公开(公告)号：EP2055380A1

公开(公告)日：2009-05-06

申请号：EP08253534.5

申请日：2008-10-29

Applicant: Petróleo Brasileiro S.A. - PETROBRAS

Inventor： Costa, Alexandre de Figueiredo ,  Feliu, Agustin Martines ,  Martinez, Joan Rollan ,  Cerqueira, Henrique Soares ,  Dias Junior, Joberto Ferreira ,  Aguiar, Eduardo Falabella Sousa

IPC: B01J23/745 ,  C07C1/04 ,  C10G2/00 ,  B01J37/02

CPC classification number: B01J35/0006 ,  B01J21/08 ,  B01J23/6527 ,  B01J23/745 ,  B01J23/75 ,  B01J23/8913 ,  B01J29/0308 ,  B01J29/068 ,  B01J29/126 ,  B01J29/7415 ,  B01J37/0201 ,  C10G2/33 ,  C10G2/332 ,  C10G2/334

Abstract: Process for the production of hybrid catalysts formed by mixing two catalysts; one active in Fischer-Tropsch synthesis, the other being bifunctional. Such hybrid catalyst thus formed is active both in hydrocracking and in hydroisomerisation reactions. The present invention in addition provides obtainment of a hybrid catalyst and application thereof conjointly with FT catalysts in Fischer-Tropsch synthesis reactions. The hybrid catalyst of the present invention is capable of producing in conditions typically such as those utilised in Fischer-Tropsch synthesis branched hydrocarbons in diverse bands relating to the products thereof (for example naphtha and diesel), reducing or even eliminating necessity for a subsequent hydrotreatment stage in such synthesis reactions. Utilisation of such hybrid catalysts of the present invention prolongs the operational efficiency and working life of conventional Fischer-Tropsch synthesis catalysts, reducing substantially encapsulation of particles thereof by waxes produced in the hydroprocessing reactions.

Abstract translation: 用于生产通过混合两种催化剂形成的杂交的催化剂; 一种活性在Fischer-Tropsch合成，另一个是双功能的。 这样形成的混合搜索催化剂既是在加氢裂化和加氢异构化中的反应活性。 此外，本发明提供了一种混合催化剂和应用程序的获取其共同地在费 - 托合成反应的FT催化剂。 本发明的混合催化剂能够在条件生产通常的：例如在费 - 托利用合成支化的烃转化为各种频带与产品有关的物（例如石脑油和柴油），减少或甚至消除必要性用于随后的水热处理 阶段在寻求合成反应。 求本发明的混合催化剂的利用率延长常规费 - 托的操作效率和工作寿命合成催化剂，其通过在加氢处理反应产生的蜡基本上减少颗粒的封装。

公开(公告)号：EP1964131B1

公开(公告)日：2009-04-22

申请号：EP06818081.9

申请日：2006-11-16

Applicant: Forschungszentrum Jülich GmbH

Inventor： REINECKE, Ernst-Arndt ,  TRAGSDORF, Inga, Maren

IPC: G21C19/317 ,  B01J35/02 ,  B01J12/00 ,  G21C9/06

CPC classification number: G21C19/317 ,  B01J23/6525 ,  B01J31/06 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0215 ,  G21Y2002/50 ,  G21Y2004/10 ,  G21Y2004/30

公开(公告)号：EP2000201A9

公开(公告)日：2009-03-18

申请号：EP07738055.8

申请日：2007-03-08

Applicant: Daihatsu Motor Co., Ltd. ,  Cataler Corporation

Inventor： TANAKA, Hirohisa ,  TAN, Isao ,  UENISHI, Mari ,  TANIGUCHI, Masashi ,  KIMURA, Mareo ,  MATSUEDA, Satoshi

IPC: B01J23/56 ,  B01D53/94 ,  B01J23/89

CPC classification number: B01D53/945 ,  B01D53/94 ,  B01D2255/1025 ,  B01D2255/204 ,  B01D2255/2047 ,  B01D2255/20738 ,  B01D2255/2092 ,  B01J23/002 ,  B01J23/58 ,  B01J23/8946 ,  B01J37/0201 ,  B01J37/031 ,  B01J2523/00 ,  Y02A50/2324 ,  Y02T10/22 ,  B01J2523/31 ,  B01J2523/3718 ,  B01J2523/822 ,  B01J2523/24 ,  B01J2523/842 ,  B01J2523/22 ,  B01J2523/47

