公开(公告)号：EP3241864A1

公开(公告)日：2017-11-08

申请号：EP17168383.2

申请日：2017-04-27

申请人： China Petroleum & Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation

发明人： Guo, Peng ,  Lyu, Mingfu ,  Xu, Yaohui ,  Zhang, Shijun ,  Quan, Hui ,  Xu, Kai ,  Bi, Fuyong ,  Song, Wenbo

IPC分类号： C08K5/00

CPC分类号： C08J9/0038 ,  C08J9/0061 ,  C08J9/0066 ,  C08J9/0076 ,  C08J9/0085 ,  C08J9/0095 ,  C08J9/122 ,  C08J2203/06 ,  C08J2323/06 ,  C08J2323/12 ,  C08J2323/16 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2375/04 ,  C08J2377/02 ,  C08K3/017 ,  C08K3/046 ,  C08K3/32 ,  C08K5/0066 ,  C08K5/52 ,  C08K2201/011 ,  C08K2201/017 ,  C08L23/12 ,  C08L23/16 ,  C08L2201/02 ,  C08L2201/08 ,  C08L2203/14 ,  C08L2205/02 ,  C09K21/02 ,  C09K21/04 ,  C09K21/12 ,  D01F9/15 ,  D10B2401/16

摘要： The present invention refers to a flame retardant comprising a complex formed by phosphine oxide and transition metal salt, wherein has good flame retardant property. The present invention also refers to a composite flame retardant and flame retardant antistatic composition, wherein composite flame retardant comprise the flame retardant and the inorganic flame retardant component as described above, which has an enhanced flame retardant effect; said flame retardant antistatic composition, comprising above described flame retardant or composite flame retardant and carbon nanofiber antistatic agent, wherein carbon nanofiber antistatic agent could have interaction with flame retardant, effectively reducing the amount of flame retardant, and the combination with the flame retardant without the adverse effect of each other which result in negative performance of each other, does not influence the subsequent foaming process and the foam structure and physical properties. The present invention also further refers to a flame resistant method, which adds the abovementioned flame retardant, composite flame retardant or flame retardant antistatic composition into the material, so that said material has flame retardance or flame retardance and antistatic, and has excellent mechanical properties.

摘要翻译： 本发明涉及包含由氧化膦和过渡金属盐形成的配合物的阻燃剂，其中阻燃性良好。 本发明还涉及一种复合阻燃阻燃抗静电组合物，其中复合阻燃剂包括如上所述的阻燃剂和无机阻燃组分，其具有增强的阻燃效果; 所述阻燃抗静电组合物包含上述阻燃剂或复合阻燃剂和碳纳米纤维抗静电剂，其中碳纳米纤维抗静电剂可与阻燃剂相互作用，有效减少阻燃剂用量，且与无阻燃剂 彼此的不利影响导致彼此的负面性能，不影响随后的发泡过程和泡沫结构以及物理性质。 本发明还涉及阻燃方法，其将上述阻燃剂，复合阻燃剂或阻燃抗静电组合物加入材料中，使得所述材料具有阻燃性或阻燃性和抗静电性，并且具有优异的机械性能。

公开(公告)号：EP3015502B1

公开(公告)日：2016-12-14

申请号：EP15191626.9

申请日：2015-10-27

申请人： China Petroleum&Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation

发明人： Gao, Dali ,  Shi, Hongwei ,  Zhang, Shijun ,  Guo, Meifang ,  Yu, Luqiang ,  Qiao, Jinliang ,  Li, Ruxian ,  Tang, Yujing ,  Yin, Jianjun ,  Wang, Liangshi ,  Huang, Honghong ,  Yang, Qingquan ,  Zou, Hao ,  Li, Jie ,  Zhang, Liying ,  Yin, Hua ,  Liu, Jianye ,  Shao, Jingbo ,  Lyu, Mingfu ,  Chu, Liqiu ,  Xu, Meng ,  Quan, Hui ,  Xu, Kai ,  Dong, Mu ,  Lyu, Yun ,  Xu, Yihui ,  Xu, Yaohui ,  Guo, Peng ,  Bai, Yiqing

