公开(公告)号：EP2404658A3

公开(公告)日：2012-12-12

申请号：EP11173001.6

申请日：2011-07-07

申请人： AIR PRODUCTS AND CHEMICALS, INC.

发明人： Wright, Andrew David ,  Fogash, Kevin Boyle ,  White, Vincent ,  Kloosterman, Jeffrey William ,  Golden, Timothy Christopher ,  Higginbotham, Paul

IPC分类号： B01D53/02 ,  B01D53/75

CPC分类号： B01D53/02 ,  B01D53/002 ,  B01D53/0462 ,  B01D53/229 ,  B01D53/75 ,  B01D53/8625 ,  B01D53/8646 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1124 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2256/22 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/80 ,  B01D2258/0283 ,  B01D2259/40054 ,  B01D2259/4145 ,  B01J20/043 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/18 ,  B01J20/28052 ,  B01J20/3408 ,  B01J20/3433 ,  B01J20/3483 ,  B01J20/3491 ,  B01J23/22 ,  B01J23/30 ,  B01J23/34 ,  B01J23/72 ,  B01J2220/56 ,  B01J2220/603 ,  F23J15/02 ,  F23J2215/10 ,  F23J2215/101 ,  F23J2215/20 ,  F23J2215/50 ,  F23J2219/60 ,  F25J3/067 ,  F25J2205/40 ,  F25J2205/66 ,  F25J2205/80 ,  F25J2210/70 ,  F25J2220/82 ,  F25J2220/84 ,  F25J2230/30 ,  F25J2230/32 ,  F25J2230/80 ,  F25J2240/90 ,  Y02A50/2345 ,  Y02C10/12 ,  Y02E20/344

摘要： NO 2 may be removed from a carbon dioxide feed gas comprising NO x and at least one "non-condensable" gas as contaminants by passing the feed gas at a first elevated pressure through a first adsorption system that selectively adsorbs at least NO 2 to produce at least substantially N0 2 -free carbon dioxide gas. The adsorption system is at least partially regenerated using a carbon dioxide-rich gas recovered from the substantially NO 2 -free carbon dioxide gas after purification. The invention has particular application in removing NO x and water from flue gas generated by oxyfuel combustion.

公开(公告)号：EP2488279A1

公开(公告)日：2012-08-22

申请号：EP10781964.1

申请日：2010-10-11

申请人： Lafarge

发明人： DUBOIS-BRUGGER, Isabelle ,  DYKMAN, Mélanie ,  HORGNIES, Matthieu

IPC分类号： B01D53/02 ,  B01J20/20 ,  B28B7/38 ,  C04B41/65

CPC分类号： B01D53/02 ,  B01D53/565 ,  B01D2253/10 ,  B01D2253/102 ,  B01D2257/106 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/708 ,  B01D2259/4591 ,  B01J20/103 ,  B01J20/14 ,  B01J20/18 ,  B01J20/20 ,  B01J20/226 ,  B01J20/28004 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/28078 ,  B01J20/28085 ,  B28B7/384 ,  C04B28/02 ,  C04B2111/00413 ,  C04B2111/10 ,  Y02A50/2345 ,  Y02C10/08 ,  C04B14/022 ,  C04B38/007 ,  C04B14/066 ,  C04B14/08 ,  C04B14/047 ,  C04B14/303

摘要： The invention relates to the use of an element for the adsorption of at least one atmospheric volatile compound and/or an atmospheric gas from the group comprising atmospheric nitrogen oxides, sulphur oxides, carbon oxides, ozone and volatile organic compounds. The aforementioned element has a surface porosity strictly greater than 8% and comprises: a one-piece body made from concrete and having a volume greater than 1 L; and, in the concrete body and/or at the surface thereof, a compound having a BET specific exchange surface area greater than 100 m
2 /g, said element containing no photocatalytic agent.

公开(公告)号：EP2404658A2

公开(公告)日：2012-01-11

申请号：EP11173001.6

申请日：2011-07-07

申请人： AIR PRODUCTS AND CHEMICALS, INC.