Abstract: Provided is a catalyst composition capable of preventing decrease in catalytic activity due to grain growth of noble metal under high temperature or under change in oxidation reduction or further for long term use, and of achieving excellent catalytic activity over a long time.
The catalyst composition containing a composite oxide represented by the following general formula (1):

        AO·x(B 2-y C y O 3-α )     (1)

(wherein A represents an element selected from monovalent elements, divalent elements and lanthanides; B represents a trivalent element; and C represents a noble metal; x represents an integer of 1 to 6; y represents an atomic ratio satisfying the following relation: 0

Abstract translation: 本发明提供一种催化剂组合物，其能够防止由于贵金属在高温下或在氧化还原变化或长期使用变化下晶粒生长而引起的催化活性降低，并且能够长期实现优异的催化活性。 （1）表示的复合氧化物：AO·x（B2-yCyO3-α）（1）（式中，A表示选自一价元素，二价元素和镧系元素中的元素，B表示三价 元素; C表示贵金属; x表示1至6的整数; y表示满足以下关系的原子比：0

公开(公告)号：EP2030680A1

公开(公告)日：2009-03-04

申请号：EP08166458.3

申请日：2002-06-10

Applicant: BASF SE

Inventor： Vanoppen, Dominic ,  Maas-Brunner, Melanie ,  Kammel, Ulrich ,  Arndt, Jan-Dirk

IPC: B01J23/46 ,  B01J37/18 ,  C07C31/26 ,  C07C29/141

CPC classification number: C07C29/132 ,  B01J21/08 ,  B01J23/462 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1023 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/18 ,  C07C31/26 ,  C07C31/18

Abstract: Die vorliegende Erfindung betrifft neue Ruthenium-Katalysatoren, die erhältlich sind durch:
i) ein oder mehrfaches Behandeln eines Trägermaterials auf Basis von amorphem Siliziumdioxid mit einer halogenfreien wässrigen Lösung einer niedermolekularen Rutheniumverbindung und anschliessendes Trocknen des behandelten Trägermaterials bei einer Temperatur unterhalb 200°C,
ii) Reduktion des in i) erhaltenen Feststoffs mit Wasserstoff bei einer Temperatur im Bereich von 100 bis 350°C,

wobei man und Schritt ii) unmittelbar im Anschluss an Schritt i) durchführt, ein Verfahren zu ihrer Herstellung und ihre Verwendung zur katalytischen Hydrierung von Mono- und Disacchariden bei der Herstellung von Zuckeralkoholen, ausgenommen von Sorbit.

Abstract translation: 提供用于生产糖醇的钌催化剂。 钌催化剂（I）通过以下方法制备：（A）使用低摩尔的无卤素溶液对无定形二氧化硅载体材料进行单次或多次处理。 重量。 钌化合物，然后在低于200℃下干燥; （B）在100-350℃下用氢还原所得固体，使得步骤（B）在步骤（A）之后立即进行。 通过催化氢化在非均相催化剂（I）中的液相中的相应的单糖和寡糖，除了生产山梨糖醇的方法外，还包括制备糖醇的方法的独立权利要求。

公开(公告)号：EP2026905A1

公开(公告)日：2009-02-25

申请号：EP07725285.6

申请日：2007-05-16

Applicant: Bayer MaterialScience AG

Inventor： WOLF, Aurel ,  MLECZKO, Leslaw ,  SCHLÜTER, Oliver, Felix-Karl ,  SCHUBERT, Stephan

IPC: B01J23/46 ,  C01B7/04

CPC classification number: C01B7/04 ,  B01J23/626 ,  B01J27/13 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/0236

Abstract: The invention relates to a method for producing chlorine by the catalytic gas phase oxidation of hydrogen chloride using oxygen, wherein the catalyst comprises tin dioxide and at least one ruthenium compound containing halogen. The invention also relates to a catalyst composition and the use thereof.

