摘要:
Provided is a formed body containing at least one carbonate compound (A1) selected from Na 2 CO 3 or K 2 CO 3 , the formed body having a volume of pores with a pore diameter of from 0.05 µm to 10 µm of from 0.10 mL/g to 0.30 mL/g and a crushing strength of from 1.8 kgf to 10.0 kgf.
摘要翻译:选自Na 2 CO 3或K 2 CO 3中选出的成形体含有至少一种碳酸酯化合物(A1)提供,具有孔的从0点05微米的孔直径从0时10分mL的体积至10微米的成形体/ g至0:30毫升/克和1.8千克力至10.0公斤力的抗碎强度。
摘要:
A method for highly selectively producing a compound with a double bond represented by the following formula (III), the method comprising the following steps (A), (B), and (C): step (A): a step of reacting a compound represented by the following formula (I) and/or a compound represented by the following formula (II) with hydrogen in the presence of 0.1 parts by weight or more of a hydrogenation catalyst, thereby obtaining a reaction liquid, step (B): a step of removing the hydrogenation catalyst until the amount of the hydrogenation catalyst contained in the reaction liquid obtained in step (A) becomes 0.0010 parts by weight or less, thereby obtaining a hydrogenation catalyst-removed liquid, step (C): a step of obtaining a compound with a double bond represented by the following formula (III) in the presence of a dehydration catalyst from the hydrogenation catalyst-removed liquid obtained in step (B),
wherein R 1 represents a hydrocarbon group,
wherein R 2 represents a hydrocarbon group containing an aromatic ring,
R 3 -CH=CH 2 (III)
wherein R 3 represents an alkyl group, or the like.
摘要:
L'invention concerne un procédé catalytique de dimérisation ou de codimérisation ou d'oligomérisation notamment sélectives d'oléfines, effectué sous pression, dans une zone de réaction (1) renfermant un lit de catalyseur solide dans lequel est plongée une pluralité d'espaces internes creux (6.3a) délimités par des parois, chacun étant divisé en un demi-espace supérieur (6.3,1a) et en un demi-espace inférieur (6.3,2a) qui communiquent entre eux par une zone relieuse (6.6a) . Un fluide autogène de thermorégulation circule, sous la forme d'une nappe, dans lesdits espaces internes creux (6.3a) après avoir traversé une zone de distribution centrale (6.1a) et des zones distributives (6.2a) et avant de passer dans des zones collectrices (6.4a) et dans une zone de collecte centrale (6.5a). Le procédé selon l'invention s'applique notamment à la dimérisation sélective du propylène en méthyl-4 pentène-1.
摘要:
A process for catalytic cracking, isomerizing of reforming of a hydrocarbon feed stock comprises the step of passing said hydrocarbon feed stock through a catalyst bed at cracking, isomerizing or reforming conditions to crack, isomerize or reform said hydrocarbon feed stock, wherein the catalyst composition in the catalyst bed, comprises a pillared fluorotetrasilicic mica, wherein said pillared fluorotetrasilicic mica has a specific surface area exceeding 75 m²/gm, wherein the mica is pillared by alumina, zirconia or chromia, and the aluminum, zirconium or chromium content is at least 8% by weight. In the catalytic cracking process, there is less carbon and hydrogen formed than in comparative processes, and the cracked product contains a relatively high proportion of C₃ and C₄ olefins.
摘要:
Catalyst supports, catalyst systems, methods for the preparation thereof, and dimerization process therewith are provided catalyst supports are extruded from a thick paste of potassium carbonate and water catalyst systems comprise at least one elemental alkali metal deposited on the catalyst support. Optionally, the catalyst system further comprises at least one promoter.
摘要:
A process for catalytic cracking, isomerizing of reforming of a hydrocarbon feed stock comprises the step of passing said hydrocarbon feed stock through a catalyst bed at cracking, isomerizing or reforming conditions to crack, isomerize or reform said hydrocarbon feed stock, wherein the catalyst composition in the catalyst bed, comprises a pillared fluorotetrasilicic mica, wherein said pillared fluorotetrasilicic mica has a specific surface area exceeding 75 m²/gm, wherein the mica is pillared by alumina, zirconia or chromia, and the aluminum, zirconium or chromium content is at least 8% by weight. In the catalytic cracking process, there is less carbon and hydrogen formed than in comparative processes, and the cracked product contains a relatively high proportion of C₃ and C₄ olefins.
摘要:
4-methyl-1-pentene is produced via the catalyst dimerization of propylene. Using a catalyst comprising at least one element selected from uranium and the rare earth metals. The selectivity to 4-methyl-1-pentene usually is at least 94 mole percent. The preferred catalysts are uranium and rare earth di(poly-substituted cyclopentadienyl) hydride complexes especially uranium (pentahaptopenta methyl cyclopentadienyl) hydride complexes.
摘要:
A process for preparing 4-methyl-1-pentene comprising dimerizing propylene in the presence of a catalyst, characterized in that the catalyst is composed from the treatment of precatalyst by at least one oxygen-containing compound selected from oxygen, alcohols, ethers, acetals, orthocarboxylates and esters. The precatalyst is composed of element or compound selected from sodium, potassium, sodium amide and potassium amide supported on a carrier principally represented by the following formula (1): wherein x has a value in the range of 0.5≦ The use of above mentioned catalyst so remarkably increases the rate of reaction and the selectivity of 4-methyl-1-pentene and allows the reaction rate and selectivity to be kept high for a long period of time.