Copolymers of atactic propene polymers, dispersants derived therefrom and lubricating oils and fuel compositions containing the dispersants
    151.
    发明公开
    Copolymers of atactic propene polymers, dispersants derived therefrom and lubricating oils and fuel compositions containing the dispersants 失效
    无规丙烯聚合物的共聚物,由其衍生的分散剂和润滑油以及含有该分散剂的燃料组合物

    公开(公告)号:EP0767182A3

    公开(公告)日:1997-07-16

    申请号:EP96307242.6

    申请日:1996-10-03

    申请人: ETHYL CORPORATION

    IPC分类号: C08F8/00 C08F8/46

    摘要: A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C 2 and C 4 to C 10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C 4 to C 10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer. The novel dispersants made from the copolymers and terpolymers of the invention can be polymeric succinic ester-amide dispersants, polymeric succinimide dispersants, polymeric succinic amide-triazole dispersants, or polymeric succinic triazole dispersants. Fuel and lubricant compositions containing such additives are a part of the invention.

    摘要翻译: 教导了不饱和酸性反应物和无规立构乙烯基封端的丙烯聚合物(VTPP)的新型共聚物及其在制备燃料和润滑剂添加剂中的用途。 VTPP具有主要量的含末端乙烯基不饱和度的聚合物链,数均分子量至少为500,并且包含至少70重量%丙烯和0-30重量%至少一种选自以下的烯烃: 的C2和C4至C10烯烃。 不饱和酸性反应物包含至少一种不饱和的C 4 -C 10羧酸或二羧酸或酸酐。 适用于油质组合物的本发明的油溶性分散剂添加剂通过使无规立构VTPP共聚物与至少一种选自胺,醇,金属反应物及其混合物的亲核试剂在有效形成亲核性加合物 试剂与共聚物。 由本发明共聚物和三元共聚物制成的新型分散剂可以是聚合琥珀酸酯 - 酰胺分散剂,聚合琥珀酰亚胺分散剂,聚合琥珀酰胺 - 三唑分散剂或聚合琥珀酸三唑分散剂。 含有这些添加剂的燃料和润滑剂组合物是本发明的一部分。

    Reducing exhaust emissions from Otto-cycle engines
    157.
    发明公开
    Reducing exhaust emissions from Otto-cycle engines 失效
    减少奥托循环发动机的废气排放

    公开(公告)号:EP0667387A3

    公开(公告)日:1995-09-27

    申请号:EP95101782.1

    申请日:1995-02-09

    申请人: ETHYL CORPORATION

    IPC分类号: C10L1/30 C10L10/02 C10L10/00

    摘要: The amount of nitrogen oxide (NOx) and hydrocarbon emissions emanating via the exhaust during operation of a gasoline engine is reduced by dispensing to a gasoline engine adjusted to operate primarily at an air-to-fuel ratio between lambda of about 0.9 to about 1.15, a gasoline that contains a minor amount of (i) a cyclopentadienyl manganese tricarbonyl compound and (ii) an alkyllead antiknock agent. Components (i) and (ii) are proportioned such that there is dissolved in the fuel a substantially equal weight of manganese as (i) and lead as (ii), and the amount of (i) and (ii) used in the fuel is an amount that reduces the amount of NOx and hydrocarbons in the engine exhaust on combustion of the fuel with an air-to-fuel ratio between lambda of about 0.9 to about 1.15. Lambda is the actual air-to-fuel ratio divided by the stoichiometric air-to-fuel ratio. The stoichiometric air-to-fuel ratio is a lambda value of one.

    摘要翻译: 通过向汽油发动机分配来减少在汽油发动机运行期间通过排气排出的氮氧化物(NOx)和碳氢化合物排放物的量,所述汽油发动机被调节成主要在λ约为0.9至约1.15之间的空气/燃料比下操作, 含有少量(i)环戊二烯基三羰基锰化合物和(ii)烷基铅抗爆剂的汽油。 将组分(i)和(ii)按比例分配,使得在燃料中溶解与(i)和(ii)的基本相同重量的锰,以及在燃料中使用的(i)和(ii)的量 是在燃料燃烧时减少发动机排气中的NOx和碳氢化合物的量的量,其中空气 - 燃料比在约0.9至约1.15的λ之间。 Lambda是实际的空燃比除以化学计量的空燃比。 化学计量的空燃比是1的λ值。

    SILICON COMPOUNDS IN BONE TREATMENT
    159.
    发明授权
    SILICON COMPOUNDS IN BONE TREATMENT 失效
    硅化合物骨的治疗。

    公开(公告)号:EP0425565B1

    公开(公告)日:1994-09-21

    申请号:EP89908653.2

    申请日:1989-07-19

    申请人: ETHYL CORPORATION

    IPC分类号: A61K31/695 A61K31/70

    摘要: Organic silicon compounds such as tetraloweralkylorthosilicates, silicon tetracarboxylates, and silicon-containing reaction products derived from carbohydrates, such as glucose, sucrose, and ascorbic acid are useful in treating, preventing, or delaying the onset of bone disease in warm blooded vertebrates, including man and domesticated animals of economic importance, such as poultry, house pets, and horses, cattle, swine, and sheep.

    RESOLUTION OF KETOPROFEN
    160.
    发明公开
    RESOLUTION OF KETOPROFEN 失效
    酮洛芬的分离。

    公开(公告)号:EP0613456A1

    公开(公告)日:1994-09-07

    申请号:EP92920678.0

    申请日:1992-09-21

    申请人: ETHYL CORPORATION

    IPC分类号: C07C51 C07B57 C07C59

    摘要: Procédé permettant de dissoudre de l'acide (U)-alpha-(-benzoylphényle)propionique qui consiste: i) à convertir ledit acide propionique à l'aide de (-)-cinchonidine en un solvant comprenant un mélange d'ester aliphatique et un alcool d'alkyle; ii) à séparer le sel diastéréomère du produit de conversion; iii) à purifier ledit sel diastéréomère séparé par une recristallisation unique; et (iv) à isoler l'acide (+)-alpha-(3-benzoylphényle)propionique sans aucune nouvelle recristallisation.