state with the homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex.

    摘要翻译： 一种使用均相还原铜四取代的氟代频哪醇配体催化剂络合物还原硝酸盐，亚硝酸盐和/或羟胺的方法。 该方法包括将四（二）四氟取代的氟代卡拉卡定氟化物配位体预催化剂配合物溶解在其中具有过量硝酸盐，亚硝酸盐和/或羟胺的水中。 将溶解在水中的溶解的铜（II）四取代的氟代卡拉酯络合物配体预催化剂络合物进行电化学还原以形成均匀的还原铜四取代氟化频哪醇酸酯配体催化剂络合物。 均相还原铜四取代的氟化聚磷酸酯络合物配体催化剂配合物将水中的硝酸盐，亚硝酸盐和/或羟胺还原为具有较低氧化态的氮的化合物与均匀的还原铜四取代氟化频哪醇酸配体催化剂络合物。

    PROCESS FOR THE REMOVAL AND RETURN OF A CATALYST TO A LIQUID PHASE MEDIUM
    3.
    发明申请
    PROCESS FOR THE REMOVAL AND RETURN OF A CATALYST TO A LIQUID PHASE MEDIUM 审中-公开
    将催化剂移除和返回到液相介质的方法

    公开(公告)号：WO2014083109A2

    公开(公告)日：2014-06-05

    申请号：PCT/EP2013074974

    申请日：2013-11-28

    申请人： PHOSPHONICS LTD ,  MURRAY PAUL

    发明人： MURRAY PAUL ,  WILKES ROBIN ,  NORTH CHRISTOPHER

    IPC分类号： C08G77/385 ,  B01J20/32 ,  C08G77/388 ,  C08G77/392 ,  C08G77/395

    CPC分类号： C07F7/10 ,  B01J31/069 ,  B01J31/1633 ,  B01J31/1658 ,  B01J31/2409 ,  B01J2231/321 ,  B01J2231/42 ,  B01J2231/4211 ,  B01J2531/0205 ,  B01J2531/16 ,  B01J2531/80 ,  B01J2531/824 ,  B01J2531/842 ,  B01J2531/847 ,  C07F7/0834 ,  C07F17/02 ,  C08G77/385 ,  C08G77/388 ,  C08G77/392 ,  C08G77/395 ,  Y02P20/588

    摘要： A process for the selective removal of a component from a liquid phase and subsequently returning the component to a liquid phase is disclosed. A novel compound of formula (I) [SUP]-[[L]-[G]]a (I) in which L is a linking group, G is an aryl group having a leaving group LG selected from Cl, Br, I, sulfonate such as triflate, a diazo group, a nitrile, an ester and an alkoxy group and substituent Q is selected from H, NR2, OR, C02R, F, Cl, N02 CN and SUP is a support having a plurality of groups -[L]-[G] bound to the support is contacted with the liquid phase to bind the component to the compound I thereby forming a captured component which is separated from and may be returned to the liquid phase. The compound I is especially useful in binding homogeneous catalysts to remove it from a reaction medium and selectively returning the catalyst to the reaction medium at a later stage. The compound is particularly useful for cross-coupling reactions, for example in Suzuki reactions.

    摘要翻译： 公开了一种从液相中选择性除去组分并随后将组分返回到液相的方法。 其中L是连接基团的式（I）[SUP] - [[L] - [G]] a（I）的新型化合物，G是具有选自Cl，Br，I ，磺酸盐如三氟甲磺酸盐，重氮基团，腈，酯和烷氧基，取代基Q选自H，NR2，OR，CO 2 R，F，Cl，NO 2 CN，而SUP是具有多个基团的支链 - 与载体接触的[L] - [G]与液相接触以将组分与化合物I结合，从而形成捕获的组分，该捕获组分与液相分离并返回到液相。 化合物I特别可用于结合均匀的催化剂以将其从反应介质中除去并且在稍后阶段选择性地将催化剂返回到反应介质中。 该化合物特别可用于交叉偶联反应，例如在Suzuki反应中。

    IMMOBILIZABLE RUTHENIUM(II)-CATALYSTS WITH A SUBSTITUTED CENTRAL ATOM, METHOD FOR THE PRODUCTION AND USE THEREOF
    9.
    发明申请
    IMMOBILIZABLE RUTHENIUM(II)-CATALYSTS WITH A SUBSTITUTED CENTRAL ATOM, METHOD FOR THE PRODUCTION AND USE THEREOF 审中-公开
    在中环原子取代，可固定钌（II）催化剂，方法使用和

    公开(公告)号：WO2006018161A3

    公开(公告)日：2006-07-13

    申请号：PCT/EP2005008526

    申请日：2005-08-05

    申请人： MERCK PATENT GMBH ,  KOEHLER KATRIN ,  VEHLOW KATI ,  BLECHERT SIEGFRIED

    发明人： KOEHLER KATRIN ,  VEHLOW KATI ,  BLECHERT SIEGFRIED

    IPC分类号： B01J31/16 ,  B01J31/02 ,  B01J31/22 ,  B01J31/24 ,  B01J37/02 ,  C07C6/04 ,  C07F15/00

    CPC分类号： C07C6/04 ,  B01J31/1608 ,  B01J31/1633 ,  B01J31/2273 ,  B01J31/2404 ,  B01J37/0209 ,  B01J2231/321 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2231/54 ,  B01J2531/821 ,  B01J2540/22 ,  C07C2531/16 ,  C07F15/0046

    摘要： The invention relates to immobilizable ruthenium(II)-catalysts having general formulae (I) and (II), containing an SiR' n (OR') 3-n structural group on at least one of the two anions. The invention also relates to a method for the production and use of compounds in a method for the production of ruthenium (II)-catalysts having general formulae (I) and (II) immobilized on inorganic oxide carriers. The invention further relates to the use of compounds having general formulae (I), (la), (II) and (IIa) as catalysts in organic and metalorganic synthesis. Said compounds can be used as catalysts in C-C coupling reactions, hydrogenations, isomerizations, silylations and hydroformylations. They can be used in particular as catalysts in olefin metathetical reactions such as cross metathesis (CM), ring closure metathesis (RCM), ring opening metathesis (ROM), ring opening metathesis-polymerization (ROMP), acyclic diene metathesis-polymerization (ADMET) and En-In metathesis or in a combination of various metathetical reactions.

    摘要翻译： 本发明涉及一种可固定钌（II）通式（I）和（II）的SIR '名词（OR'） 3-n的组轴承在催化剂 两个阴离子中的至少一个。 本发明还涉及用于它们的制备方法和在方法中的用途的化合物的用于生产无机氧化物载体固定化的钌（II）通式（Ia）和催化剂（IIa）中。 本发明还提供了通式（I），（IA），（II）和化合物（IIA），如有机和有机金属合成催化剂。 它们可以被用来作为在C-C偶联反应，氢化，异构化，Silylations和加氢甲酰化催化剂。 特别是，它们用作在烯烃复分解反应，如交叉复分解（CM），闭环复分解（RCM），开环复分解（ROM），开环易位聚合（ROMP），无环二烯烃易位聚合（ADMET），催化剂和烯炔结合复分解或不同类型 复分解反应。