IPC分类号： C08L23/08

CPC分类号： C08J5/18 ,  B32B27/08 ,  B32B27/18 ,  B32B27/32 ,  B32B27/327 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2307/406 ,  B32B2307/412 ,  B32B2307/518 ,  B32B2307/54 ,  B32B2307/558 ,  B32B2307/72 ,  B32B2410/00 ,  B32B2439/00 ,  B32B2439/06 ,  B32B2439/46 ,  C08J2323/06 ,  C08J2323/08 ,  C08L23/08 ,  C08L2203/16 ,  C08L2203/30 ,  C08L2205/025 ,  C08L2205/03

公开(公告)号：EP1947123B1

公开(公告)日：2016-03-09

申请号：EP06805124.2

申请日：2006-10-31

申请人： China Petroleum & Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation

发明人： CHEN, Wei ,  GUO, Zifang ,  ZHOU, Junling ,  WANG, Hongtao ,  YANG, Hongxu ,  LI, Ruixia ,  WANG, Ruiping

IPC分类号： C08F4/64 ,  C08F10/00 ,  B01J31/38

CPC分类号： C08F10/02 ,  B01J31/128 ,  C08F10/00 ,  C08F110/02 ,  C08F4/6586 ,  C08F4/6567 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6565

公开(公告)号：EP2454290B1

公开(公告)日：2014-04-16

申请号：EP09847203.8

申请日：2009-07-15

申请人： China Petroleum&Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

发明人： XIA, Xianzhi ,  LIU, Yuexiang ,  ZHANG, Jigui ,  WANG, Xinsheng ,  GAO, Ping ,  QIAO, Suzhen ,  YIN, Maoping ,  LI, Weili ,  ZHANG, Tianyi ,  PENG, Renqi ,  CHEN, Ying ,  ZHANG, Zhihui

IPC分类号： C08F4/02 ,  C08F10/00 ,  C08F10/06 ,  C07F3/02 ,  C08F4/654

CPC分类号： C08F110/06 ,  C07F3/003 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/24

摘要： A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.

摘要翻译： 由式（I）表示的卤化镁加合物：MgX2.mROH.nE.pH2O，其中X为氯，溴，C1-C12烷氧基，C3-C10环烷氧基或C6-C10芳氧基，条件是 至少一个X是氯或溴; R是C1-C12烷基，C3-C10环烷基或C6-C10芳基; E是由式（II）表示的邻烷氧基苯甲酸酯化合物：其中R 1和R 2基团独立地为C 1 -C 12直链或支链烷基，C 3 -C 10环烷基，C 6 -C 10芳基，C 7 -C 10烷芳基或 C7-C10芳烷基，R1和R2基团与R基团相同或不同; m为1.0〜5.0的范围; n在0.001至0.5的范围内; 并且p在0至0.8的范围内。 还公开了可用于烯烃聚合的催化剂组分，其包含（1）卤化镁加合物，（2）钛化合物和任选的（3）电子给体化合物的反应产物。

公开(公告)号：EP2399902A1

公开(公告)日：2011-12-28

申请号：EP10743392.2

申请日：2010-02-12

申请人： China Petroleum&Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

发明人： XIE, Lunjia ,  TIAN, Yu ,  FENG, Zaixing ,  ZHAO, Siyuan ,  KANG, Yu ,  SUN, Zhufang

IPC分类号： C07C253/30

CPC分类号： C07C253/30 ,  C07C51/09 ,  C07C67/08 ,  C07C255/22 ,  C07C55/02 ,  C07C69/34

摘要： A process for preparing 2,3-di(non-linear-alkyl)-2-cyanosuccinate compounds, especially 2,3-diisopropyl-2-cyanosuccinate compounds, and processes for preparing 2.3-di(non-linear-alkyl)succinic acids and esters thereof by using the 2,3-di-non-linear propyl-2-cyanosuccinate compounds as intermediates are disclosed.

