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    PREPARING CYCLOCARBONATE-FUNCTIONALIZED COMPOUNDS
    13.
    发明公开
    PREPARING CYCLOCARBONATE-FUNCTIONALIZED COMPOUNDS 有权
    制备环碳酸酯官能化合物

    公开(公告)号：EP2797908A1

    公开(公告)日：2014-11-05

    申请号：EP12791501.5

    申请日：2012-11-29

    Applicant: BASF SE

    Inventor： MEZGER, Jochen ,  WALTHER, Burkhard ,  MECFEL-MARCZEWSKI, Joanna ,  KLOPSCH, Rainer

    IPC: C07D317/38 ,  C07D407/14

    CPC classification number: C07D307/20 ,  C07D307/33 ,  C07D317/38 ,  C07D317/40 ,  C07D407/14

    Abstract: An improved process is proposed for preparing cyclocarbonate-functionalized compounds of the general formula (I) where R
    1 and R
    2 in each occurrence are independently selected from hydrogen, methyl and ethyl, I in each occurrence independently is from 2 to 50, m in each occurrence independently is 0 or 1, and n is = 3, subject to the proviso that the sum of all I values in the molecule is from 5 to 100, by reacting a chloroformate of formula (II) with a trifunctional amine of the general formula (III) characterized in that the reacting is carried out in an aqueous/organic two-phase system in the presence of an auxiliary base and of a phase transfer catalyst.

    Abstract translation: 提出了用于制备通式（I）的环碳酸酯官能化的化合物的改进方法，其中R 1和R 2在每次出现时独立地选自氢，甲基和乙基，I在每次出现时独立地为2至50，m in 通过使式（II）的氯甲酸酯与一般的三官能胺反应，各自独立地为0或1，并且n为= 3，条件是分子中所有I值的总和为5至100 式（III）的特征在于反应在含水/有机两相体系中在辅助碱和相转移催化剂存在下进行。

    HÄRTUNG VON EPOXIDHARZ-ZUSAMMENSETZUNGEN, WELCHE CYCLISCHE CARBONATE ENTHALTEN, MIT GEMISCHEN VON AMINOHÄRTERN
    20.
    发明公开
    HÄRTUNG VON EPOXIDHARZ-ZUSAMMENSETZUNGEN, WELCHE CYCLISCHE CARBONATE ENTHALTEN, MIT GEMISCHEN VON AMINOHÄRTERN 审中-公开
    固化环氧组合物，其环状碳酸酯混合体AMINOHÄRTERN含

    公开(公告)号：EP2758470A1

    公开(公告)日：2014-07-30

    申请号：EP12756475.5

    申请日：2012-09-10

    Applicant: BASF SE

    Inventor： KLOPSCH, Rainer ,  YU, Miran

    IPC: C08L63/00 ,  C08G59/00 ,  C08K5/156

    CPC classification number: C08G59/50 ,  C08K5/109 ,  C08K5/1565 ,  C09D163/00 ,  C09J163/00 ,  C08L63/00

    Abstract: A process for curing epoxy resins which comprises curing epoxy resin compositions comprising a) epoxy resins and b) a compound of the general formula I in which R
    1 and R
    2 independently of one another are hydrogen, C
    1 -C
    6 -alkyl, C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkyl, C
    5 -C
    6 -cycloalkyl, phenyl, phenyl-C
    1 -C
    4 -alkyl, C
    2 -C
    6 -alkenyl or C
    2 -C
    6 -alkynyl, or R
    1 and R
    2 together are a C
    3 -C
    11 -alkylene group; R
    3 and R
    4 independently of one another are hydrogen, C
    1 -C
    6 -alkyl, C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkyl, C
    5 -C
    6 -cycloalkyl, phenyl, phenyl-C
    1 -C
    4 -alkyl, C
    2 -C
    6 -alkenyl or C
    2 -C
    6 -alkynyl, or R
    3 and R
    4 together are a C
    4 -C
    6 -alkylene group; by adding amino hardeners, 0.1% to 50% by weight of the amino hardeners being aliphatic, cycloaliphatic or aromatic amine compounds having 1 to 4 primary amino groups and optionally further functional groups, selected from secondary amino groups, tertiary amino groups, and hydroxyl groups, the primary amino groups in the case of the cycloaliphatic and aromatic amine compounds being attached as aminomethylene groups (H
    2 N-CH
    2 -) to the cycloaliphatic or aromatic ring system (referred to below for short as co-hardeners).

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