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1.发明授权CHELATE-CONTROLLED DIASTEREOSELECTIVE HYDROGENATION WITH HETEROGENEOUS CATALYST 有权非均相催化剂对螯合物进行选择性加氢反应
公开(公告)号：EP3134203B1
公开(公告)日：2018-04-04
申请号：EP15774672.8
申请日：2015-09-28
发明人： DUNN, David , SUTTON, Howard Winston Tyrrell , DALY, John Ing Chuan , GRANT, Simon Jonathon , HUTCHINGS, Lian , RIBIERE, Patrice Georges Antonin , GIBBINGS, Matthew Richard , GAMBOA MARTINEZ, Sergio Aaron , ANDERSON, Craig , ROGAN, Yulia
IPC分类号： B01J23/58 , C07D307/06 , C07D307/12
CPC分类号： C07D307/12 , B01J23/58
摘要： A hydrogenation catalyst, preferably palladium on a support, preferably alumina or activated charcoal support, is used in the presence of lithium salts, with salts such as the borates being preferred. This provides hydrogenation of precursors to give rise to a stereoselective, such as diastereoselective bias in the product of alkene hydrogenation using the catalyst.
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2.发明公开CHELATE-CONTROLLED DIASTEREOSELECTIVE HYDROGENATION WITH HETEROGENEOUS CATALYST 有权CHELATGESTEUERTE DIASTEREOSELEKTIVE HYDRIERUNG MIT异构体KATALYSATOR
公开(公告)号：EP3134203A1
公开(公告)日：2017-03-01
申请号：EP15774672.8
申请日：2015-09-28
发明人： DUNN, David , SUTTON, Howard Winston Tyrrell , DALY, John Ing Chuan , GRANT, Simon Jonathon , HUTCHINGS, Lian , RIBIERE, Patrice Georges Antonin , GIBBINGS, Matthew Richard , GAMBOA MARTINEZ, Sergio Aaron , ANDERSON, Craig , ROGAN, Yulia
IPC分类号： B01J23/58 , C07D307/06
CPC分类号： C07D307/12 , B01J23/58
摘要： A hydrogenation catalyst, preferably palladium on a support, preferably alumina or activated charcoal support, is used in the presence of lithium salts, with salts such as the borates being preferred. This provides hydrogenation of precursors to give rise to a stereoselective, such as diastereoselective bias in the product of alkene hydrogenation using the catalyst.
摘要翻译： 一种立体选择性氢化的方法，包括提供下式的底物：其中Cyc1表示不饱和部分为五或六元杂环，杂原子是O，S，N或P之一; R1代表氢或非手性有机化学基团; 催化剂组合物包含：在锂盐存在下在载体上的金属氢化催化剂。 底物可以是1,2-二（2-呋喃基）丙烷，并且可以以超过52％的内消旋异构体存在。 金属氢化催化剂是铂，钯，钌，铑或镍中的一种或多种。 载体选自碳，氧化铝，二氧化硅，二氧化钛，碳酸钙，铝酸锂和硫酸钡。 锂盐可以是四硼酸锂，偏硼酸锂或它们的水合物。
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公开(公告)号：EP1091920A1
公开(公告)日：2001-04-18
申请号：EP99928139.7
申请日：1999-06-30
发明人： POLIAKOFF, Martyn , MEEHAN, Nicola, Jane , ROSS, Stephen, Keith , WIELAND, Stefan , ROEDER, Stefan
CPC分类号： C07C45/50 , Y02P20/544 , C07C47/02
摘要： In a process for the hydroformylation of alkanes, alkenes or trialkylboranes under supercritical or near-critical conditions, hydroformylation is effected using a heterogeneous catalyst in a continuous flow reactor containing a supercritical or near-critical reaction medium. Selectivity of product formation may be achieved by independently varying one or more of the temperature, pressure, catalyst, mole ratios of hydrogen and carbon monoxide and flow rate.
