公开(公告)号：WO2016091771A1

公开(公告)日：2016-06-16

申请号：PCT/EP2015/078756

申请日：2015-12-07

Applicant: RHODIA OPERATIONS

Inventor： DAMBRIN, Valery ,  REVELANT, Denis

IPC: C07C303/00 ,  C07C303/02 ,  C07C303/22 ,  C07C309/00 ,  C07C309/06 ,  C07B45/04

CPC classification number: C07C303/02 ,  C07C303/00 ,  C07C309/06 ,  C07C309/00

Abstract: La présente invention concerne un procédé de préparation d'un dérivé oxysulfuré et fluoré de formule (III) Ea-SO 3 R (III) comprenant la mise en contact, en présence d'un solvant organique aprotique polaire, d'un composé de formule (II) Ea-SOOR (II) - Ea représentant l'atome de fluor ou un groupe ayant de 1 à 10 atomes de carbone choisi parmi les fluoroalkyles, les perfluoroalkyles et les fiuoroalkényles; et - R représentant l'hydrogène, un cation monovalent ou un groupe alkyle; avec un agent oxydant.

Abstract translation: 本发明涉及一种制备式（III）的氧硫化物和氟化衍生物的方法，其包括使式（II）化合物Ea-SOOR（II）-Ea表示氟原子的化合物或具有 选自氟代烷基，全氟烷基和氟烯基的1至10个碳原子; 和-R代表氢，一价阳离子或烷基; 在极性非质子有机溶剂的存在下与氧化剂接触。

公开(公告)号：WO2009073426A2

公开(公告)日：2009-06-11

申请号：PCT/US2008/084464

申请日：2008-11-24

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  JUNK, Christopher, P. ,  ROSTOVTSEV, Vsevolod ,  SIEVERT, Allen, Capron ,  SPRAGUE, Lee, G.

Inventor： JUNK, Christopher, P. ,  ROSTOVTSEV, Vsevolod ,  SIEVERT, Allen, Capron ,  SPRAGUE, Lee, G.

IPC: C07C303/00 ,  C07C309/00

CPC classification number: C07C303/00 ,  C07C309/00

Abstract: The invention provides a process for the preparation of fluorinated alkanesulfonic acid anhydrides by contacting alkanesulfonic acids with phosphorus pentoxide, the phosphorus pentoxide being provided as a dispersion in an inert oil. The invention also provides novel fluorinated alkanesulfonic acid anhydrides including 2-hydrotetrafluoroethanesulfonic acid anhydride.

Abstract translation: 本发明提供了一种通过使烷基磺酸与五氧化磷接触来制备氟化烷基磺酸酐的方法，五氧化二磷作为分散体提供在惰性油中。 本发明还提供包含2-氢四氟乙磺酸酐的新型氟化烷基磺酸酐。

公开(公告)号：WO2008012433A3

公开(公告)日：2008-03-13

申请号：PCT/FR2007001276

申请日：2007-07-25

Applicant: RHODIA OPERATIONS ,  BESSON BERNARD

Inventor： BESSON BERNARD

IPC: C07C303/00 ,  C07C309/06

CPC classification number: C07C303/00 ,  C07C309/00

Abstract: The present invention relates to a process for preparing a sulphonic acid anhydride, and more particularly to the preparation of triflic anhydride. The process for preparing a sulphonic acid anhydride according to the invention is characterized in that it comprises reacting a sulphonic acid or a mixture of two sulphonic acids with a reactant exhibiting pseudo acid halide tautomerism with at least one carbon atom which is involved in the tautomerism bearing two halogen atoms.

Abstract translation: 本发明涉及一种制备磺酸酐的方法，更具体地说涉及制备三氟甲磺酸酐。 根据本发明的制备磺酸酐的方法的特征在于它包括使磺酸或两种磺酸的混合物与表现出假酸卤化物互变异构体的反应物与至少一个碳原子反应，所述碳原子参与互变异构体轴承 两个卤素原子。

公开(公告)号：WO2007147782A2

公开(公告)日：2007-12-27

申请号：PCT/EP2007/055936

申请日：2007-06-15

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  YAMATO, Hitoshi ,  ASAKURA, Toshikage ,  NISHIMAE, Yuichi ,  IWAI, Takeshi ,  IRIE, Makiko ,  NAKAYAMA, Kazuhiko

