公开(公告)号：EP3016738A1

公开(公告)日：2016-05-11

申请号：EP14735943.4

申请日：2014-07-03

Applicant: Total Research & Technology Feluy ,  Centre National de la Recherche Scientifique (CNRS)

Inventor： HAW, Kok-Giap ,  GOUPIL, Jean-Michel ,  GILSON, Jean-Pierre ,  VALTCHEV, Valentin ,  NESTERENKO, Nikolai ,  MINOUX, Delphine ,  DATH, Jean-Pierre

IPC: B01J29/00 ,  B01J29/40 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G47/00 ,  C10G11/00 ,  C10G3/00 ,  C10G50/00 ,  C07C1/00 ,  C07C4/00 ,  C07C5/00

CPC classification number: B01J29/40 ,  B01J29/00 ,  B01J29/005 ,  B01J29/041 ,  B01J29/043 ,  B01J29/405 ,  B01J29/44 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0209 ,  B01J37/0211 ,  B01J37/0246 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2229/62 ,  B01J2229/64 ,  C07C4/18 ,  C07C2529/068 ,  C07C2529/076 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/48 ,  C07C2529/80 ,  C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G11/02 ,  C10G11/18 ,  C10G29/205 ,  C10G35/06 ,  C10G35/085 ,  C10G45/60 ,  C10G45/62 ,  C10G47/02 ,  C10G47/12 ,  C10G50/00 ,  Y02P20/52 ,  Y02P30/20 ,  C07C15/04 ,  C07C15/085

Abstract: A catalyst composition contains an inorganic porous material with pore diameters of at least 2 nm and of crystals of molecular sieve. The crystals of molecular sieve have an average diameter, measured by scanning electron microscopy, not bigger than 50 nm. The catalyst composition has a concentration of acid sites ranges from 50 to 1200 μmol/g measured by TPD NH3 adsorption. An XRD pattern of the catalyst composition is the same as an XRD pattern of the inorganic porous material.

公开(公告)号：EP3010640A1

公开(公告)日：2016-04-27

申请号：EP13815169.1

申请日：2013-08-27

Applicant: Hindustan Petroleum Corporation Ltd. ,  Indian Institute of Technology

Inventor： VELU, Jeyalakshmi ,  KONDA, Krishnamurthy Ramaswamy ,  BALASUBRAMANIAN, Viswanathan ,  RAMESH, Kanaparthi ,  PEDDY, Venkata Chalapathi Rao ,  NETTEM, Venkateswarlu Choudary ,  GANDHAM, Sri Ganesh

IPC: B01J23/847 ,  B01J23/89 ,  B01J37/03 ,  B01J37/16 ,  B01J35/00 ,  B01J37/02 ,  C07C31/04

CPC classification number: B01J23/898 ,  B01J19/123 ,  B01J19/127 ,  B01J23/6486 ,  B01J23/682 ,  B01J23/8476 ,  B01J35/0006 ,  B01J35/004 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/08 ,  B01J37/16 ,  B01J37/344 ,  B01J37/345

Abstract: The present subject matter describes a catalyst composition based on sodium tantalate, a modifying agent and at least one co-catalyst and the process of preparing the catalyst composition. The process for photocatalytic reduction of CO2 comprises re-acting carbon dioxide and alkaline water in the presence of catalyst composition that is irradiated with radiation with wavelength in the range of 300-700 nm to produce lower hydrocarbons and hydrocarbon oxygenates.

Abstract translation: 本主题描述了基于钽酸钠，改性剂和至少一种助催化剂的催化剂组合物和制备催化剂组合物的方法。 用于光催化还原CO 2的方法包括在用波长在300-700nm范围内的辐射照射的催化剂组合物存在下再作用二氧化碳和碱性水以产生低级烃和烃类含氧化合物。

公开(公告)号：EP3006107A1

公开(公告)日：2016-04-13

申请号：EP15187914.5

申请日：2015-10-01

Applicant: Evonik Degussa GmbH

Inventor： Micoine, Kévin ,  Meier, Ralf ,  Herwig, Jürgen ,  Bétard, Angélique ,  Quandt, Thomas