发明人： Wright, Andrew David ,  Fogash, Kevin Boyle ,  White, Vincent ,  Kloosterman, Jeffrey William ,  Golden, Timothy Christopher ,  Higginbotham, Paul

IPC分类号： B01D53/02 ,  B01D53/75

CPC分类号： B01D53/02 ,  B01D53/002 ,  B01D53/0462 ,  B01D53/229 ,  B01D53/75 ,  B01D53/8625 ,  B01D53/8646 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1124 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2256/22 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/80 ,  B01D2258/0283 ,  B01D2259/40054 ,  B01D2259/4145 ,  B01J20/043 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/18 ,  B01J20/28052 ,  B01J20/3408 ,  B01J20/3433 ,  B01J20/3483 ,  B01J20/3491 ,  B01J23/22 ,  B01J23/30 ,  B01J23/34 ,  B01J23/72 ,  B01J2220/56 ,  B01J2220/603 ,  F23J15/02 ,  F23J2215/10 ,  F23J2215/101 ,  F23J2215/20 ,  F23J2215/50 ,  F23J2219/60 ,  F25J3/067 ,  F25J2205/40 ,  F25J2205/66 ,  F25J2205/80 ,  F25J2210/70 ,  F25J2220/82 ,  F25J2220/84 ,  F25J2230/30 ,  F25J2230/32 ,  F25J2230/80 ,  F25J2240/90 ,  Y02A50/2345 ,  Y02C10/12 ,  Y02E20/344

摘要： NO 2 may be removed from a carbon dioxide feed gas comprising NO x and at least one "non-condensable" gas as contaminants by passing the feed gas at a first elevated pressure through a first adsorption system that selectively adsorbs at least NO 2 to produce at least substantially N0 2 -free carbon dioxide gas. The adsorption system is at least partially regenerated using a carbon dioxide-rich gas recovered from the substantially NO 2 -free carbon dioxide gas after purification. The invention has particular application in removing NO x and water from flue gas generated by oxyfuel combustion.

摘要翻译： 可以通过使第一升高压力下的进料气体通过第一吸附系统从包含NO x和至少一种“不可冷凝”气体作为污染物的二氧化碳进料气体中去除NO 2，该第​​一吸附系统选择性吸附至少NO 2以至少基本上产生 不含NO2的二氧化碳气体。 在纯化后使用从基本上不含NO 2的二氧化碳气体回收的富含二氧化碳的气体至少部分再生吸附系统。 本发明在氧燃烧燃烧产生的烟气中去除NOx和水方面具有特殊的应用。

公开(公告)号：EP2115277B1

公开(公告)日：2010-07-07

申请号：EP08707458.9

申请日：2008-01-31

申请人： Umicore AG & Co. KG

发明人： ECKHOFF, Stephan ,  GRISSTEDE, Ina ,  MUELLER, Wilfried ,  KREUZER, Thomas

IPC分类号： F01N3/033 ,  F01N3/08 ,  F01N13/04

CPC分类号： F01N3/2066 ,  F01N3/0253 ,  F01N3/033 ,  F01N3/035 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/0885 ,  F01N3/103 ,  F01N3/106 ,  F01N9/002 ,  F01N13/009 ,  F01N13/0093 ,  F01N13/011 ,  F01N13/107 ,  F01N2250/02 ,  F01N2510/065 ,  F01N2610/02 ,  F01N2610/03 ,  F02B75/22 ,  F02D41/0245 ,  F02D41/029 ,  F02D41/405 ,  Y02A50/2325 ,  Y02A50/2345 ,  Y02T10/24 ,  Y02T10/26 ,  Y02T10/47

摘要： In order to comply with legal exhaust gas regulations, the exhaust gases of a lean mix engine (1) must be freed from soot particles and nitrogen oxides. For this purpose, the emission control system usually contains a soot filter (6) and a catalyst (7) for the removal of the nitrogen oxides. The soot deposited in the soot filter must be combusted at regular intervals by the raising of the exhaust gas temperature to the soot ignition temperature. This process can cause thermal damage to the catalyst for the removal of the nitrogen oxides. It is proposed that the cylinders of the lean mix engine be divided into two groups (2, 2') which deliver the exhaust gases to two allocated exhaust pipes (3, 3'), each of which contains a soot filter (6, 6'), and which are brought together at the inlet (4) to a common exhaust pipe (5). The common exhaust pipe contains the catalyst for the removal of the nitrogen oxides. By means of the temporally offset regeneration of the two soot filters, the exhaust gas temperature in the common exhaust pipe is limited to a temperature which is the average of the exhaust gas temperature of normal operation and that of regeneration operation, and the catalyst for the removal of the nitrogen oxides is treated with care.

