PFAS REMEDIATION METHOD AND SYSTEM
    2.
    发明申请

    公开(公告)号:WO2020005966A1

    公开(公告)日:2020-01-02

    申请号:PCT/US2019/039020

    申请日:2019-06-25

    Abstract: A method and system to remediate soil containing PFAS compounds and organic carbon. Total organic carbon is reduced by heating the soil at a sufficient temperature and for a sufficient duration to reduce surface effects between the PFAS compounds and the organic carbon to permit evaporation and treatment of the PFAS compounds from the soil.

    PRODUCING CF3CH2CF3 AND/OR CF3CH=CF2 BY THE CONVERSION OF ALPHA-HYDROPERFLUOROISOBUTYRIC ACID COMPOUNDS
    6.
    发明申请
    PRODUCING CF3CH2CF3 AND/OR CF3CH=CF2 BY THE CONVERSION OF ALPHA-HYDROPERFLUOROISOBUTYRIC ACID COMPOUNDS 审中-公开
    通过ALPHA-水合氯代异丁酸化合物的转化制备CF 3 CH 2 CF 3和/或CF 3 CH = CF 2

    公开(公告)号:WO1996032364A1

    公开(公告)日:1996-10-17

    申请号:PCT/US1996005219

    申请日:1996-04-15

    CPC classification number: C07C17/00 C07C17/361 C07C17/363 C07C21/18 C07C19/08

    Abstract: A process is disclosed for producing 1,1,1,3,3,3-hexafluoropropane and/or 1,1,1,3,3-pentafluoropropene from (CF3)2CHCOOH and/or its water soluble salts. The process involves providing a mixture containing water and such carboxy compound(s) which has a pH of less than about 4, and reacting the mixture at a temperature of at least about 75 DEG C. Certain ether compounds may be included in the mixture along with (CF3)2CHCOOH and/or its water soluble salts. The reaction of the carboxy (and optionally ether) compound(s) with water may be employed in connection with a process for producing tetrafluoroethylene and/or hexafluoropropylene by pyrolysis, where by-product perfluoroisobutylene is reacted with water (and optionally an alkanol) to produce (CF3)2CHCOOH (and optionally one or more ether compounds).

    Abstract translation: 公开了从(CF 3)2 CHCOOH和/或其水溶性盐制备1,1,1,3,3,3-六氟丙烷和/或1,1,1,3,3-五氟丙烯的方法。 该方法包括提供含有水的混合物和pH小于约4的羧基化合物,并在至少约75℃的温度下使混合物反应。某些醚化合物可以包含在混合物中 与(CF 3)2 CHCOOH和/或其水溶性盐。 羧基(和任选的醚)化合物与水的反应可以用于通过热解制备四氟乙烯和/或六氟丙烯的方法,其中副产物全氟异丁烯与水(和任选的烷醇)反应到 产生(CF 3)2 CHCOOH(和任选的一种或多种醚化合物)。

    PROCESS FOR PREPARING FLUOROBENZENE DERIVATIVES AND BENZOIC ACID HYPOFLUORITE DERIVATIVES

    公开(公告)号:WO2021036048A1

    公开(公告)日:2021-03-04

    申请号:PCT/CN2019/120701

    申请日:2019-11-25

    Abstract: Provided is a process for the manufacture of a fluorinated benzene derivative starting from benzoic acid derivative by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F2) is preferably present in a high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite derivative obtained by direct fluorination. The fluorination process of the invention may be performed batch-wise or in a continuous manner. If the process is performed batch-wise, a column (tower) reactor may be used. If the process is continuous a microreactor may be used.

    PROCESS FOR PREPARING FLUOROBENZENE AND BENZOIC ACID HYPOFLUORITE

    公开(公告)号:WO2021036047A1

    公开(公告)日:2021-03-04

    申请号:PCT/CN2019/120700

    申请日:2019-11-25

    Abstract: A process for the manufacture of a fluorinated benzene starting from benzoic acid by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F2) is preferably present in a high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite obtained by direct fluorination. And a process for the manufacture of a benzoic acid hypofluoriteby direct fluorination of benzoic acid. The fluorination process may be performed batch-wise or in a continuous manner. If the process is performed batch-wise, a column (tower) reactor may be used. If the process is continuous, a micro-reactor may be used.

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