公开(公告)号：EP3371158A1

公开(公告)日：2018-09-12

申请号：EP16791378.9

申请日：2016-11-03

Applicant: BASF SE

Inventor： GORDILLO, Alvaro ,  BOHN, Martin Alexander ,  SCHUNK, Stephan A. ,  JEVTOVIKJ, Ivana ,  WERHAN, Holger ,  DÜFERT, Svenia ,  PIEPENBRINK, Markus ,  BACKES, René ,  DEHN, Richard

IPC: C07D307/46

CPC classification number: C07D307/50 ,  C07D307/46

Abstract: Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：EP3209416A1

公开(公告)日：2017-08-30

申请号：EP15785090.0

申请日：2015-10-23

Applicant: BASF SE

Inventor： KÖNIG, René ,  KOBAN, Wieland ,  MILANOV, Andrian ,  SCHWAB, Ekkehard ,  SCHUNK, Stephan A. ,  LIZANDARA, Carlos ,  WASSERSCHAFF, Guido

IPC: B01J23/78 ,  B01J23/83 ,  C01F7/02 ,  C01F17/00 ,  C01B3/40

CPC classification number: B01J23/83 ,  B01J23/002 ,  B01J23/78 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/04 ,  B01J37/086 ,  B01J37/088 ,  B01J37/349 ,  B01J2523/00 ,  C01B3/02 ,  C01B3/40 ,  C01B2203/0238 ,  C01F7/02 ,  C01F7/16 ,  C01F17/0025 ,  C01G51/006 ,  C01G51/70 ,  C01P2002/60 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  Y02P20/142 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/845

Abstract: The invention relates to a method for producing aluminates of general formula (I): A
1 B
x Al
12-x O
19-y , wherein A means at least one element from the group consisting of Sr, Ba, and La, B means at least one element from the group consisting of Mn, Fe Co, Ni, Rh, Cu, and Zn, x means 0.05 to 1.0, and y means a value that is determined by the oxidation states of the other elements, comprising the following steps: (i) providing one or more solutions or suspensions containing precursor compounds of elements A and B and a precursor compound of aluminum in a solvent, (ii) converting the solutions or suspensions or the suspensions into an aerosol, (iii) introducing the aerosol into a directly or indirectly heated pyrolysis zone, (iv) performing the pyrolysis, and (v) separating the formed particles containing hexaaluminate of general formula (I) from the pyrolysis gas.

Abstract translation: 本发明涉及通式（I）的铝酸盐的制备方法：其中A表示选自Sr，Ba和La中的至少一种元素，B表示选自以下的至少一种元素：AlBxAl12-xO19- 由Mn，Fe，Co，Ni，Rh，Cu和Zn组成，x表示0.05至1.0，y表示由其它元素的氧化态确定的值，包括以下步骤：（i） （ii）将溶液或悬浮液或悬浮液转化成气溶胶，（iii）将气溶胶引入直接或间接加热的热解中 （iv）进行热解，和（v）从热解气体中分离含有通式（I）的六铝酸盐的所形成的颗粒。

公开(公告)号：EP3142995A1

公开(公告)日：2017-03-22

申请号：EP15721272.1

申请日：2015-05-13

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  LEJKOWSKI, Michael ,  HUGUET SUBIELA, Nuria ,  GORDILLO, Alvaro ,  LINDNER, Ronald ,  BRU ROIG, Miriam ,  SCHUNK, Stephan A.

IPC: C07C51/15 ,  C07C57/05

CPC classification number: C07C51/15 ,  C07C57/04

Abstract: Catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, wherein an alkene and carbon dioxide are reacted in the presence of a carboxylation catalyst and in the presence of a specific aryloxide to obtain the α,β-ethylenically unsaturated carboxylic acid salt, the carboxylation catalyst being a transition metal complex. The process allows for efficient preparation of α,β-ethylenically unsaturated carboxylic acid derivatives from CO2 and an alkene.

Abstract translation: 用于制备α，β-烯键式不饱和羧酸盐的催化方法，其中烯烃和二氧化碳在羧化催化剂存在下和在特定芳氧化物存在下反应，得到α，β-烯属不饱和羧酸盐 羧化催化剂是过渡金属络合物。 该方法允许从CO 2和烯烃有效制备α，β-烯键式不饱和羧酸衍生物。

公开(公告)号：EP3142992A1

公开(公告)日：2017-03-22

申请号：EP15722197.9

申请日：2015-05-13

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  JEVTOVIKJ, Ivana ,  HUGUET SUBIELA, Nuria ,  GORDILLO, Alvaro ,  STIEBER, Sabine Chantal Eileen ,  LINDNER, Ronald ,  BRU ROIG, Miriam ,  LEJKOWSKI, Michael ,  KAGEYAMA, Takeharu ,  SCHUNK, Stephan A.

IPC: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

CPC classification number: C07C51/15 ,  B01J31/2409 ,  B01J31/2433 ,  B01J31/2452 ,  B01J31/2476 ,  B01J2231/32 ,  B01J2531/824 ,  B01J2531/847 ,  C07C57/04

Abstract: Catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising reacting an alkene and carbon dioxide in the presence of a carboxylation catalyst and releasing the α,β-ethylenically unsaturated carboxylic acid salt with a base, the carboxylation catalyst being a transition metal complex, which comprises a structurally constrained bidentate P,X ligand, wherein X is selected from the group consisting of P, N, O, and carbene, the P and X atom are separated by 2 to 4 bridging atoms, and wherein the bridging atoms are part of at least one 5- to 7-membered cyclic substructure. A further catalytic processes for preparing α-βethylenically unsaturated carboxylic acid derivatives from CO2 and an alkene is provided.

