Abstract:
Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Bistolanen, die in der 1,1 '-Position mit Halogen substituiert sind und von Erzeugnissen aus diesen Verbindungen. Die C-C-Dreifachbindungen der Bistolane werden durch Eliminierungsreaktionen erzeugt.
Abstract:
A method and system to remediate soil containing PFAS compounds and organic carbon. Total organic carbon is reduced by heating the soil at a sufficient temperature and for a sufficient duration to reduce surface effects between the PFAS compounds and the organic carbon to permit evaporation and treatment of the PFAS compounds from the soil.
Abstract:
The present invention refers to a process for preparing a compound of the formula (I) wherein R denotes an organic radical which, together with the two carbon atoms to which it is bonded, forms a carbocyclic or heterocyclic ring; R 1 , R 2 , R 3 and X, independently, denote hydrogen, halogen, nitro, cyano or an organic radical; or R 1 and R 2 or R 2 and R 3 , together with the carbon atoms to which they are bonded, form a ring; which comprises exposing a compound of the formula (II) wherein R 1 , R 2 , R 3 and X are defined as given above and Y and Z, independently, have one of the meanings of X; to an energy source in the presence of a catalyst system.
Abstract:
The present invention provides a process for the preparation of organic bromides, by a radical bromodecarboxylation of carboxylic acids with a bromoisocyanurate.
Abstract:
Verfahren zur Herstellung von 5-Halo-2,4,6-Trifluorisophthalsäure der Formel (I) wobei X für F, Cl, Br, oder I steht, durch Hydrolyse von 5-Halo-2,4,6-Trifluorisophthalodinitril der Formel (II), dadurch gekennzeichnet, dass man in einem ersten Schritt unter Bildung von 5-HaIo-2,4,6-Trifluorisophthalodiamid der allgemeinen Formel (III) Isophthalodinitril (II) oder eine Isophthalodinitril (II) enthaltende Lösung mit konzentrierter Schwefelsäure bei Raumtemperatur versetzt und anschließend erhitzt und in einem zweiten Schritt unter weiterem Erhitzen und Zugeben von Wasser Isophthalsäure (I) herstellt.
Abstract:
A process is disclosed for producing 1,1,1,3,3,3-hexafluoropropane and/or 1,1,1,3,3-pentafluoropropene from (CF3)2CHCOOH and/or its water soluble salts. The process involves providing a mixture containing water and such carboxy compound(s) which has a pH of less than about 4, and reacting the mixture at a temperature of at least about 75 DEG C. Certain ether compounds may be included in the mixture along with (CF3)2CHCOOH and/or its water soluble salts. The reaction of the carboxy (and optionally ether) compound(s) with water may be employed in connection with a process for producing tetrafluoroethylene and/or hexafluoropropylene by pyrolysis, where by-product perfluoroisobutylene is reacted with water (and optionally an alkanol) to produce (CF3)2CHCOOH (and optionally one or more ether compounds).
Abstract:
Provided is a process for the manufacture of a fluorinated benzene derivative starting from benzoic acid derivative by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F2) is preferably present in a high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite derivative obtained by direct fluorination. The fluorination process of the invention may be performed batch-wise or in a continuous manner. If the process is performed batch-wise, a column (tower) reactor may be used. If the process is continuous a microreactor may be used.
Abstract:
A process for the manufacture of a fluorinated benzene starting from benzoic acid by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F2) is preferably present in a high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite obtained by direct fluorination. And a process for the manufacture of a benzoic acid hypofluoriteby direct fluorination of benzoic acid. The fluorination process may be performed batch-wise or in a continuous manner. If the process is performed batch-wise, a column (tower) reactor may be used. If the process is continuous, a micro-reactor may be used.
Abstract:
The present invention provides a halo-de-carboxylation process for the preparation of organic chlorides, organic bromides and mixtures thereof, from their corresponding carboxylic acids, using a chlorinating agent selected from trichloroisocyanuric acid (TCCA), dichloroisocyanuric acid (DCCA), or combination thereof, and a brominating agent.