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公开(公告)号：EP1050775A1
公开(公告)日：2000-11-08
申请号：EP00303355.2
申请日：2000-04-20
IPC分类号： G02F1/1334 , G02F1/29
CPC分类号： G02F1/292 , G02F1/1334 , G02F2203/06 , G02F2203/22 , G02F2203/50
摘要： A phase modulator includes a lower layer of glass or silicon substrate containing a 1-D array of pixels (42) formed from either ITO or aluminium respectively. The substrate is covered by an upper glass plate coated uniformly with ITO to make one large transparent electrode. Polymer-dispersed LC composite material is sandwiched between these layers, the polymer-dispersed material containing a nematic LC (with positive dielectric). Figure 4a shows the bipolar director configuration within the droplets (40) in the field-off condition where the bipolar axis of each droplet is assumed to be randomly oriented. Light impinging on this material may encounter small enough scattering centres to be suitable for Rayleigh scattering. An applied electric field exerts an electric torque on the directors. This is balanced by an elastic torque generated by the distortion of the director pattern away from its equilibrium position. The balance of these two forces determines an equilibrium position of the director and a rotation of the bipolar axis towards an orientation normal to the plane of the SLM. The device is thus able to provide an analogue modulation of the refractive index, and hence phase delay, encountered by incoming light. Figure 4b shows the final switch configuration in which voltages of different magnitudes have been applied to different pixels (42) to produce several different regions (44) of PDLC, with different switch states, and hence a phase pattern suitable to defract light into first order spot with high efficiency.
摘要翻译： 相位调制器包括分别由ITO或铝形成的包含1-D像素阵列（42）的玻璃或硅衬底的下层。 基板被用ITO均匀涂覆的上玻璃板覆盖以制造一个大的透明电极。 聚合物分散的LC复合材料夹在这些层之间，聚合物分散的材料含有向列型LC（具有正电介质）。 图4a示出了在每个液滴的双极轴被假定为随机取向的场关闭状态下液滴（40）内的双极导向器配置。 撞击这种材料的光可能会遇到足够小的散射中心，以适合瑞利散射。 施加的电场对董事施加电力矩。 这通过由导向器图案从其平衡位置的扭曲产生的弹性扭矩来平衡。 这两个力的平衡决定了导向器的平衡位置和双极轴线朝向垂直于SLM平面的方向的旋转。 因此，该装置能够提供由入射光遇到的折射率的模拟调制，并因此提供相位延迟。 图4b示出了其中不同幅度的电压已经被施加到不同像素（42）以产生PDLC的几个不同区域（44）的最终开关配置，具有不同的开关状态，因此适合于将光分解为一阶 现场高效率。
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公开(公告)号：EP0687749B1
公开(公告)日：1998-09-16
申请号：EP95303956.7
申请日：1995-06-08
CPC分类号： C23C16/45574 , C23C16/45514 , C23C16/45565 , C23C16/45572 , C30B25/14
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6.发明授权Bis(2,4-organylthio-s-triazin-6-yl)polysulfane, Verfahren zu ihrer Herstellung und sie enthaltende vulkanisierbare Kautschukmischungen 无效双（2,4-二organylthio -S-三嗪-6-基）它们的制备方法和含有它们的硫化的橡胶混合物的组合物polysulphanes过程。
公开(公告)号：EP0347524B1
公开(公告)日：1995-06-28
申请号：EP89104878.7
申请日：1989-03-18
发明人： Hellwig, Georg, Dr. , Stober, Reinhard, Dr. , Klatte, Christoph , Deschler, Ulrich, Dr. , Wolff, Siegfried, Dr. , Görl, Udo, Dr.
IPC分类号： C07D251/38 , C08K5/37
CPC分类号： C08K5/378 , C07D251/38 , C08L21/00
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公开(公告)号：EP1850100A2
公开(公告)日：2007-10-31
申请号：EP07015552.8
申请日：2004-12-09
发明人： Holmes, Melanie
摘要： Apparatus and methods are described for calibrating an optical system having a Spatial Light Modulator, SLM, the method comprising a comparison of: a phase and/or amplitude distribution of at least one beam incident on the SLM, this phase and/or amplitude distribution measured by means of phase modulating elements on the SLM; with at least one known feature of the beam.