Abstract translation: 用于制备α，β-烯键式不饱和羧酸盐的催化方法，包括在羧化催化剂存在下使烯烃和二氧化碳反应并与碱释放α，β-烯属不饱和羧酸盐，羧化催化剂为 过渡金属络合物，其包含结构受限的二齿P，X配体，其中X选自P，N，O和卡宾，P和X原子被2至4个桥连原子分开，并且其中 桥连原子是至少一个5-至7-元环结构的一部分。 提供了从CO 2和烯烃制备α，β-烯键式不饱和羧酸衍生物的另外的催化方法。

公开(公告)号：EP3325457B1

公开(公告)日：2020-01-01

申请号：EP16733103.2

申请日：2016-07-01

Applicant: BASF SE

Inventor： GORDILLO, Alvaro ,  WERHAN, Holger ,  DEHN, Richard ,  BLANK, Benoit ,  TELES, Joaquim Henrique ,  SCHUNK, Stephan A. ,  PIEPENBRINK, Markus ,  BACKES, René ,  ZHANG, Lei

IPC: C07D307/46

公开(公告)号：EP3568387A1

公开(公告)日：2019-11-20

申请号：EP17804580.3

申请日：2017-11-29

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  GORDILLO, Alvaro ,  SCHROETER, Marie Katrin ,  MELDER, Johann-Peter ,  BECHTEL, Juergen ,  HEIDEMANN, Thomas ,  SCHUNK, Stephan A. ,  MÜLLER, Ulrich

IPC: C07C209/16 ,  C07C211/14 ,  C07C211/10

公开(公告)号：EP3528944A1

公开(公告)日：2019-08-28

申请号：EP17784315.8

申请日：2017-10-19

Applicant: BASF SE ,  The Regents of the University of California

Inventor： LEIDINGER, Peter ,  TITLBACH, Sven ,  HAAS, Andreas ,  SCHUNK, Stephan A. ,  KANADY, Jacob

IPC: B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/16 ,  B01J37/34 ,  B01J23/58 ,  B01J23/63 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  H01M4/00

公开(公告)号：EP3116826B1

公开(公告)日：2018-07-04

申请号：EP15708833.7

申请日：2015-03-11

Applicant: BASF SE

Inventor： SCHUNK, Stephan A. ,  SCHWAB, Ekkehard ,  MILANOV, Andrian ,  WASSERSCHAFF, Guido ,  ROUSSIERE, Thomas ,  STRASSER, Andreas ,  LIZANDARA, Carlos ,  MÜLLER, Robert

IPC: C01B3/40 ,  B01J23/00 ,  B01J21/02

CPC classification number: B01J23/83 ,  B01J21/04 ,  B01J23/002 ,  B01J23/89 ,  B01J23/894 ,  B01J35/1009 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1235 ,  C01B2203/1241 ,  C10G2/50 ,  Y02P20/52

公开(公告)号：EP3142995B1

公开(公告)日：2018-03-21

申请号：EP15721272.1

申请日：2015-05-13

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  LEJKOWSKI, Michael ,  HUGUET SUBIELA, Nuria ,  GORDILLO, Alvaro ,  LINDNER, Ronald ,  BRU ROIG, Miriam ,  SCHUNK, Stephan A.

IPC: C07C51/15 ,  C07C57/05

CPC classification number: C07C51/15 ,  C07C57/04

Abstract: Catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, wherein an alkene and carbon dioxide are reacted in the presence of a carboxylation catalyst and in the presence of a specific aryloxide to obtain the α,β-ethylenically unsaturated carboxylic acid salt, the carboxylation catalyst being a transition metal complex. The process allows for efficient preparation of α,β-ethylenically unsaturated carboxylic acid derivatives from CO2 and an alkene.

公开(公告)号：EP3215266A1

公开(公告)日：2017-09-13

申请号：EP15804328.1

申请日：2015-11-05

Applicant: BASF SE

Inventor： TITLBACH, Sven ,  SCHUNK, Stephan A. ,  MÜLLER, Robert ,  SUNDERMANN, Andreas ,  GOEBEL, Michael ,  KARPOV, Andrey ,  DEEBA, Michel ,  ZHENG, Xiaolai ,  GLAUM, Robert ,  SCHMITZ, Andreas

IPC: B01J23/63 ,  B01D53/94 ,  C01F17/00

CPC classification number: B01J23/10 ,  B01D53/945 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2092 ,  B01D2255/40 ,  B01D2255/908 ,  B01D2255/9202 ,  B01D2255/9207 ,  B01J21/04 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/035 ,  B01J37/06 ,  B01J37/08 ,  C01F7/02 ,  C01F17/0043 ,  C01G25/02 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/13 ,  Y02T10/22

Abstract: The present invention relates to a composite oxide comprising ceria, praseodymia and alumina, wherein the cerium : praseodymium molar ratio of the composite oxide is 84:16 or less, as well as to a method of preparing the composite oxide and to its use, in particular in a method of treating an exhaust gas stream.

Abstract translation: 本发明涉及包含二氧化铈，氧化镨和氧化铝的复合氧化物，其中复合氧化物的铈：镨摩尔比为84:16或更低，以及制备该复合氧化物的方法及其用途， 特别是在处理废气流的方法中。