Inventor： YAMATO, Hitoshi ,  ASAKURA, Toshikage ,  NISHIMAE, Yuichi ,  IWAI, Takeshi ,  IRIE, Makiko ,  NAKAYAMA, Kazuhiko

IPC: G03F7/039 ,  G03F7/027 ,  C07C309/00 ,  G03C1/73

CPC classification number: G03F7/0045 ,  C07C309/00 ,  C07C2603/18 ,  C08F20/36 ,  G03F7/0046 ,  G03F7/0397

Abstract: Compounds of the formula (I), (Il) or (III), wherein R 1 is for example C 1 -C 18 alkylsulfonyl, C 1 -C 10 haloalkylsulfonyl, camphorylsulfonyl, phenyl-C 1 -C 3 alkylsulfonyl, phenylsulfonyl, naphthylsulfonyl, anthrylsulfonyl, phenanthrylsulfonyl or heteroarylsulfonyl, R' 1 is for example phenylenedisulfonyl, R 2 is for example CN, C 1 -C 10 haloalkyl or C 1 -C 10 haloalkyl which is substituted by (IV); Ar 1 is for example phenyl optinally substituted by a group of formula (IV); Ar' 1 is for example phenylene which optionally is substituted by a group of formula (IV); A 1 , A 2 and A 3 independently of each other are for example hydrogen, halogen, CN, or C 1 -C 18 alkyl; D 2 is for example a direct bond, O, (CO)O, (CO)S, SO 2 , OSO 2 or C 1 -C 18 alkylene; or A 3 and D 2 together form C 3 -C 30 cycloalkenyl; or A 2 and D 2 together with the carbon of the ethylenically unsaturated double bond to which they are attached form C 3 -C 30 cycloalkyl; D 3 and D 4 for example independently of each other are a direct bond, O, S, C 1 -C 18 alkylene or C 3 -C 30 cycloalkylene provided that at least one of the radicals R 2 , Ar 1 or Ar 1 ' comprises a group of the formula (IV); are suitable as photolatent acid donors and for the preparation of corresponding polymers to be employed in chemically amplified photoresists.

Abstract translation: 式（I），（II）或（III）的化合物，其中R 1是例如C 1 -C 18烷基磺酰基， C 1 -C 10卤代烷基磺酰基，樟脑磺酰基，苯基-C 1 -C 3烷基磺酰基，苯基磺酰基，萘基磺酰基， 蒽基磺酰基，菲基磺酰基或杂芳基磺酰基，R 1'是例如亚苯基二磺酰基，R 2是例如CN，C 1 -C 10 （IV）取代的卤代烷基或C 1 -C 10 - 卤代烷基; Ar 1是例如被式（IV）基团取代的苯基; Ar'1是例如任选被式（IV）的基团取代的亚苯基; 彼此独立的A 1，A 2，A 3和A 3是例如氢，卤素，CN或C 1〜 SUB> -C _{18 烷基; D 2是例如直接键合O，（CO）O，（CO）S，SO 2，OSO 2或C < SUB> 1 -C 18 亚烷基; 或A 3和D 2一起形成C 3〜C 30环烯基; 或者它们所连接的烯属不饱和双键的碳一起形成C 3 -C 3亚烷基， 30 环烷基; D 3和D 4，例如彼此独立地是直接键，O，S，C 1 -C 18， / SUB>亚烷基或C 3 -C 30亚环烷基，条件是基团R 2，Ar 1中的至少一个， 或者是式（Ⅳ）所示的基团。 适合作为光潜酸供体，并用于制备用于化学放大光致抗蚀剂的相应聚合物。}

公开(公告)号：WO1991001968A1

公开(公告)日：1991-02-21

申请号：PCT/HU1990000051

申请日：1990-07-25

Applicant: CHINOIN GYOGYSZER- ÉS VEGYÉSZETI TERMÉKEK GYARA ... ,  BAN, Károly ,  BAN, Annamária ,  PALI, Lajosné ,  KRUPPA, Márta ,  SOMFAI, Éva ,  HUSZAR, Csaba

Inventor： CHINOIN GYOGYSZER- ÉS VEGYÉSZETI TERMÉKEK GYARA ...