摘要翻译： 制备2,3-二（非线性烷基）-2-氰基琥珀酸盐化合物，特别是2,3-二异丙基-2-氰基琥珀酸盐化合物的方法，以及制备2.3-二（非直链 - 烷基）琥珀酸的方法 公开了通过使用2,3-二 - 非线性丙基-2-氰基琥珀酸盐化合物作为中间体的酯及其酯。

公开(公告)号：EP1767548A1

公开(公告)日：2007-03-28

申请号：EP05762388.6

申请日：2005-07-04

申请人： China Petroleum & Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation

发明人： YANG, Yuanyi ,  DU, Hongbin ,  LI, Zhenhu ,  WANG, Zhiwu ,  TAN, Zhong ,  ZHANG, Kai ,  XIA, Xianzhi ,  LI, Tianyi ,  WANG, Xinsheng ,  ZHANG, Tianyi ,  CHEN, Wei ,  ZHENG, Xuan

IPC分类号： C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00 ,  B01J31/0212 ,  B01J2231/12 ,  B01J2531/46 ,  C08F10/06 ,  C08F110/06 ,  C08F4/022 ,  C08F4/6543 ,  C08F2/00 ,  C08F2/01 ,  C08F2500/15 ,  C08F2500/24 ,  C08F2500/18

摘要： The present invention provides a spheric catalyst component as well as a catalyst for olefin polymerization. The spheric catalyst component comprises at least one titanium compound and optionally at least one electron donor compound supported on an active magnesium halide spheric carrier, wherein the active magnesium halide spheric carrier is solid particles obtained by dispersing a melt of a magnesium halide/alcohol adduct by rotation under high-gravity field. The catalyst has good particle morphology and narrow particle size distribution, and when used in olefin polymerization, especially in propylene polymerization, exhibits relatively high activity and stereoelectivity, and gives polymers having good particle morphology and high bulk density.

摘要翻译： 本发明提供球形催化剂组分以及用于烯烃聚合的催化剂。 球形催化剂组分包含至少一种钛化合物和任选的至少一种负载在活性卤化镁球载体上的电子给体化合物，其中活性卤化镁球载体是通过将卤化镁/醇加合物的熔体分散在 在高重力场下旋转。 该催化剂具有良好的颗粒形态和较窄的粒度分布，当用于烯烃聚合反应中，特别是在丙烯聚合反应中，表现出较高的活性和立体选择性，并且得到具有良好的颗粒形态和高体积密度的聚合物。

公开(公告)号：EP1669375A1

公开(公告)日：2006-06-14

申请号：EP04762053.9

申请日：2004-08-09

申请人： China Petroleum & Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation

发明人： YANG, Yuanyi ,  LI, Zhenhu ,  DU, Hongbin ,  WANG, Zhiwu ,  TAN, Zhong ,  LI, Tianyi ,  CHEN, Qi ,  CHEN, Wei

IPC分类号： C08F4/02 ,  C08F10/00

CPC分类号： C08F10/00 ,  B01J27/138 ,  B01J35/023 ,  B01J2231/12 ,  C08F4/6543 ,  C08F4/022

摘要： The present invention provides a process for preparing particles of magnesium halide/alcohol adduct, said process comprising: preparing a melt of magnesium halide/alcohol adduct in an inert liquid medium, dispersing the melt of the magnesium halide/alcohol adduct by high-speed rotation under a high-gravity field to obtain a dispersion of magnesium halide/alcohol adduct melt; and cooling the dispersion of the melt to form spheric particles of magnesium halide/alcohol adduct. The present invention further relates to the particles of magnesium halide/alcohol adduct prepared by the process of the present invention and the use thereof in the preparation of catalysts for olefin polymerization.

摘要翻译： 本发明提供一种制备卤化镁/醇加合物颗粒的方法，所述方法包括：在惰性液体介质中制备卤化镁/醇加合物的熔体，通过高速旋转分散卤化镁/醇加合物的熔体 在高重力场下获得卤化镁/醇加成物熔体的分散体; 并冷却熔体的分散体以形成卤化镁/醇加合物的球形颗粒。 本发明还涉及通过本发明的方法制备的卤化镁/醇加合物的颗粒及其在制备用于烯烃聚合的催化剂中的用途。

公开(公告)号：EP1478617A1

公开(公告)日：2004-11-24

申请号：EP03739422.8

申请日：2003-01-30

申请人： China Petroleum & Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation

发明人： GAO, Mingzhi ,  WANG, Jun ,  LI, Changxiu ,  LI, Jiyu ,  LI, Tianyi ,  LI, Xianzhong ,  MA, Jing ,  XING, Lingyan ,  LIU, Haitao

IPC分类号： C07C69/78 ,  C07C69/82 ,  C07C69/16 ,  C07C69/28 ,  C07D305/10 ,  C07C69/54 ,  C07C69/618 ,  C07C69/04 ,  C07C67/00 ,  C08F4/654

