摘要:
It is provided a self-healing polymer network comprising transition metal thiolates, particularly thiolates of a transition metal that is able to self-assemble by metallophilic attractions, and more particularly Au(I), Ag(I), Cu(I) thiolates, or a mixture thereof, and, optionally, disulfide bonds, thiol and other thiolate groups. It is also provided several processes for the preparation of the self-healing polymer networks of the invention, as well as uses thereof.
摘要:
The present invention is to provide a polymerizable compound which can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7, and an optical component composed of such a resin. Specifically disclosed are a compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin.
摘要:
"A high-molecular compound or high-molecular antioxidant obtained by reacting at least three compounds of (A) a sulfur-containing organic compound having at least two active hydrogen atoms, (B) a polyisocyanate compound having at least two isocyanate groups and (C) an amine compound having at least two active hydrogen atoms and then cationizing with an acid at least some of amino groups in a resultant reaction product" or "a high-molecular antioxidant obtained by reacting at least three compounds of (A) a sulfur-containing organic compound having at least two active hydrogen atoms, (B) a polyisocyanate compound having at least two isocyanate groups and (E) a nonionic polyol compound having at least two active hydrogen atoms" and a recording medium obtained by using the high-molecular antioxidant. The present invention provides a recording medium, which effectively prevents discoloration or color fading of images by acidic gas in the atmosphere and light and also migration of the images at high temperature and high humidity, and therefore, is suited for the long-term storage of the images.
摘要:
The self-healing cross-linked polymer comprises units of formula (I), wherein: P is a polymeric chain, R1 and R1' are independently selected from the group consisting of: -H, (C1-C20)alkyl, (C5-C14)aryl, -OR4, -(CO)R5, -O(CO)R6, -(SO)R7, -NH-CO-R8, -COOR9, -NR10R11, -NO2, and halogen; R2, R2', R3 and R3' are independently selected from the group consisting of: -H, (C1-C20)alkyl and (C5-C14)aryl; R4 to R11 are the same or different, and are selected from the group consisting of: -H, (C1-C20)alkyl, and (C5-C14)aryl; m is from 3 to 4;n is from 1 to 2; provided that n + m is 5; the polymer having H-bonding interactions and being able to undergo catalyst free aromatic disulfide metathesis at room-temperature, and having a tensile strength value from 0.5 to 1.5 MPa and an elongation at break value higher than 200% at room- temperature. (I)
摘要:
A polyol compound characterized by being denoted by general formula (I). A transparent molded article obtained by polymerizing monomer components comprising the aforementioned polyol compound. A transparent molded article obtained by polymerizing monomer components comprising components (C) and (D). A method of manufacturing a transparent molded article, comprising casting a mixture of component (C) and component (D) into a casting mold and then polymerizing component (C) and component (D) to obtain a molded article.