Abstract translation: 本发明涉及一种通过使用氧的催化气相氧化氯化氢来生产氯的方法，其中所述催化剂包含二氧化锡和至少一种含卤素的钌化合物。 本发明还涉及催化剂组合物及其用途。

公开(公告)号：EP1162172A4

公开(公告)日：2009-02-25

申请号：EP00902051

申请日：2000-02-02

Applicant: SINTOKOGIO LTD

Inventor： MAEKAWA MASAAKI ,  SHIRAI CHISAKO ,  TAKEUCHI SATOSHI ,  YAMADA ZENICHI

IPC: B01J21/08 ,  B01D53/86 ,  B01D53/94 ,  B01J21/06 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  C02F1/30 ,  C02F1/32 ,  C02F1/72 ,  C01B33/157 ,  C09D5/00 ,  C09D133/00

CPC classification number: C02F1/30 ,  B01D53/8628 ,  B01D53/9413 ,  B01D2255/20707 ,  B01D2255/802 ,  B01J21/063 ,  B01J21/08 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/004 ,  B01J35/10 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0209 ,  C02F1/32 ,  C02F1/725 ,  C02F2101/308 ,  C02F2305/10 ,  Y02W10/37

Abstract: A silica gel which carries a titanium oxide photocatalyst in high concentration, characterized in that it has an average micropore diameter of 6 to 100 nm and it has a gradient of titanium oxide concentration such that a titanium oxide content of a micropore located in the vicinity of the surface of a silica gel particle is 7 to 70 wt % and is no less than 1.5 times that of a micropore located in the vicinity of the central portion of the particle; and a method for preparing the same. The silica gel has a gradient of titanium oxide concentration wherein a titanium oxide content is higher in the vicinity of the surface of a particle and lower in a central part thereof, which results in the improvement of the ability to decompose environmental pollutants or the like such as a malodorous or hazardous substance contained in air, an organic solvent contained in water and an agricultural chemical, and also has various excellent characteristics from view points of safety, economy, stability and resistance to water (no crack when placed in water).

公开(公告)号：EP2021125A1

公开(公告)日：2009-02-11

申请号：EP07728395.0

申请日：2007-04-23

Applicant: BASF SE

Inventor： HIBST, Hartmut ,  HUBER, Sabine ,  ROSOWSKI, Frank

IPC: B01J23/22 ,  B01J23/847 ,  B01J35/02 ,  C07C253/28

CPC classification number: B01J23/22 ,  B01J21/04 ,  B01J23/002 ,  B01J23/30 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0205 ,  B01J2523/00 ,  C07C253/28 ,  B01J2523/15 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/69 ,  C07C255/51 ,  C07C255/50

Abstract: The present invention relates to a process for preparing an aromatic or heteroaromatic nitrile in the presence of a supported catalyst which comprises a support having a mean diameter of ≤ 78 µm. The present invention further relates to the novel supported catalyst as such and to a process for preparing this novel supported catalyst.

公开(公告)号：EP1569869A4

公开(公告)日：2008-11-19

申请号：EP03786654

申请日：2003-11-12

Applicant: CONOCOPHILLIPS CO

Inventor： RAPIER CHARLES R ,  XIE SHUIBO ,  HU BAILI ,  ORTEGO BEATRICE C ,  SIMON DAVID E ,  MINAHAN DAVID M ,  ERCAN CEMAL

IPC: B01J21/04 ,  B01J21/10 ,  B01J21/12 ,  B01J23/00 ,  B01J23/10 ,  B01J23/40 ,  B01J23/46 ,  B01J23/56 ,  B01J23/63 ,  B01J23/656 ,  B01J23/75 ,  B01J23/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/06 ,  B01J37/08 ,  C01B3/26 ,  C01B3/38 ,  C01B3/40 ,  C07C27/06 ,  C10G2/00 ,  C01B3/42 ,  C01B3/56