公开(公告)号：EP2048115A3

公开(公告)日：2009-07-29

申请号：EP09075049.8

申请日：2002-12-11

申请人： ENGELHARD CORPORATION

发明人： Deeba, Michel

IPC分类号： C01B39/02 ,  C01B39/08 ,  B01J29/89 ,  B01J20/18

CPC分类号： F01N3/0835 ,  B01D53/9431 ,  B01J29/166 ,  B01J29/44 ,  B01J29/78 ,  B01J35/0006 ,  F01N3/0222 ,  F01N3/0226 ,  F01N3/0231 ,  F01N3/035 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/0871 ,  F01N3/2807 ,  F01N3/2828 ,  F01N13/009 ,  F01N13/0097 ,  F01N2330/06 ,  F01N2330/12 ,  F01N2370/24 ,  F01N2510/06 ,  F01N2510/065 ,  F01N2570/10 ,  F01N2570/12 ,  F01N2570/14 ,  Y02A50/2344 ,  Y02A50/2345 ,  Y02T10/24

摘要： A composition comprising a zeolite exchanged with selected base metal or ion exchanged with hydrogen is disclosed. The composition is suitable for use for adsorbing gaseous components and, in particular, is suitable for use as a low temperature NO 2 trap material in an exhaust system. A preferred zeolite is titanium silicate such as ETS-10 and preferred base metals include Mn and Co.

摘要翻译： 公开了包含用选定的碱金属交换的沸石或与氢进行离子交换的组合物。 该组合物适用于吸附气体组分，并且特别适合用作排气系统中的低温NO 2捕集材料。 优选的沸石是硅酸钛例如ETS-10，优选的贱金属包括Mn和Co.

公开(公告)号：EP1309775B1

公开(公告)日：2008-06-18

申请号：EP01956107.5

申请日：2001-08-03

申请人： BASF Catalysts LLC

发明人： KAKWANI, Ramesh, M. ,  VOSS, Kenneth ,  PATCHETT, Joseph, A. ,  GRIMSTON, Karl, R.

IPC分类号： F01N3/023 ,  F01N3/20 ,  F01N3/035

CPC分类号： F01N3/2066 ,  B01D53/9409 ,  B01D2251/2062 ,  B01D2255/20738 ,  B01D2255/50 ,  B01D2258/012 ,  F01N3/0231 ,  F01N3/035 ,  F01N13/009 ,  F01N13/0097 ,  F01N13/011 ,  F01N2510/06 ,  F01N2510/063 ,  F01N2610/02 ,  F01N2610/03 ,  Y02A50/2325 ,  Y02A50/2345 ,  Y02C20/10

摘要： A diesel engine aftertreatment exhaust system uses catalyzed soot filters for particulate matter reduction and urea SCR catalysts for NOx reduction on diesel engines in a combined system to lower particulate matter and NOx at the same time. With this integral emission control system, diesel engines are able to meet ultra low emission standards.

摘要翻译： 柴油发动机的排气后处理系统使用催化颗粒物质还原和尿素SCR催化剂上的柴油发动机的NO x降低碳烟过滤器中，一个联合系统，以降低颗粒物和NOx的同时。 有了这个整体的排放控制系统，柴油发动机能够满足超低排放标准。

公开(公告)号：EP0908230B1

公开(公告)日：2005-12-07

申请号：EP98402525.4

申请日：1998-10-12

申请人： Hitachi Zosen Corporation

发明人： Ichiki, Masayoshi, c/o Hitachi Zosen Corporation ,  Sairyo, Yuki, c/o Hitachi Zosen Corporation ,  Fukuju, Atsushi, c/o Hitachi Zosen Corporation

IPC分类号： B01J20/22 ,  B01J20/32 ,  B01D53/86 ,  B01D53/56 ,  B01D53/94 ,  B01D53/02

CPC分类号： B01J20/20 ,  B01D53/02 ,  B01D53/565 ,  B01D2257/404 ,  B01J20/0211 ,  B01J20/0222 ,  B01J20/0225 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/165 ,  B01J20/28004 ,  B01J20/28028 ,  B01J20/28033 ,  B01J20/28045 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3248 ,  B01J20/3251 ,  B01J20/3289 ,  B01J20/3293 ,  B01J2220/42 ,  B01J2220/4831 ,  B01J2220/64 ,  Y02A50/2345 ,  Y10S95/90

摘要： The present invention provides a nitrogen dioxide absorbent for the exhaust gas purifying facility designed to remove by absorption or adsorption of NO2 from a gas (such as ventilation gas from road tunnels) containing NOx in low concentrations. The absorbent is composed of a porous carrier and a basic amino acid and/or organic amine compound supported thereon. The absorbent is produced by impregnating a porous carrier sequentially with two aqueous solutions each containing in an amount of, for example, 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound, or impregnating a porous carrier with a solution containing 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and/or 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound.

