BIOMASS LIQUEFACTION TO PRODUCE REFINERY-READY BIO-OIL

    公开(公告)号:WO2018187699A1

    公开(公告)日:2018-10-11

    申请号:PCT/US2018/026471

    申请日:2018-04-06

    摘要: A bio-oil product is produced from biomass material by subjecting the biomass material to a first stage liquefaction process, where the first stage liquefaction process includes combining the biomass material with a co-solvent including methanol and water to form a first slurry mixture, providing the slurry mixture within a first liquefaction reactor and maintaining the first slurry mixture at a sufficient temperature and pressure so as to convert a portion of the biomass material into a first liquefied bio-oil product as well as form a first aqueous product and a first solid product, and separating the first liquefied bio-oil product from the aqueous and solid products. The solid product obtained from the first stage liquefaction process is subjected to a second stage liquefaction process, where the second stage liquefaction process includes combining the first solid product with methane to form a second slurry mixture, and providing the second slurry mixture within a second liquefaction reactor and maintaining the second slurry mixture at a sufficient temperature and pressure so as to convert a portion of the first solid product to a second liquefied bio-oil product as well as form a second aqueous product and a second solid product.

    REMOVAL OF HYDROGEN IN A SIDE STREAM
    3.
    发明申请
    REMOVAL OF HYDROGEN IN A SIDE STREAM 审中-公开
    除去侧流中的氢

    公开(公告)号:WO2018007488A1

    公开(公告)日:2018-01-11

    申请号:PCT/EP2017/066867

    申请日:2017-07-06

    IPC分类号: C10G3/00 C07C1/20

    摘要: The present application relates to a process for conversion of methanol to hydrocarbons comprising aromatics (MTA), said process comprising the steps of - reacting a reactor feed comprising methanol over a bifunctional catalyst thereby obtaining a reaction efflu-ent, - separating the reaction effluent into at least an aqueous condensate stream, a liquid hydrocarbon stream and a gas stream, - obtaining a first recycle stream from the gas stream - obtaining a first side stream from the gas stream, - passing the first side stream through at least one hydrogen (H2) removal step thereby obtaining a hydrogen depleted stream, and - mixing the first recycle stream and the hydrogen depleted stream with a first feed stream comprising methanol to obtain the reactor feed.

    摘要翻译: 本申请涉及将甲醇转化成包含芳族化合物(MTA)的烃的方法,所述方法包括以下步骤: - 使包含甲醇的反应器进料在双功能催化剂上反应,从而获得反应流出物 - - 将反应流出物分离成至少含水冷凝物流,液态烃流和气流, - 从气流获得第一循环流 - - 从气流获得第一侧流, - 通过第一侧 通过至少一个氢气(H 2)去除步骤,从而获得贫氢气流,以及 - 将第一循环物流和贫氢物流与包含甲醇的第一进料物流混合以获得反应器进料。

    FUEL FORMULATION
    7.
    发明申请
    FUEL FORMULATION 审中-公开
    燃油配方

    公开(公告)号:WO2017025612A1

    公开(公告)日:2017-02-16

    申请号:PCT/EP2016/069178

    申请日:2016-08-11

    摘要: A gasoline fuel formulation which contains 60% v/v or more of a combination of (a) a biologically-derived alcohol and (b) a mixture of C 4 to C 12 hydrocarbon fuel components, all of which hydrocarbon fuel components have been derived, whether directly or indirectly, from catalytic conversion of a biologically-derived oxygenate component, wherein the concentration of the alcohol (a) in the formulation is from 0.1 to 30% v/v.

    摘要翻译: 一种汽油燃料配方,其含有(a)生物衍生的醇和(b)C4至C12烃燃料组分的混合物的组合的60%v / v或更多的所有烃燃料组分的衍生物, 直接或间接地来自生物衍生的含氧化合物组分的催化转化,其中制剂中醇(a)的浓度为0.1-30%v / v。

    PROCESS FOR THE PRODUCTION OF BIODEGRADABLE HYDROCARBON FLUIDS
    9.
    发明申请
    PROCESS FOR THE PRODUCTION OF BIODEGRADABLE HYDROCARBON FLUIDS 审中-公开
    生物可降解碳氢化合物生产流程

    公开(公告)号:WO2016185046A1

    公开(公告)日:2016-11-24

    申请号:PCT/EP2016/061504

    申请日:2016-05-20

    IPC分类号: C10G3/00

    摘要: The invention provides for a process for preparing a fluid having a boiling point in the range of from 100 to 400°C and comprising more than 95% isoparaffins and containing less than 100ppm aromatic, comprising the step of catalytically hydrogenating a feed comprising more than 95% by weight of a hydrodeoxygenated isomerized hydrocarbon biomass feedstock, at a temperature from 80 to 180°C and at a pressure from 50 to 60 bars. The invention also provides for a fluid having a boiling point in the range of from 100 to 400°C and a boiling range below 80°C, said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight and having a ratio of iso-paraffins to n-paraffins of at least 12:1, a biodegradability at 28 days of at least 60%, as measured according to the OECD 306 standard, a biocarbon content of at least 95% by weight, containing less than 100ppm aromatics by weight, and comprising carbon expressed as CH 3 sat less than 30%.

    摘要翻译: 本发明提供了一种制备沸点在100-400℃范围内且包含大于95%异链烷烃并含有少于100ppm芳族化合物的流体的方法,其包括催化氢化包含大于95 重量%的加氢脱氧异构化烃生物质原料,温度为80至180℃,压力为50至60巴。 本发明还提供了沸点在100-400℃和沸点低于80℃的流体,所述流体包含大于95%的异链烷烃和小于3重量%的重氮,并具有 异链烷烃与正链烷烃的比例至少为12:1,28天时的生物降解性至少为60%,根据OECD 306标准测定,生物碳含量至少为95重量%,含有少于 100ppm芳族化合物,并且包含表示为CH3的少于30%的碳。