IPC: C07C229/36

CPC classification number: C07D307/58 ,  C07C227/18 ,  C07C229/36 ,  C07C309/00

Abstract: Process for the preparation of compounds (I), wherein X, Y, A and R are defined as in Claim 1, by reaction of a substituted phenyl-glycine (VII) in the presence of alkanol with 1.05-1.3 moles of alkali-hydroxide and reacting the reaction mixture with an acid, the pH-value of which is higher than 4.3, or by reaction of (VII) with an equivalent amount of alkali salts derived from acids having a pH value higher than 4.3, and condensing the obtained amine acid salt in the presence of alkanol with a compound (VIII) -R is defined as in Claim 1- at the boiling point of the reaction mixture, removing water continuously from the reaction mixture by a binary or ternary azeotropic distillation. The thus obtained compound is optionally reacted with a reactive derivative of trifluoro-methane-sulphonic acid.

Abstract translation: 化合物（I）的制备方法，其中X，Y，A和R 2如权利要求1所定义，通过在烷醇存在下取代的苯基 - 甘氨酸（VII）与1.05-1.3摩尔 碱金属氢氧化物，并使反应混合物与其pH值高于4.3的酸反应，或通过（Ⅶ）与等于pH值大于4.3的酸等量的碱金属盐反应，并使 在烷醇与化合物（VIII）-R 1的存在下，所得的胺酸盐在反应混合物的沸点下定义，如权利要求1所述，通过二元或三元共沸从反应混合物中连续除去水 蒸馏。 由此获得的化合物任选地与三氟甲烷磺酸的反应性衍生物反应。

公开(公告)号：WO1985003075A1

公开(公告)日：1985-07-18

申请号：PCT/US1985000057

申请日：1985-01-14

Applicant: CRONYN, Marshall, W.

IPC: C07C143/68

CPC classification number: C07F7/0834 ,  C07C309/00 ,  C07D327/00

Abstract: Bifunctional cyclic disulfonic ester compounds effective in treating certain types of cancers. Initial nucleophilic reaction with the compound produces a negatively charged sulfonic acid end-group which remains attached to the compound until a second alkylation reaction can occur.

Abstract translation: 双官能环状二磺酸酯化合物有效治疗某些类型的癌症。 与化合物的初始亲核反应产生负电荷的磺酸端基，其保持与化合物连接，直至发生第二烷基化反应。

公开(公告)号：WO1984000959A1

公开(公告)日：1984-03-15

申请号：PCT/JP1983000300

申请日：1983-09-06

Applicant: TAIHO PHARMACEUTICAL COMPANY, LIMITED ,  FUJII, Setsuro ,  OGAWA, Kazuo ,  MURANAKA, Yoshiyuki ,  HAMAKAWA, Toshihiro

Inventor： TAIHO PHARMACEUTICAL COMPANY, LIMITED

IPC: C07C143/68

CPC classification number: C07C309/00

Abstract: Sulfonic ester derivatives represented by general formula (I), wherein R1 represents hydrogen, C1-4 alkyl or C$(,3)$-4 alkoxy, A represents (II), (wherein R2 and R3 each represent C1-4 alkyl) or (III), (wherein R4 and R5 each represent C1-4 alkyl, or they may be connected to each other to form C4-6 cycloalkyl together with the adjacent carbon atom), and $(,3)$ represents an integer of 1 to 3, and a process for their preparation.

公开(公告)号：WO2018213572A1

公开(公告)日：2018-11-22

申请号：PCT/US2018/033175

申请日：2018-05-17

Applicant: WILLIAM MARSH RICE UNIVERSITY

Inventor： KATTAMURI, Padmanabha Venkatesh ,  KURTI, Laszlo

IPC: C07D211/60 ,  C07D211/78

CPC classification number: C07D409/12 ,  C07C227/06 ,  C07C251/08 ,  C07C251/38 ,  C07C309/00 ,  C07C311/06 ,  C07C311/19 ,  C07C319/20 ,  C07C381/00 ,  C07C2601/02 ,  C07C2601/04 ,  C07C2601/08 ,  C07C2601/14 ,  C07D211/58 ,  C07D213/127 ,  C07D213/74 ,  C07D307/79 ,  C07D317/66 ,  C07D333/36 ,  C07D333/66 ,  C07F7/1804 ,  C07C229/42 ,  C07C229/46 ,  C07C229/04 ,  C07C323/36

Abstract: In one aspect, the present disclosure provides methods of preparing a secondary amine. In some embodiments, the secondary amine comprises two different groups or two identifical groups. Also provided herein are compositions for use in the preparation of the secondary amine.