CPC classification number: C01B3/40 ,  B01J21/04 ,  B01J21/10 ,  B01J21/12 ,  B01J23/002 ,  B01J23/10 ,  B01J23/40 ,  B01J23/464 ,  B01J23/468 ,  B01J23/56 ,  B01J23/63 ,  B01J23/6567 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0053 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1011 ,  C01B2203/1017 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  C01B2203/1633 ,  C10G2/30 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/22 ,  B01J2523/3737 ,  B01J2523/822 ,  B01J2523/821 ,  B01J2523/845 ,  B01J2523/41

Abstract: The present invention relates to stabilized supports stable at temperatures above 800 °C, and method of preparing such supports, which includes adding a rare earth metal to an aluminum-containing precursor prior to calcining. The present invention can be more specifically seen as a support, process and catalyst wherein the stabilized alumina catalyst support comprises a rare earth aluminate with a molar ratio of aluminum to rare earth metal greater than 5:1 and, optionally, an aluminum oxide. More particularly, the invention relates to the use of catalysts comprising rhodium, ruthenium, iridium, or combinations thereof, loaded onto said stabilized supports for the synthesis gas production via partial oxidation of light hydrocarbons, and further relates to gas-to-liquids conversion processes.

公开(公告)号：EP1975128A1

公开(公告)日：2008-10-01

申请号：EP07713646.3

申请日：2007-01-19

Applicant: OSAKA Titanium Technologies Co., Ltd. ,  Yoshihara, Masahiro

Inventor： OGASAWARA, Tadashi ,  SHIMOSAKI, Shinji ,  AZUMA, Kazuomi

IPC: C01G23/04 ,  B01J35/02 ,  C23C16/02

CPC classification number: B01J35/004 ,  B01D53/8668 ,  B01D2255/20707 ,  B01D2255/802 ,  B01D2257/70 ,  B01D2259/804 ,  B01J21/063 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/0244 ,  B01J37/03 ,  C01G23/0536 ,  C23C18/04 ,  C23C18/1204 ,  C23C18/1216 ,  C23C18/1241 ,  C23C18/1279 ,  C25D11/02 ,  C25D11/26

Abstract: An even titanium oxide film is economically formed on the surface of a substrate. To actualize the film formation, an aqueous titanium tetrachloride solution containing 0.1 to 17% by weight of Ti is applied in a film-like state on the surface of a heat resistant substrate. While the liquid film state is kept as it is, the aqueous titanium tetrachloride solution is heated to 300°C or more and H 2 O and HCl in the liquid film are accordingly evaporated to form a titanium oxide film. In the case where the substrate is of aluminum inferior in acid resistance, an acid-resistant film such as an oxide film is previously formed on the surface of the metal substrate.

Abstract translation: 在衬底的表面上经济地形成均匀的钛氧化物膜。 为了实现成膜，将含有0.1〜17重量％的Ti的四氯化钛水溶液以膜状涂布在耐热性基材的表面上。 在保持液膜状态的同时，将四氯化钛水溶液加热至300℃或更高，并且液膜中的H 2 O和HCl相应地蒸发以形成氧化钛膜。 在基材为耐酸性差的铝的情况下，预先在金属基材的表面上形成耐酸膜，例如氧化膜。

公开(公告)号：EP1960100A1

公开(公告)日：2008-08-27

申请号：EP06816887.1

申请日：2006-10-13

Applicant: BASF Catalysts LLC

Inventor： YANG, Xiaolin, David

IPC: B01J21/04 ,  B01J23/10 ,  B01J23/40 ,  B01J23/63 ,  B01J37/02

CPC classification number: B01J21/04 ,  B01D53/945 ,  B01D2255/206 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2092 ,  B01J23/10 ,  B01J23/40 ,  B01J23/63 ,  B01J37/0201 ,  C01F7/02 ,  C01F7/021 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/80 ,  Y02T10/22

Abstract: A low cost support useful in chemical reactions and automotive arts is formed by rehydrating a flash calcined gibbsite in an aqueous acidic solution. The rehydrated support can be subsequently stabilized by doping with a stabilizing metal such as lanthanum. The alumina support has excellent thermal stability, high sodium tolerance, high activity with low precious metal loading, and high pore volume and surface area.