VERFAHREN ZUR AUFARBEITUNG EINES BUTEN- UND/ODER BUTADIEN ENTHALTENDEN STOFFSTROMS
    4.
    发明公开
    VERFAHREN ZUR AUFARBEITUNG EINES BUTEN- UND/ODER BUTADIEN ENTHALTENDEN STOFFSTROMS 有权
    VERFAHREN ZUR AUFARBEITUNG EINES BUTEN - UND / ODER BUTADIEN ENTHALTENDEN STOFFSTROMS

    公开(公告)号:EP2681178A1

    公开(公告)日:2014-01-08

    申请号:EP12706605.8

    申请日:2012-03-02

    申请人: BASF SE

    摘要: The invention relates to a process for workup of a stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen and carbon dioxide, comprising the following steps: (a) absorption of the stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen, with or without carbon dioxide, with a mixture (5) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to obtain a stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, and a stream (7) comprising hydrogen and/or nitrogen and butane, (b) extractive distillation of the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, with a stream (13) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to separate the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, into a stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene, and a stream (15) comprising essentially butane, with or without carbon dioxide, (c) distillation of the stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene into a stream (23) comprising essentially N-methylpyrrolidone and water, and a stream (21) comprising butene and/or butadiene.

    摘要翻译: 本发明涉及包含丁烯和/或丁二烯,丁烷,氢气和/或氮气和二氧化碳的物流(1)的处理方法,其包括以下步骤:(a)将包含丁烯和 (5)包含80-97重量%的N-甲基吡咯烷酮和3-20重量%的水以获得流(9),所述混合物(5)包含具有或不具有二氧化碳的丁二烯,丁烷,氢和/ )包含N-甲基吡咯烷酮,水,丁烯和/或丁二烯和丁烷(含有或不含二氧化碳)以及包含氢和/或氮和丁烷的物流(7),(b)物流(9)的萃取蒸馏包含 (13)包含80-97重量%的N-甲基吡咯烷酮和3-20重量%的水以分离含有或不含二氧化碳的N-甲基吡咯烷酮,水,丁烯和/或丁二烯和丁烷, 包含N-甲基吡咯烷酮,水,丁烯和/或丁二烯和丁烷的物流(9),有或没有汽车 (17),包含N-甲基吡咯烷酮,水,丁烯和/或丁二烯,以及基本上包含丁烷的物流(15),其中含有或不含有二氧化碳,(c)蒸馏包含N (23)和包含丁烯和/或丁二烯的物流(21),所述物流(23)基本上包含N-甲基吡咯烷酮和水。

    VERFAHREN ZUR AUFTRENNUNG EINES GEMISCHES VON KOHLENWASSERSTOFFEN DURCH EXTRAKTIVDESTILLATION

    公开(公告)号:EP2903955A2

    公开(公告)日:2015-08-12

    申请号:EP13767004.8

    申请日:2013-09-30

    申请人: BASF SE

    IPC分类号: C07C7/08

    摘要: The invention relates to a continuous method for separation of a mixture of hydrocarbons by extractive distillation having a mixture of a polar aprotic solvent and water as a selective solvent, in a system comprising an extractive distillation column and an outgas column, characterized in that the method is carried out under continuous measurement of the water content of the selective solvent via NIR spectroscopy, wherein the measured values from the continuous measurement of the water content of the selective solvent are compared to a specified target value and regulated to a value within a specified concentration range above and below the target value by addition or exfiltration of water or by addition of polar aprotic solvent.

    摘要翻译: 本发明涉及一种通过萃取蒸馏分离烃混合物的连续方法,所述萃取蒸馏具有极性非质子传递溶剂和水作为选择性溶剂的混合物,在包含萃取蒸馏塔和排气塔的系统中,其特征在于所述方法 通过NIR光谱在连续测量选择性溶剂的水含量下进行,其中将来自选择性溶剂的水含量的连续测量的测量值与指定的目标值进行比较并调节至指定浓度内的值 通过加入或渗透水或通过加入极性非质子溶剂,在目标值之上和之下。