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公开(公告)号：WO2018202707A1
公开(公告)日：2018-11-08
申请号：PCT/EP2018/061201
申请日：2018-05-02
Applicant: BASF SE , MICRONISERS PTY LTD
Inventor： JAYARATNE, Vidura Nalin , TURNEY, Terence William , HORTON, Murray , DABBOUS, Raphael
Abstract: A method of manufacture of zinc monoglycerolate containing an incorporated modifier, and the product, the zinc monoglycerolate being in the form of agglomerates of crystallites, wherein the crystallite size based on the average coherence domain length is not more than 30nm in the direction, and not more than 60nm in the direction, as determined by the Scherrer equation via powder X-ray diffraction; and the aspect ratio computed by / coherent domain lengths is less than 0.65, preferably less than 0.56, in particular less than 0.44. Polymers containing this nucleating agent and methods for their production are also described. The zinc monoglycerolate is useful as a nucleating agent, and is very effective at low loading levels in polymers such as polypropylene.
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公开(公告)号：WO2015177764A1
公开(公告)日：2015-11-26
申请号：PCT/IB2015/053777
申请日：2015-05-22
Applicant: RELIANCE INDUSTRIES LIMITED
Inventor： GUPTA, Virendrakumar , CHAUHAN SANJAY, Govindbhai , BHAJIWALA HIREN, Manojkumar , SAYYED SHAKIL, Shabbir , VAKIL, Suketu
CPC classification number: C08F110/02 , C07C31/30 , C07F7/006 , C08F10/00
Abstract: The present disclosure relates to a single-pot process for the preparation of a shape controlled pro-catalyst. The process comprises the steps of i. reacting at least one alkanol with magnesium metal using at least one modifier and optionally, at least one solvent resulting in evolution of hydrogen gas, increasing the evolution of the hydrogen gas in a controlled manner by increasing the temperature in a graded manner to 100 °C to obtain a mass, and ii. subjecting the mass to drying to obtain a free flowing pro-catalyst.
Abstract translation: 本公开涉及用于制备形状控制的助催化剂的单锅法。 该方法包括以下步骤： 使用至少一种改性剂和任选的至少一种溶剂使至少一种链烷醇与镁金属反应，导致氢气逸出，通过以分级方式将温度升高到100℃，以受控的方式增加氢气的释放 以获得质量，ii。 使物料干燥以获得自由流动的前催化剂。
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公开(公告)号：WO2009130707A3
公开(公告)日：2009-10-29
申请号：PCT/IN2008/000555
申请日：2008-09-01
Applicant: RELIANCE INDUSTRIES LIMITED , GUPTA, Virendrakumar , SINGH, Saurabh , MAKWANA, Umesh , JOSEPH, Jomichan , SINGALA, Kamlesh , RAJESH, Smitha , PATEL, Vallabhbhai , YADAV, Mukeshkumar , SINGH, Gurmeet
Inventor： GUPTA, Virendrakumar , SINGH, Saurabh , MAKWANA, Umesh , JOSEPH, Jomichan , SINGALA, Kamlesh , RAJESH, Smitha , PATEL, Vallabhbhai , YADAV, Mukeshkumar , SINGH, Gurmeet
Abstract: The invention relates to a process for the synthesis of spheroidal magnesium alkoxide having improved mechanical strength and narrow particle size distribution, the process comprising reacting magnesium metal, in the presence of iodine, with a mixture of alcohols by step- wise heating first in the range of 40°C to 65°C for a period of 2 hours and then in the range of 65°C to 80°C for a period of 1 hour, further by maintaining reaction temperature at 80°C for a period of 6 - 10 hours, the vapours of the mixture produced during the reaction being condensed in an overhead condenser, hydrogen gas produced during the reaction being vented off and the mixture of alcohols left after the reaction being filtered and reused. The invention also relates to spheroidal magnesium alkoxide particles synthesized by the method, to the Ziegler natta procatalyst synthesized by using the alkoxide and to the polymer resin synthesised using the procatalyst.
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4.发明申请
公开(公告)号：WO2009130707A2
公开(公告)日：2009-10-29
申请号：PCT/IN2008000555
申请日：2008-09-01
Applicant: RELIANCE IND LTD , GUPTA VIRENDRAKUMAR , SINGH SAURABH , MAKWANA UMESH , JOSEPH JOMICHAN , SINGALA KAMLESH , RAJESH SMITHA , PATEL VALLABHBHAI , YADAV MUKESHKUMAR , SINGH GURMEET
Inventor： GUPTA VIRENDRAKUMAR , SINGH SAURABH , MAKWANA UMESH , JOSEPH JOMICHAN , SINGALA KAMLESH , RAJESH SMITHA , PATEL VALLABHBHAI , YADAV MUKESHKUMAR , SINGH GURMEET
CPC classification number: C07C31/28 , C07C29/70 , C08F10/00 , C07C31/30 , C08F4/6494 , C08F4/6548
Abstract: The invention relates to a process for the synthesis of spheroidal magnesium alkoxide having improved mechanical strength and narrow particle size distribution, the process comprising reacting magnesium metal, in the presence of iodine, with a mixture of alcohols by step- wise heating first in the range of 40°C to 65°C for a period of 2 hours and then in the range of 65°C to 80°C for a period of 1 hour, further by maintaining reaction temperature at 80°C for a period of 6 - 10 hours, the vapours of the mixture produced during the reaction being condensed in an overhead condenser, hydrogen gas produced during the reaction being vented off and the mixture of alcohols left after the reaction being filtered and reused. The invention also relates to spheroidal magnesium alkoxide particles synthesized by the method, to the Ziegler natta procatalyst synthesized by using the alkoxide and to the polymer resin synthesised using the procatalyst.