公开(公告)号：WO2015071455A1

公开(公告)日：2015-05-21

申请号：PCT/EP2014/074747

申请日：2014-11-17

Applicant: GRILLO-WERKE AG

Inventor： OTT, Timo ,  BIERTÜMPEL, Ingo

IPC: C07C309/00

CPC classification number: C07C409/44 ,  C07C303/06 ,  C07C309/00 ,  C07C407/00 ,  C07C309/04

Abstract: A compound of the formula (I) ALK-SO 2 -O-O-SO 2 OX, wherein ALK is a branched or unbranched alkyl group, especially a methyl, ethyl, propyl, butyl, isopropyl, isobutyl group, or a higher alkyl group, and X = hydrogen, zinc, aluminium, an alkali or alkaline earth metal.

Abstract translation: 式（I）的化合物，其中ALK是支链或非支链烷基，特别是甲基，乙基，丙基，丁基，异丙基，异丁基或高级烷基，X = 氢，锌，铝，碱金属或碱土金属。

公开(公告)号：WO2013040985A1

公开(公告)日：2013-03-28

申请号：PCT/CN2012/081062

申请日：2012-09-06

Applicant: TORAY ADVANCED MATERIALS RESEARCH LABORATORIES (CHINA) CO., LTD. ,  CHEN, Qiao ,  SHAO, Fangke ,  WU, Gang ,  IZUHARA, Daisuke ,  UMEDA, Hiroaki

Inventor： CHEN, Qiao ,  SHAO, Fangke ,  WU, Gang ,  IZUHARA, Daisuke ,  UMEDA, Hiroaki

IPC: C08G65/40 ,  C07C303/06 ,  H01M8/02 ,  H01M8/10 ,  H01B1/06

CPC classification number: C08G65/00 ,  C07C309/00 ,  C07C309/44 ,  C07C317/14 ,  C08G65/4043 ,  C08G65/4056 ,  H01B1/122 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1032 ,  H01M8/1034 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56

Abstract: It is an object of the present invention to provide a sulfonic acid group- containing polymer and a sulfonic acid group-containing aromatic compound, which have excellent proton conductivity even under the low humidification condition, are excellent in mechanical strength and chemical stability and, moreover, can attain high output and excellent physical durability when processed into a solid polymer fuel cell, as well as a polymer electrolyte material, a polymer electrolyte molded product and a solid polymer fuel cell respectively using the same. The sulfonic acid group-containing polymer of the present invention is a sulfonic acid group-containing polymer comprising a constituent unit containing a sulfonic acid group (A1), and a constituent unit not containing a sulfonic acid group (A2), wherein the polymer contains a constituent unit having a specified structure as at least one constituent unit containing a sulfonic acid group (A1) at 25 mol% or more based on a sum of the constituent unit containing a sulfonic acid group (A1). Further, the polymer electrolyte material, polymer electrolyte molded product and solid polymer fuel cell of the present invention are constituted using such a sulfonic acid group-containing polymer.

Abstract translation: 本发明的目的是提供即使在低加湿条件下也具有优异的质子传导性的含磺酸基的聚合物和含磺酸基的芳族化合物，其机械强度和化学稳定性优异，此外 当加工成固体聚合物燃料电池时，可以获得高产量和优异的物理耐久性，以及分别使用它们的聚合物电解质材料，聚合物电解质模制产品和固体聚合物燃料电池。 本发明的含磺酸基的聚合物是含有含有磺酸基（A1）的构成单元和不含磺酸基（A2）的构成单元的含磺酸基的聚合物，其中，聚合物含有 基于含有磺酸基（A1）的构成单元的总和，具有指定结构的构成单元作为至少一种含有25mol％以上的磺酸基（A1）的构成单元。 此外，本发明的高分子电解质材料，高分子电解质成型体和固体高分子型燃料电池使用这样的含有磺酸基的聚合物构成。