公开(公告)号：EP2794539A1

公开(公告)日：2014-10-29

申请号：EP12809717.7

申请日：2012-12-14

Applicant: BASF SE

Inventor： SCHNEIDER, Daniel ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  FRIES, Donata, maria ,  TELES, Joaquim, Herinque ,  BASSLER, Peter ,  RITTINGER, Stefan ,  SCHRAUB, Thomas

IPC: C07C51/02 ,  C07C51/09 ,  C07C51/15 ,  C07C51/44 ,  C07C53/02 ,  C07C53/06

CPC classification number: C07C51/02 ,  C07C51/09 ,  C07C51/41 ,  C07C51/412 ,  C07C51/48 ,  C07C53/02 ,  C07C53/06

Abstract: The invention relates to a method for obtaining formic acid by thermally separating a flow containing formic acid and a tertiary amine (I), wherein a liquid flow containing formic acid, tertiary amine (I), and water is produced by bringing together a tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed, and formic acid is removed from the obtained liquid flow by means of distillation in a distillation device, wherein the removed flow containing water and organic decomposition products of the tertiary amine (I) is separated into two liquid phases, the upper liquid phase is removed, and the lower liquid phase containing water is fed back to the formic acid source.

Abstract translation: 本发明涉及一种通过热分离含甲酸和叔胺（I）的流动物来获得甲酸的方法，其中通过将叔胺（I）和叔胺 （I）和甲酸源的存在下，除去叔胺（I）的水和有机分解产物，并通过蒸馏装置中的蒸馏从所得液体流中除去甲酸，其中 将含有水的被除去的流体和叔胺（I）的有机分解产物分离成两个液相，将上层液相除去，将含有水的下层液体回流至甲酸源。

公开(公告)号：EP0931054B2

公开(公告)日：2012-07-11

申请号：EP97942889.3

申请日：1997-08-28

Applicant: BASF SE

Inventor： LUYKEN, Hermann ,  REHFINGER, Alwin ,  BASSLER, Peter ,  VOIT, Guido ,  FISCHER, Rolf ,  MERGER, Martin ,  RUST, Harald

IPC: C07C209/86

CPC classification number: C07C209/86 ,  C07C211/36 ,  C07C2601/08 ,  Y10S203/11 ,  C07C211/12

Abstract: Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.

Abstract translation: 一种用于从通过在从1到300毫巴的压力下蒸馏该混合物由......组成六亚甲基二胺和2- aminomethylcyclopentylamine的混合物中分离2- aminomethylcyclopentylamine过程。

公开(公告)号：EP1558364B1

公开(公告)日：2010-03-24

申请号：EP03772249.3

申请日：2003-10-23

Applicant: BASF SE

Inventor： BASSLER, Peter ,  GÖBBEL, Hans-Georg ,  TELES, Joaquim-Henrique ,  RUDOLF, Peter

IPC: B01D53/14 ,  C07D301/12 ,  C07D301/32

CPC classification number: C07D301/12 ,  B01D53/1487 ,  B01D53/1493 ,  B01D2257/702 ,  C07D301/32

Abstract: The invention relates to a method for continuously returning an olefin which has not been reacted with hydroperoxide in order to form oxiranes during the oxidation of olefins. Said olefin is contained in the flow of waste gas which is produced during oxidation. Said method is characterised by the following steps: (i) separating the olefin from the flow of waste gas by absorption in a hydrocarbon, (ii) desorption of the olefin from the hydrocarbon, (iii) returning the olefin obtained in step (ii) into the oxidation process.

公开(公告)号：EP1708804B1

公开(公告)日：2009-11-18

申请号：EP05701075.3

申请日：2005-01-20

Applicant: BASF SE

Inventor： GÖBBEL, Hans-Georg ,  BASSLER, Peter ,  TELES, Joaquim Henrique ,  RUDOLF, Peter

IPC: B01J8/06

CPC classification number: B01J8/067 ,  B01J19/2425 ,  B01J19/243 ,  B01J19/2445 ,  B01J2208/00849 ,  B01J2219/1944 ,  F28D7/024 ,  F28F1/02 ,  F28F1/08

Abstract: The invention relates to a method and a device for the continuous production of a chemical compound in at least one reactor. At least one of the reactors is a pipe assembly reactor which comprises a covering and at least one inner pipe (9) which is arranged in the covering. The invention is characterised in that at least one of the inner pipes arranged in the area where it is surrounded by a covering, at least partially comprises a non-circular transversal cross-section and is helically shaped.

公开(公告)号：EP1278726B1

公开(公告)日：2009-07-08

申请号：EP01927931.4

申请日：2001-04-30

Applicant: BASF SE

Inventor： OHLBACH, Frank ,  ANSMANN, Andreas ,  BASSLER, Peter ,  FISCHER, Rolf-Hartmuth ,  LUYKEN, Hermann ,  MAIXNER, Stefan ,  MELDER, Johann-Peter

IPC: C07D201/08

CPC classification number: C07D201/08

Abstract: The invention relates to a method for producing cyclic lactams of the formula (II), wherein n and m may each represent 0, 1, 2, 3, 4, 5, 6, 7, 8 and 9 and the sum of n + m is at least 3, preferably at least 4, R?1 and R2¿ represent C¿1?-C6 alkyl, C5-C7 cycloalkyl or C6-C12 aryl groups, by reacting a compound of the formula (I), wherein R?1, R2¿, m and n have the meaning indicated above, and R represents nitrile groups, carboxylic acid amide groups and carboxylic acid groups, with water vapor in the gaseous phase. The inventive method is further characterized in that a) the compound (I) is reacted with water vapor in the gaseous phase, adding an organic diluent (III) before or after the reaction, which diluent has a miscibility gap under certain quantitative, pressure and temperature conditions, said reaction resulting in a mixture (IV) that contains a lactam (II), b) adjusting the mixture (IV) before or after the removal of ammonia to quantitative, pressure and temperature conditions under which the diluent (III) and water are present in a liquid form and have a miscibility gap, and obtaining a two-phase system consisting of a phase (V) that has a higher proportion of diluent (III) than water, and a phase (VI) that has a higher proportion of water than diluent (III), c) separating phase (V) from phase (VI) and, d) removing from phase (V) the diluent (III) and optionally by-products selected from the group of the low-boilers, high-boilers and unreacted compound (I), and obtaining a lactam (II).