Abstract translation: 本发明涉及一种合成具有改善的机械强度和窄粒度分布的球形镁醇盐的方法，该方法包括在碘存在下使镁金属与醇的混合物反应，首先在该范围内逐步加热 在40℃至65℃下进行2小时，然后在65℃至80℃的范围内，持续1小时，此外，通过将反应温度保持在80℃持续6-10分钟 在反应过程中产生的混合物的蒸气在塔顶冷凝器中冷凝，反应过程中产生的氢气被排出，反应后留下的醇的混合物被过滤并重复使用。 本发明还涉及通过该方法合成的球形烷醇镁颗粒，使用通过使用醇盐合成的齐格勒纳塔催化剂和使用前催化剂合成的聚合物树脂。
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5.发明申请
公开(公告)号：WO2007026017A2
公开(公告)日：2007-03-08
申请号：PCT/EP2006/065918
申请日：2006-09-01
Applicant: CHEMETALL GMBH , DIETZ, Rainer , EMMEL, Ute , WIETELMANN, Dr. Ulrich , KRÄMER, Gerd
Inventor： DIETZ, Rainer , EMMEL, Ute , WIETELMANN, Dr. Ulrich , KRÄMER, Gerd
CPC classification number: C07C29/70 , C07C31/30 , Y10T428/2982
Abstract: Gegenstand der vorliegenden Erfindung sind Magnesiumalkoxidgranulate, ein Verfahren zu deren Herstellung sowie deren Verwendung.
Abstract translation: 本发明的目的是镁的醇盐，它们的制备和它们的用途的方法。
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Patent Agency Ranking
公开(公告)号：WO2022167311A1
公开(公告)日：2022-08-11
申请号：PCT/EP2022/051869
申请日：2022-01-27
Applicant: EVONIK FUNCTIONAL SOLUTIONS GMBH
Inventor： ROETTGER, Dirk , REIMANN, Sebastian , PAUL, Niklas , RIX, Armin Matthias , ZITZEWITZ, Philip , SCHRÖDER, Moritz
Abstract: Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Alkalimetallalkoholaten im Gegenstrom durch Reaktivrektifikation, wobei das Alkalimetall aus Natrium und Kalium ausgewählt ist. Das Verfahren erfolgt in mindestens einer Reaktionskolonne und mindestens einer Rektifikationskolonne. Das erfindungsgemäße Verfahren zeichnet sich dadurch aus, dass der zum Betrieb der Kolonnen und somit zur Durchführung des Verfahrens genutzte Heizdampf kondensiert, und die Energie im erhaltenen Kondensat eingesetzt wird.
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公开(公告)号：WO2013058193A1
公开(公告)日：2013-04-25
申请号：PCT/JP2012/076502
申请日：2012-10-12
Applicant: 日本曹達株式会社
Inventor： 小林 仁
Abstract: 本発明は、粒径が小さくても、粒度分布が狭く、球状又は楕円体形状のマグネシウムアルコラートを提供することを目的とする。本発明により、金属マグネシウムと、アルコールと、ハロゲン又はハロゲン原子含有化合物の少なくとも一方とを、アルコール還流下の反応系に分割添加して反応させるマグネシウムアルコラートの製造方法において、金属マグネシウムと、アルコールと、ハロゲン又はハロゲン原子含有化合物の少なくとも一方との混合物を、分割添加毎に反応系に添加することを特徴とするマグネシウムアルコラートの製造方法が提供される。
Abstract translation: 本发明的目的是提供一种包含具有窄的粒度分布的球形或椭球形颗粒的醇镁，尽管粒径很小。 本发明提供了一种通过在醇流下在反应体系中通过镁金属，醇和卤素和/或含卤原子的化合物的分配加成和反应来制备醇镁的方法，其特征在于产生镁醇盐的方法 其中每个分配物将镁金属，醇和卤素或含卤原子的化合物的混合物加入到反应体系中。
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公开(公告)号：WO2007116815A1
公开(公告)日：2007-10-18
申请号：PCT/JP2007/057012
申请日：2007-03-23
CPC classification number: C07C29/70 , C07C31/28 , C08F10/00 , Y10T428/2982 , C08F4/6548 , C07C31/30
Abstract: Ｄ 50 で示される平均粒径が６０～２００μｍの範囲の球状又は楕円体状の粒子形状を有し、０．２～０．７ｇ／ｍｌの嵩比重を有し、内部にＴＥＭ観察による孔径が０．１～５μｍの細孔を多数有し、（Ｄ 90 −Ｄ 10 ）／Ｄ 50 で示される粒度分布が１以下であるジアルコキシマグネシウム粒状物。アルコール還流下の金属マグネシウムとアルコールとの反応系に粒状の金属マグネシウムとアルコールとを連続的または断続的に分割添加して反応させる。微粉を含まず、粒度分布が均一な、大粒径のジアルコキシマグネシウム粒状物が提供される。
Abstract translation: 公开了具有球形或椭圆形颗粒形状的二烷氧基镁颗粒材料，其平均颗粒直径由D 50表示为60至200μm，堆积比重为0.2至0.7g / ml，具有 在其内部具有通过TEM观察测量的孔径为0.1至5μm的多个微孔，并且具有由下式表示的晶粒度分布：（D> 90 < 10 ）/ D <50 <1。 颗粒状材料可以通过在醇的回流下进行包含金属镁和醇的反应体系的反应来制备，其中金属镁为颗粒形式，并且颗粒状金属镁和醇分别连续地或间歇地添加 部分。 可以生产不含细粉状材料并具有均匀的粒度分布和大的晶粒尺寸的二烷氧基镁颗粒材料。