公开(公告)号：EP1493484A1

公开(公告)日：2005-01-05

申请号：EP04014458.6

申请日：2004-06-21

申请人： Haldor Topsoe A/S

发明人： Mogensen, Gurli

IPC分类号： B01D53/94 ,  F01N3/022 ,  F01N3/035 ,  F01N3/28 ,  B01D39/20 ,  C04B38/00

CPC分类号： B01D53/945 ,  B01D39/2075 ,  B01J23/6527 ,  F01N3/0222 ,  F01N3/023 ,  F01N3/035 ,  F01N3/2828 ,  F01N2430/04 ,  F01N2510/06 ,  F01N2570/02 ,  Y02A50/2343 ,  Y02A50/2345 ,  Y02T10/22

摘要： The invention provides a process and filter for catalytic purification of exhaust gas from a diesel engine by passing the exhaust gas through a wall flow filter provided with material being catalytic active in the reduction of nitrogen oxides to nitrogen and oxidation of carbonaceous compounds to carbon dioxide and water. The wall flow filter is prepared from silicon carbide and provided with a layer of titanium dioxide on its surface and wherein the catalytic active material comprises oxides of vanadium, tungsten and metallic palladium.

公开(公告)号：EP1063000A4

公开(公告)日：2003-01-02

申请号：EP98907162

申请日：1998-03-11

申请人： HITACHI SHIPBUILDING ENG CO

发明人： ICHIKI MASAYOSHI ,  AKIYAMA MASAKI ,  FUKUJU ATSUSHI

IPC分类号： B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J23/22

CPC分类号： B01D53/8625 ,  Y02A50/2345 ,  Y02C20/10

摘要： The invention provides a process for removing NOx which is free of impairment in denitration efficiency at a reaction temperature of up to 300 DEG C even when the component molar ratio of NOx in the gas to be treated is NO2 > NO. For use in removing NOx from the gas to be treated and containing NO2 in a larger amount than NO, that is, having a (NO2)/NOx ratio in excess of 0.5, by selective reduction with use of ammonia serving as a main reducing agent in the presence of a denitration catalyst, the process of the invention for removing NOx comprises adding to the denitration reaction system a substance for removing an excess of oxygen accumulating on catalyst active sites by selectively reducing the oxygen at not higher than 300 DEG C, for example, at 300 to 150 DEG C, in other words, a substance which reacts with the excess of oxygen on the catalyst active sites and becomes oxidized at not higher than 300 DEG C.

摘要翻译： 本发明提供一种除去NOx的方法，即使在待处理气体中的NOx的成分摩尔比为NO2> NO时，在高达300℃的反应温度下，脱硝效率也不受损害。 用于从待处理的气体中除去NOx并且含有比NO大的NO 2，即（NO 2）/ NOx比超过0.5时，通过使用氨作为主要还原剂进行选择性还原 在脱硝催化剂的存在下，本发明除去NOx的方法包括向脱硝反应体系中加入一种物质，用于通过选择性地将氧气在不高于300℃还原的方式除去积聚在催化剂活性位上的过量的氧，用于 例如，在300〜150℃，换句话说，与催化剂活性部位上的过量氧反应并在不高于300℃氧化的物质。

公开(公告)号：EP0749774B1

公开(公告)日：2002-01-30

申请号：EP96304610.7

申请日：1996-06-21

申请人： NGK INSULATORS, LTD.

发明人： Noda, Naomi ,  Shibagaki, Yukinari ,  Mizuno, Hiroshige ,  Takahashi, Akira

IPC分类号： B01D53/94

CPC分类号： B01D53/9481 ,  B01D53/945 ,  B01J23/58 ,  B01J23/63 ,  F01N3/0835 ,  F01N3/0842 ,  F01N2240/18 ,  F01N2570/12 ,  Y02A50/2324 ,  Y02A50/2345 ,  Y02T10/22

摘要： A system for exhaust gas purification disposed in the exhaust pipe of internal combustion engine, includes the followings (C) and (D): (C) a catalyst giving an excellent light-off performance at low temperatures, comprising a carrier and a catalyst layer supported thereon, the catalyst layer comprising a precious metal and a substance having an electron donatability and/or a nitrogen dioxide absorbability and releasability, and (D) an adsorbent comprising a carrier and an adsorbent layer having a hydrocarbon adsorbability, supported on the carrier. This system for exhaust gas purification can effectively purify the harmful substances contained in the exhaust gases discharged from internal combustion engines of automobiles, etc., particularly the hydrocarbons discharged in a large amount from gasoline engines during their cold start.