摘要翻译： 描述了用于校准具有空间光调制器SLM的光学系统的装置和方法，该方法包括以下比较：入射到SLM上的至少一个光束的相位和/或幅度分布，测量该相位和/或幅度分布 通过SLM上的相位调制元件; 具有梁的至少一个已知特征。
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公开(公告)号：EP1221068A2
公开(公告)日：2002-07-10
申请号：EP00964505.2
申请日：2000-10-04
发明人： WARR, Steven , TAN, Kim, Leong , CROSSLAND, William , MANOLIS, Ilias , REDMOND, Maura , WILKINSON, Timothy , HOLMES, Melanie,The Forge , ROBERTSON, Brian,c/o Raymond Robertson
IPC分类号： G02F1/31
CPC分类号： G03H1/08 , G02B5/32 , G02B6/264 , G02B6/32 , G02F1/136277 , G02F1/1393 , G02F1/1395 , G02F1/141 , G02F1/31 , G02F2001/133638 , G02F2203/02 , G02F2203/12 , G02F2203/50 , G03H1/0005 , G03H1/02 , G03H1/2294 , G03H2001/0224 , G03H2001/0825 , G03H2001/085 , G03H2001/221 , G03H2001/261 , G03H2001/306 , G03H2210/20 , G03H2222/31 , G03H2222/32 , G03H2222/34 , G03H2223/19 , G03H2223/20 , G03H2225/22 , G03H2225/32 , G03H2225/52 , G03H2227/03 , G03H2240/41 , H04Q2213/1301 , H04Q2213/1319
摘要： An optical switch uses two ferroelectric liquid crystal spatial light modulators (10, 11) with an interconnect region in between. The switch uses bulk lenses (2, 8) to focus light from an input fibre array (1) to a first spatial light modulator (10), and from the second spatial light modulator (11) to an output array (9). Each spatial light modulator displays a respective hologram selected from a previously calculated set, to cause a desired switching of light from the input fibre array to the output array.
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10.发明公开
公开(公告)号：EP0258676A3
公开(公告)日：1989-05-10
申请号：EP87111430.2
申请日：1987-08-07
发明人： Deschler, Ulrich, Dr. , Hellwig, Georg, Dr. , Michel, Rudolf , Kleinschmit, Peter, Dr. , Wolff, Siegfried
IPC分类号： C07D251/52 , C08K5/37
CPC分类号： C07D251/52 , C08K5/378 , C08L21/00
摘要： Die Erfindung betrifft Mischungen schwefelhaltiger Triazinverbindungen und Verfahren zur Herstellung dieser Verbindungen mit der allgemeinen Formel
in welcher bedeuten:
R1 , R 2 = H, R 2 = Benzyl, R 2 , R 3 , R 4 = C 1 -C 8 -Alkyl, Allyl, C 3 -C 8 Cycloalkyl, letzteres unsubstituiert oder mit 1-3 Methylgruppen substituiert, 2-Hydroxiethyl, 3-Hydroxipropyl, 2-Hydroxipropyl oder R 3 und R 4 (zusammen): C 4 -C 6 -Alkylen,-(CH 2 -CHX) 2 Y mit X = H, CH 3 , Y = O,S, S a : Polysulfankette mit 2-10 S-Atomen (d.h. 2 ≦ a ≦ 10), wobei die einzelnen Polysulfane in solchen Konzentrationen vorliegen, daß das statistische Mittel a ganze oder gebrochene Zahlenwerte von 2 bis 5 annimmt, dadurch gekennzeichnet, daß man eine Triazinverbindung der allgemeinen Formel
mit einer in einem protischen, polaren, Lösungsmittel, insbesondere Wasser, gelösten Ammonium-oder Alkalipolysulfid bei einer Temperatur von 80 bis 140°C umsetzt.
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