VERBESSERTES VERFAHREN ZUR HERSTELLUNG VON NICKEL(0)-PHOSPHORLIGAND-KOMPLEXEN
    11.
    发明授权
    VERBESSERTES VERFAHREN ZUR HERSTELLUNG VON NICKEL(0)-PHOSPHORLIGAND-KOMPLEXEN 有权
    用于生产镍改进方法(0) - 磷络合物

    公开(公告)号:EP1988998B1

    公开(公告)日:2011-06-15

    申请号:EP07704548.2

    申请日:2007-02-13

    Applicant: BASF SE

    CPC classification number: B01J31/1845 B01J31/24 B01J2231/32 B01J2531/847

    Abstract: Process for producing nickel(0)-phosphorus ligand complexes containing at least one nickel(0) central atom and at least one phosphorus-containing ligand, by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, characterized in that, a) in the reaction the molar ratio of reducing agent:nickel(II) compound is 1:1 to 1000:1, calculated as molar ratio of redox equivalents, b) in the reaction the molar ratio of phosphorus-containing ligand:nickel(II) compound is at most 30:1, calculated as molar ratio of P atoms:Ni atoms, c) in the resultant reaction mixture the nickel(0) content is at most 1.3% by weight, and d) the resultant reaction mixture is extracted by adding at least one dinitrile and at least one hydrocarbon, at least two immiscible phases forming.

    VERFAHREN ZUR AUFARBEITUNG EINES BUTEN- UND/ODER BUTADIEN ENTHALTENDEN STOFFSTROMS
    13.
    发明公开
    VERFAHREN ZUR AUFARBEITUNG EINES BUTEN- UND/ODER BUTADIEN ENTHALTENDEN STOFFSTROMS 有权
    VERFAHREN ZUR AUFARBEITUNG EINES BUTEN - UND / ODER BUTADIEN ENTHALTENDEN STOFFSTROMS

    公开(公告)号:EP2681178A1

    公开(公告)日:2014-01-08

    申请号:EP12706605.8

    申请日:2012-03-02

    Applicant: BASF SE

    CPC classification number: B01D3/40 C07C7/04 C07C7/08 C07C7/11 C07C11/16 C07C11/167

    Abstract: The invention relates to a process for workup of a stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen and carbon dioxide, comprising the following steps: (a) absorption of the stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen, with or without carbon dioxide, with a mixture (5) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to obtain a stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, and a stream (7) comprising hydrogen and/or nitrogen and butane, (b) extractive distillation of the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, with a stream (13) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to separate the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, into a stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene, and a stream (15) comprising essentially butane, with or without carbon dioxide, (c) distillation of the stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene into a stream (23) comprising essentially N-methylpyrrolidone and water, and a stream (21) comprising butene and/or butadiene.

    Abstract translation: 本发明涉及包含丁烯和/或丁二烯,丁烷,氢气和/或氮气和二氧化碳的物流(1)的处理方法,其包括以下步骤:(a)将包含丁烯和 (5)包含80-97重量%的N-甲基吡咯烷酮和3-20重量%的水以获得流(9),所述混合物(5)包含具有或不具有二氧化碳的丁二烯,丁烷,氢和/ )包含N-甲基吡咯烷酮,水,丁烯和/或丁二烯和丁烷(含有或不含二氧化碳)以及包含氢和/或氮和丁烷的物流(7),(b)物流(9)的萃取蒸馏包含 (13)包含80-97重量%的N-甲基吡咯烷酮和3-20重量%的水以分离含有或不含二氧化碳的N-甲基吡咯烷酮,水,丁烯和/或丁二烯和丁烷, 包含N-甲基吡咯烷酮,水,丁烯和/或丁二烯和丁烷的物流(9),有或没有汽车 (17),包含N-甲基吡咯烷酮,水,丁烯和/或丁二烯,以及基本上包含丁烷的物流(15),其中含有或不含有二氧化碳,(c)蒸馏包含N (23)和包含丁烯和/或丁二烯的物流(21),所述物流(23)基本上包含N-甲基吡咯烷酮和水。

    VERFAHREN ZUR PHOTOKATALYTISCHEN WASSERREINIGUNG
    15.
    发明公开
    VERFAHREN ZUR PHOTOKATALYTISCHEN WASSERREINIGUNG 审中-公开
    法光催化水处理

    公开(公告)号:EP2445840A1

    公开(公告)日:2012-05-02

    申请号:EP10730128.5

    申请日:2010-06-23

    Applicant: BASF SE

    Abstract: The present invention relates to a method for purifying a contaminant-laden current by bringing the current to be purified in contact with a heterogeneous photocatalyst and irradiating it with light, wherein it is brought into contact in the presence of at least one compound, which is dissolved in the current and contains at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese, and mixtures thereof, and to the use of a heterogeneous photocatalyst for purifying a contaminant-laden current, wherein at least one compound containing at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese, and mixtures thereof, is present in dissolved form in the current to be purified.

    METHYL-SUBSTITUIERTE TETA-VERBINDUNGEN
    16.
    发明公开
    METHYL-SUBSTITUIERTE TETA-VERBINDUNGEN 有权
    甲基 - SUBSTITUIERTE TETA-VERBINDUNGEN

    公开(公告)号:EP2443088A1

    公开(公告)日:2012-04-25

    申请号:EP10725162.1

    申请日:2010-06-14

    Applicant: BASF SE

    CPC classification number: C07D207/327 C07C211/14

    Abstract: The invention relates to a method for producing triethylenetetramine that is substituted with at least one methyl group (Me-TETA or methyl-substituted TETA compounds). Me-TETA is produced by hydrogenating biscyanomethyl imidazolidine (BCMI) in the presence of a catalyst. The present invention further relates to methyl-substituted TETA compounds as such. The present invention further relates to the use of methyl-substituted TETA compounds as an educt or intermediate product in the production of, for example, coatings or adhesives.

    Abstract translation: 本发明涉及用至少一个甲基取代的三亚乙基四胺(Me-TETA或甲基取代的TETA化合物)的制备方法。 Me-TETA是通过在催化剂存在下氢化双氰甲基咪唑烷(BCMI)而生产的。 本发明进一步涉及甲基取代的TETA化合物本身。 本发明进一步涉及甲基取代的TETA化合物在生产例如涂料或粘合剂中作为离析物或中间产物的用途。

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