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9.发明申请MIXED METAL ALKOXIDE AND CYCLOALKADIENYL CATALYSTS FOR THE PRODUCTION OF POLYOLEFINS 审中-公开用于生产聚烯烃的混合金属烷基氧化物和环烷基二烯基催化剂
公开(公告)号：WO01048037A1
公开(公告)日：2001-07-05
申请号：PCT/US2000/035377
申请日：2000-12-27
IPC: C07C31/28 , C07C31/30 , C07F7/00 , C07F7/28 , C07F17/00 , C07F19/00 , C08F4/02 , C08F4/44 , C08F4/654 , C08F4/656 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC classification number: C08F10/00 , C08F4/65912 , C08F210/16 , Y10S526/943 , C08F4/6567 , C08F4/651 , C08F4/6548 , C08F4/65904 , C08F210/14 , C08F2500/12
Abstract: A solid self-supported cycloalkadienyl catalyst component is disclosed that includes: (i) a mixed metal alkoxide complex which is the reaction product of a magnesium alkoxide or aryloxide and at least one group IVB metal-containing alkoxide or aryloxide; and (ii) Cp, where Cp is a cyclic or polycyclic hydrocarbon having from 3-30 carbon atoms. A self-supported hybrid catalyst also is disclosed which contains the above components (i) and (ii), as well as (iii) a Ziegler-Natta catalyst species. A method of making the self-supported cycloalkadienyl catalyst and the self-supported hybrid catalyst and a method of polymerizing olefins using the catalysts also are disclosed. The catalysts are capable of producing polyolefins in high yield having a broad molecular weight distribution, or a bimodal distribution.
Abstract translation: 公开了一种固体自支撑的环烷二烯基催化剂组分，其包括：（i）作为醇盐或芳氧化镁与至少一种IVB族金属的醇盐或芳氧基的反应产物的混合金属醇盐络合物; 和（ii）Cp，其中Cp是具有3-30个碳原子的环状或多环烃。 还公开了一种自支撑的杂化催化剂，其包含上述组分（i）和（ii），以及（iii）齐格勒 - 纳塔催化剂种类。 公开了一种制备自支撑的环二烯基催化剂和自支撑的杂化催化剂的方法和使用该催化剂聚合烯烃的方法。 催化剂能够以高产率生产具有宽分子量分布或双峰分布的聚烯烃。
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公开(公告)号：WO01042178A1
公开(公告)日：2001-06-14
申请号：PCT/EP2000/012440
申请日：2000-12-08
CPC classification number: B01D3/141 , B01D1/2856 , C07C29/70 , C07C31/30
Abstract: The invention relates to a method for producing alkali methylates from an aqueous alkaline lye that is optionally mixed with methanol and methanol in a reaction column, said column comprising at least 5, preferably 15 to 30 theoretical trays between the inlet of the alkaline lye and the site of addition of the methanol. According to the inventive method, the vapor methanol-water mixture formed during the reaction is separated in a reaction column. According to an embodiment of the invention, the reaction column that is configured as a bubble-tray, valve-tray or sieve-plate column is provided with trays, each letting through maximally 5 %, preferably
Abstract translation: 本发明涉及在具有至少5个，优选在反应中形成的碱溶液的进料点和甲醇的进料点和分解的蒸气的15至30个理论塔板的反应塔任选地与甲醇，碱金属氢氧化物和甲醇混合用于从水溶液制备碱金属甲醇盐的方法 甲醇 - 水混合物中的反应塔。 根据本发明的变体已被选择用于形成为泡罩，阀或Siebbödenkolonne反应塔，地板，其中最多5％，优选
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