IPC: B01J35/00 ,  B01J21/06

CPC classification number: C07C45/58 ,  B01J21/066 ,  B01J21/08 ,  B01J23/38 ,  B01J23/40 ,  B01J23/44 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/08 ,  C07C2601/20 ,  C07D225/02 ,  C07C49/307

Abstract: Es wird eine Katalysatorzusammensetzung zur Verfügung gestellt, die mindestens ein Edelmetall und mindestens ein Mischoxid umfassend Zirconiumdioxid und Siliciumdioxid umfasst. Das Edelmetall ist geträgert und der Träger besteht nicht aus dem Mischoxid. Das Massenverhältnis von Zirconiumdioxid zu Siliciumdioxid im Mischoxid beträgt 86 : 14 bis 99,9 : 0,1.
Das Katalysatorsystem kann zur Herstellung eines Ketons aus einer mindestens eine Epoxidgruppe enthaltenden Verbindung verwendet werden

Abstract translation: 催化剂组合物可用于从含有至少一个环氧基的化合物制备酮，并且催化剂组合物含有至少一种贵金属; 和至少一种混合氧化物; 其中所述混合氧化物含有二氧化锆和二氧化硅; 其中所述贵金属被支撑并且所述支撑体不完全由所述混合氧化物制成; 并且其中所述混合氧化物中二氧化锆与二氧化硅的质量比为86:14至99.9:0.1。

公开(公告)号：EP3003551A1

公开(公告)日：2016-04-13

申请号：EP14736985.4

申请日：2014-06-05

Applicant: Saudi Basic Industries Corporation

Inventor： KARTICK, Chandra Mondal ,  VYAS, Mayank Harishbhai ,  SASMAL, Sankar

IPC: B01J23/78 ,  B01J35/10 ,  C01B3/40

CPC classification number: B01J23/78 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  Y02P20/52

Abstract: The invention is directed to a catalyst composition comprising a mesoporous catalyst support and oxides of nickel (Ni), cobalt (Co) and magnesium (Mg). to a process for the production of the catalyst composition and to the use of the catalyst composition for the production of a syngas.

Abstract translation: 本发明涉及包含介孔催化剂载体和镍（Ni），钴（Co）和镁（Mg）的氧化物的催化剂组合物。 涉及制备催化剂组合物的方法以及催化剂组合物用于生产合成气的用途。

公开(公告)号：EP2604339B1

公开(公告)日：2016-04-06

申请号：EP11816226.2

申请日：2011-08-04

Applicant: Mitsubishi Hitachi Power Systems, Ltd.

Inventor： KAI, Keiichiro ,  KATO, Yasuyoshi ,  IMADA, Naomi

IPC: B01J27/053 ,  B01J37/02 ,  B01J21/06 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01D53/86 ,  B01J37/04

CPC classification number: B01J27/053 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2092 ,  B01J21/04 ,  B01J21/063 ,  B01J21/08 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/038 ,  B01J37/04

公开(公告)号：EP2404873A4

公开(公告)日：2016-04-06

申请号：EP10748798

申请日：2010-03-04

Applicant: TORAY INDUSTRIES

Inventor： NISHINO HIDEKAZU ,  KATO HAJIME ,  OKAMOTO NAOYO ,  IKEUCHI SHUKO ,  SATO KENICHI ,  TANAKA SHIHO ,  HIGUCHI KAZUYOSHI

IPC: C01B31/02 ,  B01J21/10 ,  B01J23/40 ,  B01J23/74 ,  B01J23/745 ,  B01J23/78 ,  B01J35/02 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: B01J21/10 ,  B01J23/40 ,  B01J23/74 ,  B01J23/745 ,  B01J23/78 ,  B01J35/02 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/168 ,  C01B32/174 ,  C01B2202/22 ,  C01B2202/34 ,  C01B2202/36 ,  Y10S977/742 ,  Y10S977/752 ,  Y10T428/2982

