POLYMER MANUFACTURING METHOD
    21.
    发明公开
    POLYMER MANUFACTURING METHOD 审中-公开
    POLYMERHERSTELLUNGSVERFAHREN

    公开(公告)号:EP2301990A1

    公开(公告)日:2011-03-30

    申请号:EP09794549.7

    申请日:2009-07-09

    IPC分类号: C08G77/60 C08G77/08 C08G79/00

    CPC分类号: C08G77/60 C07F7/0896

    摘要: A polymer production process comprising reacting a compound represented by the following formula (1) in the presence of a binuclear metal complex represented by the following formula (2).

            R 4-n MH n      (1)

    (in the formula (1), R is a monovalent organic group, M is a silicon atom or a germanium atom, and n is 2 or 3.)

            [CpM(µ-CH 2 )] 2      (2)

    (in the formula (2), Cp is a cyclopentadienyl-based ligand, M is a metal atom selected from Rh and Ir, and the bond between M's is a double bond.)

    摘要翻译: 一种聚合物制备方法,包括在下式(2)表示的双核金属络​​合物的存在下使由下式(1)表示的化合物反应。 ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒR4-n MH n€ƒ€ƒ€ƒ(1)(在公式(1)中,R是一价有机组,M 是硅原子或锗原子,n为2或3.)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ[CpM(μ-CH 2)] 2€ƒ€ƒ€ƒ€ ƒƒ(2)(式(2)中,Cp为环戊二烯基配体,M为选自Rh和Ir的金属原子,M之间的键为双键。

    HOMO AND HETEROMETALLIC SOLUBLE COORDINATION POLYMERS CONTAINING AN OXALATE LIGAND AND METHOD FOR OBTAINING SPINELS FROM SAME
    22.
    发明公开
    HOMO AND HETEROMETALLIC SOLUBLE COORDINATION POLYMERS CONTAINING AN OXALATE LIGAND AND METHOD FOR OBTAINING SPINELS FROM SAME 审中-公开
    连同其OBTAINING SPIN ELLEN一个OXALATLIGAND和过程HOMO和异性非金属水溶性配位聚合物

    公开(公告)号:EP2270072A1

    公开(公告)日:2011-01-05

    申请号:EP09733865.1

    申请日:2009-04-24

    IPC分类号: C08G79/00 C01B13/32

    摘要: Soluble homo and heterometallic coordination polymers based on the oxalate ligand and method for obtaining spinels from them. Homo or heterometallic coordination polymers comprising at least one oxalate ligand are characterised by comprising also at least one organic molecule that can stabilise extended structures of metal complexes by the formation of supramolecular interactions so that this polymer is substantially water-soluble and insoluble in organic solvents. These polymers, when in solid state, can generate spinel-type metal oxides or other mixed oxides after thermal oxidation treatment comprising the steps of preparing an alcohol solution of a metal complex comprising at least one oxalate ligand and a metal salt, precipitate this metal complex and this metal salt with a cryptand-type molecule by formation of a coordination polymer which is water-soluble and insoluble in organic solvents, separate the precipitate obtained in the previous step and heat it under oxidising atmosphere at a temperature of at least 350°C until the spinel or the mixed oxide are formed.

    摘要翻译: 水溶性均聚物和基于草酸盐配体和方法,用于从它们获得尖晶石杂金属配位聚合物。 均聚或杂金属配位聚合物,其包含至少一种草酸盐配体可通过包括这样的至少一个的有机分子也可通过超分子相互作用的形成稳定的金属配合物的伸长结构,使得thatthis聚合物基本上是水溶性的,并且不溶于有机溶剂为特征。 聚合物合成,当在固体状态下,可生成热氧化处理,其包括制备一种金属络合物,其包含至少一种草酸盐配体和金属盐的醇溶液的步骤之后的尖晶石型金属氧化物或其它混合氧化物,沉淀该金属络合物 并与通过形成配位聚合物的所有的穴状配体型分子此金属盐在有机溶剂中的水溶性和不溶性的,分离前一步骤中获得的沉淀物和下在至少350℃的温度,在氧化气氛中加热它 直到尖晶石或混合氧化物形成。

    METAL-CONTAINING COMPOUND AND USE THEREOF
    25.
    发明公开
    METAL-CONTAINING COMPOUND AND USE THEREOF 有权
    VERBINDUNG VERBINDUNG VERWENDUNG DAVON

    公开(公告)号:EP1813639A1

    公开(公告)日:2007-08-01

    申请号:EP05806699.4

    申请日:2005-11-16

    摘要: The present invention is to provide a polymerizable compound which can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7, and an optical component composed of such a resin.
    Specifically disclosed are a compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin.

    摘要翻译: 本发明提供一种聚合性化合物,其可以成为具有高透明度,高耐热性和塑料透镜等的光学部件所需的机械强度的树脂的原料,同时达到高折射率(nd) 1.7,以及由这种树脂构成的光学部件。 具体公开了具有两个以上硫醇基和选自分子内的金属原子的原子的化合物,含有这种化合物的多硫醇组合物,含有这种多硫醇组合物的聚合性组合物,通过聚合这种聚合性组合物得到的树脂, 和由这种树脂获得的光学部件。