CPC分类号： C07D307/42 ,  C07C69/007 ,  C07C69/16 ,  C07C69/28 ,  C07C69/618 ,  C07C69/76 ,  C07C69/78 ,  C07C2603/18 ,  C07D307/68 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/04

摘要： The present application relates to polyol ester compounds, having general formula (I): R1CO-O-CR3R4-A-CR5R6-O-CO-R2 (I) wherein, R, and R2 groups, which may be identical or different, can be substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R3-R6 groups, which may be identical or different, can be selected from the group consisting of hydrogen, halogen or substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R1-R6 groups optionally contain one or more hetero-atoms replacing carbon, hydrogen atom or the both, said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, two or more of R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring; A is a single bond or bivalent linking group with chain length between two free radicals being 1-10 atoms, wherein said bivalent linking group is selected from the group consisting of aliphatic, alicyclic and aromatic bivalent radicals, and can carry C1-C20 linear or branched substituents; one or more of carbon atom and/or hydrogen atom on the substituents can be replaced by a hetero-atom selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus, and halogen atom, and two or more said substituents on the linking group as well as above-mentioned R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring. The compounds of formula (I) find use in preparing a catalyst for olefin polymerization.

公开(公告)号：EP3875565B1

公开(公告)日：2024-10-23

申请号：EP19879913.2

申请日：2019-09-27

发明人： JIANG, Haibin ,  QIAO, Jinliang ,  ZHANG, Xiaohong ,  LIU, Wenlu ,  GAO, Jianming ,  QI, Guicun ,  SONG, Zhihai ,  LAI, Jinmei ,  CAI, Chuanlun ,  LI, Binghai ,  WANG, Xiang ,  RU, Yue ,  ZHANG, Hongbin ,  HAN, Peng ,  ZHANG, Jiangru ,  JIANG, Chao ,  GUO, Zhaoyan

IPC分类号： C10G1/00 ,  C10G1/10

公开(公告)号：EP4382568A1

公开(公告)日：2024-06-12

申请号：EP22852227.2

申请日：2022-08-03

申请人： China Petroleum & Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation ,  Tsinghua University

发明人： SHAO, Qing ,  HE, Jinliang ,  YUAN, Hao ,  LI, Qi ,  ZHANG, Yaru ,  HU, Jun ,  WANG, Mingti ,  HUANG, Shangshi ,  LI, Juan ,  HU, Shixun ,  ZHANG, Qi ,  GAO, Dali ,  SHI, Hongwei

IPC分类号： C08L23/12 ,  C08F255/02 ,  C08F255/04 ,  C08F222/06 ,  H01B3/30

CPC分类号： C08F255/04 ,  C08L23/12 ,  C08F255/02 ,  C08F222/06 ,  H01B3/30

摘要： The invention belongs to the field of insulating materials, in particular cable insulating materials, and particularly relates to a modified flexible polypropylene insulating material, and preparation method and use thereof. The modified flexible polypropylene insulating material comprises a propylene-based continuous phase, and a rubber phase and a grafted phase derived from an unsaturated bond-containing polymerizable monomer dispersed in the propylene-based continuous phase; wherein, the modified flexible polypropylene insulating material has a content of xylene solubles of 10-55 wt%, preferably 15-45 wt%, more preferably 18-40 wt%, and still more preferably 20-40 wt%, based on the total weight of the modified flexible polypropylene insulating material; the content of structural units derived from the unsaturated bond-containing polymerizable monomer and in a grafted state in the modified flexible polypropylene insulating material is 0.3-6 wt%, and preferably 0.7-5 wt%; the flexural modulus of the modified flexible polypropylene insulating material is 200-1000 MPa, preferably 200-950 MPa, more preferably 200-700 MPa, and still more preferably 250-600 MPa; preferably, the ratio of the mass of the structural units derived from the unsaturated bond-containing polymerizable monomer in xylene insolubles to the mass of the structural units derived from the unsaturated bond-containing polymerizable monomer in the modified flexible polypropylene insulating material is more than 0.1, preferably 0.3-0.9. The modified flexible polypropylene insulating material of the invention can give consideration to both mechanical property and electrical property at a higher working temperature, and is suitable for working conditions of high temperature and high operating field strength.