公开(公告)号：EP2977103A1

公开(公告)日：2016-01-27

申请号：EP14178004.9

申请日：2014-07-22

Applicant: Paul Scherrer Institut

Inventor： Schildhauer, Tilman J. ,  Kampolis, Anastasios ,  Kröcher, Oliver

IPC: B01J23/755 ,  C10K3/04 ,  C10L3/08 ,  B01J21/04 ,  B01J21/02

CPC classification number: C10K3/04 ,  B01J23/002 ,  B01J23/755 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/18 ,  B01J2523/00 ,  C10L3/08 ,  Y02E50/343 ,  B01J2523/305 ,  B01J2523/31 ,  B01J2523/828 ,  B01J2523/847

Abstract: It is therefore the objective of the present invention to provide a method for the production of SNG taking advantage from a catalyst which has a high selectivity for the catalytic reactions and achieves long lifetime of the catalyst due to minor clogging and strong carbon resistance to prevent its deactivation.
These objectives are achieved according to the present invention by a method to convert a CO and/or CO 2 comprising a gas mixture stemming from an industrial processes, such as gasification of carbonaceous feedstocks (i.e. biomass), pyrolysis, ore conversion, combustion, calcination or fermentation, wherein the gas mixture further comprises saturated hydrocarbons in concentrations above 15% and/or unsaturated hydrocarbons, such as olefins, tars and/or aromatic compounds, into a methane rich gas by bringing the gas mixture into a contact with a supported metal catalyst comprising:
a) as an active phase nickel and optionally cobalt, ruthenium, iridium, molybdenum, iron or any possible combination thereof,
b) as a promoter boron and optionally sodium, potassium, calcium, magnesium, boron, rubidium, barium, gallium, phosphorus or any possible combinations thereof, and
c) as a support alumina and optionally silica, titania, lanthana, zirconia, ceria, magnesia or any possible combination thereof.
The presented invention improves the carbon resistance of nickel catalysts for low temperature (250-400°C) applications such as the methanation. Polymeric carbon is formed by reaction of carbon atoms on the catalyst surface under locally hydrogen-deficient situations. These carbon atoms stem from dissociation of carbon oxides and hydrocarbons whereby unsaturated hydrocarbons (ethylene, acetylene) and CO lead to higher carbon deposition rates. Using presently the promoter boron in the nickel catalyst avoids the formation of intermediates for polymeric carbon. As a second benefit, the formation of nickel carbides and carbon whiskers is decreased, too.

Abstract translation: 因此，本发明的目的是提供一种利用对催化反应具有高选择性的催化剂生产SNG的方法，并由于较小的堵塞和强的耐碳性而使催化剂寿命长，以防止其 失活。 根据本发明，通过转化CO和/或CO 2的方法来实现这些目的，所述CO和/或CO 2包括来自工业过程的气体混合物，例如碳质原料（即生物质）的气化，热解，矿石转化，燃烧，煅烧 或发酵，其中气体混合物还包含浓度高于15％的饱和烃和/或不饱和烃如烯烃，焦碳和/或芳族化合物，通过使气体混合物与负载金属接触而进入富含甲烷的气体 催化剂包括：a）作为活性相镍和任选的钴，钌，铱，钼，铁或其任何可能的组合，b）作为助催化剂硼和任选的钠，钾，钙，镁，硼，铷，钡，镓 ，磷或其任何可能的组合，和c）作为载体氧化铝和任选的二氧化硅，二氧化钛，氧化镧，氧化锆，二氧化铈，氧化镁或任何可能的组合 复查。 本发明改进了镍催化剂对于低温（250-400℃）应用如碳化反应的耐碳性。 在局部氢缺陷的情况下，通过碳原子在催化剂表面上的反应形成聚合碳。 这些碳原子源于碳氧化物和烃的解离，因此不饱和烃（乙烯，乙炔）和CO导致更高的碳沉积速率。 目前使用镍催化剂中的促进剂硼避免形成聚合碳的中间体。 作为第二个好处，镍碳化物和碳晶须的形成也减少了。

公开(公告)号：EP2970040A1

公开(公告)日：2016-01-20

申请号：EP14714866.2

申请日：2014-03-07

Applicant: The Procter & Gamble Company

Inventor： KELLETT, Patti, Jean ,  COLLIAS, Dimitris, Ioannis

IPC: C07C1/22 ,  B01J23/42 ,  B01J23/755 ,  C07C37/50

CPC classification number: B01J29/67 ,  B01J23/42 ,  B01J23/44 ,  B01J23/58 ,  B01J23/626 ,  B01J23/6482 ,  B01J23/6522 ,  B01J23/72 ,  B01J23/755 ,  B01J23/78 ,  B01J23/835 ,  B01J23/8472 ,  B01J23/86 ,  B01J29/44 ,  B01J29/46 ,  B01J29/68 ,  B01J37/0201 ,  B01J37/18 ,  C07C1/22 ,  C07C37/50 ,  C07C2521/04 ,  C07C2529/44 ,  C07C2529/46 ,  Y02P20/52 ,  C07C39/19 ,  C07C15/02

Abstract: Hydrotreating catalysts and processes useful for the conversion of methoxylated aromatic compounds to simple aromatic compounds are provided. The catalysts comprise transition metal selected from the group consisting of Group 8 metals, Group 9 metals, Group 10 metals, Group 11 metals, and mixtures thereof, and catalyst support selected from the group consisting of shape-selective zeolite, silica, titania, zirconia, and mixtures thereof.

Abstract translation: 提供加氢处理催化剂和方法为甲氧基化的芳香族化合物，以简单的芳族化合物的转化率是有用的。 催化剂包含选自组的8族金属，第9族金属，第10族金属，11种族金属，选定的过渡金属及其混合物，和选自形状选择性沸石，二氧化硅，二氧化钛，氧化锆中选择的催化剂载体 和它们的混合物。

公开(公告)号：EP2969188A1

公开(公告)日：2016-01-20

申请号：EP14716936.1

申请日：2014-03-14

Applicant: Johnson Matthey Public Limited Company

Inventor： KILMARTIN, John ,  FISHER, Janet Mary ,  COLLIER, Jillian Elaine ,  THOMPSETT, David ,  RAJARAM, Raj Rao

IPC: B01J23/34 ,  B01J37/02 ,  B01J37/03 ,  B01J35/10 ,  B01J37/08 ,  B01D53/94

CPC classification number: B01J29/045 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/208 ,  B01D2255/2065 ,  B01D2255/2073 ,  B01D2255/50 ,  B01D2257/404 ,  B01J23/34 ,  B01J29/04 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/033 ,  B01J37/08 ,  B01J37/30

Abstract: Catalysts and articles useful for selective catalytic reduction (SCR) are disclosed. The catalyst comprises a cerium oxide and an octahedral molecular sieve (OMS) comprising manganese oxide. The catalysts, which comprise 0.1 to 50 wt.% of cerium, can be made by doping, ion-exchange, deposition, or other techniques. Also disclosed is an SCR process in which a gaseous mixture comprising nitrogen oxides is selectively reduced in the presence of a reductant and the cerium-modified OMS catalyst. The cerium-modified manganese oxide OMS catalysts offer unexpected advantages for selective catalytic reduction, especially NH
3 -SCR, including improved thermal stability and improved activity for NOx conversion, especially at relatively low temperatures (100°C to 250°C).

公开(公告)号：EP2827987A4

公开(公告)日：2016-01-20

申请号：EP13764224

申请日：2013-03-15

Applicant: VÄLINGE PHOTOCATALYTIC AB

Inventor： HUMLE MICHAEL ,  ØSTERGAARD SIMON LAUSTEN

IPC: B01J35/00 ,  B01J21/06 ,  B01J35/02 ,  C09C1/36 ,  G03C1/775

CPC classification number: B01J31/38 ,  B01J21/063 ,  B01J23/42 ,  B01J35/004 ,  B01J35/006 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0209 ,  B01J2231/70 ,  C08K3/20 ,  C08K3/22 ,  C08K2003/2241 ,  C09D1/00 ,  C09D5/1618 ,  C09D7/48 ,  C09D183/12 ,  C08L71/02

Abstract: The present disclosure relates to a photocatalytic composition comprising photocatalytic titanium dioxide particles being dispersed in a continuous phase, and at least one anti-photogreying additive, wherein said at least one anti-photogreying additive is adapted to limit photogreying of said titanium dioxide particles while the photocatalytic activity of said titanium dioxide particles is maintained, and wherein the photo greying index (ΔL) of said composition is less than 6.